钟羽武

男， 中国科学院化学研究所， 教授/研究员/教授级高工或同等级别

学习/工作经历

1995.09– 1999.07, 南开大学化学系，本科学生
1999.09– 2004.07, 中国科学院上海有机所, 博士研究生
2004.09– 2006.09, 日本东京大学化学系, 博士后
2006.09– 2009.09, 美国康奈尔大学化学与生物学系, 博士后
2009.09至今, 中国科学院化学研究所, 研究员

研究领域和兴趣

光功能材料与光电化学，光功能配合物的合成与组装，近红外电致变色，混合价电子转移，有机功能分子设计与合成，电化学聚合薄膜的制备与应用，有机空穴传输材料的合成及其在钙钛矿太阳能电池中的应用。

主要业绩

光功能配合物是重要的分子材料，在分子光电子学和光电/电光转换器件中有重要用途。近年来，围绕金属有机光功能配合物的分子设计合成、功能薄膜制备、微纳晶体制备及光电性能开展工作，取得了如下创新性进展：
1. 基于“有机-无机共轭”策略，合成了一系列三芳胺和金属钌共轭的给-受体电子转移化合物，利用三芳胺和金属有机钌之间的强电子耦合，实现迄今为止多联苯桥基诱导的最长电子转移过程。发展了“金属/有机共轭”近红外分子设计策略，已被国内外8个课题组多次使用和借鉴，并扩展到三芳胺与钌、锇、铁、钴、钼、铱等6种不同金属共轭的分子体系。
2. 利用电化学聚合以及自组装成膜，实现了金属有机钌配合物形貌、厚度可控的功能薄膜制备。基于配合物与电极之间高效的界面电子转移过程，实现高性能近红外电致变色和电信息存储，在光纤通讯和信息处理方面有重要应用前景。发展的桥联配体和电聚合方法被不同课题组用于金属配合物薄膜的制备。
3. 通过结晶驱动组装法，首次制备了双组份光功能配合物的高质量微纳晶体，实现高效三线态能量转移和天线放大效应，并具备微纳尺度光信号处理功能。通过改变分子结构与组装条件，实现微纳晶体形貌与发光性能的调控，为纳米光子学奠定重要分子及材料基础。
近五年（2014 – 2019）发表通讯作者论文60余篇，包括J. Am. Chem. Soc. 6篇、Angew. Chem. Int. Ed. 4篇、Nat. Commun. 2篇、Chem. Sci. 2篇，应邀在Coord. Chem. Rev.、Chem. Rec.等期刊撰写综述，撰写专著章节2次。近5年在国际配位化学会议、ACS年会等重要学术会议上做邀请报告10余次。迄今共发表论文140余篇，近五年他引1800次。先后担任《中国科学：化学》，Sci. Rep.等4种期刊编委，入选2018年度《中国科学》《科学通报》优秀编委。获2015年中国电化学青年奖、2019年国家杰出青年科学基金、中国光化学-泊菲莱优秀青年科学家奖、卢嘉锡优秀导师奖。

代表成果

论文：
(1) Zhong-Qiu Li, Yu-Duan Wang, Jiang-Yang Shao, Zeyang Zhou, Zhong-Liang Gong, Chuang Zhang, Jiannian Yao and Yu-Wu Zhong*, Electrically Amplified Circularly Polarized Luminescence by a Chiral Anion Strategy. Angew. Chem. Int. Ed. 2023, 62, e202302160.
(2) Zhong-Qiu Li, Zhong-Liang Gong, Tongling Liang, Stefan Bernhard, Yu-Wu Zhong* and Jiannian Yao*, Circularly polarized phosphorescence and photon transport of micro/nanocrystals of ruthenium and iridium complexes with chiral anions. Sci. China Chem. 2023, 66, 2892-2902.
(3) Jiang-Yang Shao†, Dongmei Li†, Jiangjian Shi†, Chuang Ma†, Yousheng Wang†, Xiaomin Liu†, Xianyuan Jiang†, Mengmeng Hao†, Luozheng Zhang†, Chang Liu†, Yiting Jiang†, Zhenhan Wang†, Yu-Wu Zhong*, Shengzhong (Frank) Liu*, Yaohua Mai*, Yongsheng Liu*, Yixin Zhao*, Zhijun Ning*, Lianzhou Wang*, Baomin Xu*, Lei Meng*, Zuqiang Bian*, Ziyi Ge*, Xiaowei Zhan*, Jingbi You*, Yongfang Li and Qingbo Meng*, Recent progress in perovskite solar cells: material science. Sci. China Chem. 2023, 66, 10-64.
(4) Zhong-Qiu Li, Dian-Xue Ma, Fa-Feng Xu, Ti-Xiong Dan, Zhong-Liang Gong, Jiang-Yang Shao, Yong Sheng Zhao, Jiannian Yao and Yu-Wu Zhong*, Selective, Anisotropic, or Consistent Polarized-Photon Out-Coupling of 2D Organic Microcrystals. Angew. Chem. Int. Ed. 2022, 61, e202205033.
(5) Fa-Feng Xu#, Wei Zeng#, Meng-Jia Sun, Zhong-Liang Gong, Zhong-Qiu Li, Yong Sheng Zhao, Jiannian Yao and Yu-Wu Zhong*, Organoplatinum(II) Cruciform: A Versatile Building Block to Fabricate 2D Microcrystals with Full-Color and White Phosphorescence and Anisotropic Photon Transport. Angew. Chem. Int. Ed. 2022, 61, e202116603.
(6) Rui Li, Zhong-Liang Gong*, Qijian Zhu, Meng-Jia Sun, Yanke Che, Jiannian Yao and Yu-Wu Zhong*, A pre-organized monomer-reservoir strategy to prepare multidimensional phosphorescent organoplatinum nanocrystals and suprastructures. Sci. China Chem. 2022, 65, 328-338.
(7) Ming-Hua Li#, Jiang-Yang Shao#, Yan Jiang*, Fa-Zheng Qiu, Shuo Wang, Jianqi Zhang, Guangchao Han, Jilin Tang, Fuyi Wang, Zhixiang Wei, Yuanping Yi, Yu-Wu Zhong*, and Jin-Song Hu*, Electrical Loss Management by Molecularly Manipulating Dopant-free Poly(3-hexylthiophene) towards 16.93% CsPbI2Br Solar Cells. Angew. Chem. Int. Ed. 2021, 60, 16388-16393.
(8) Zhong-Qiu Li, Zhong-Liang Gong, Jiang-Yang Shao, Jiannian Yao and Yu-Wu Zhong*, Full-Color and White Circularly Polarized Luminescence of Hydrogen-Bonded Ionic Organic Microcrystals. Angew. Chem. Int. Ed. 2021, 60, 14595-14600.
(9) Zhong-Liang Gong†, Xuefeng Zhu†, Zhonghao Zhou†, Si-Wei Zhang†, Dong Yang†, Biao Zhao†, Yi-Pin Zhang†, Jianping Deng*, Yixiang Cheng*, You-Xuan Zheng*, Shuang-Quan Zang*, Hua Kuang*, Pengfei Duan*, Mingjian Yuan*, Chuan-Feng Chen*, Yong Sheng Zhao*, Yu-Wu Zhong*, Ben Zhong Tang* and Minghua Liu*, Frontiers in circularly polarized luminescence: molecular design, self-assembly, nanomaterials, and applications. Sci. China Chem. 2021, 64, 2060-2104.
(10) Zhong-Liang Gong, Yu-Wu Zhong*, Handedness-Inverted Polymorphic Helical Assembly and Circularly Polarized Luminescence of Chiral Platinum Complexes. Sci. China Chem. 2021, 64, 788-799.
(11) Tian‐Ge Sun, Zhong‐Liang Gong, Jiang‐Yang Shao*, Yu‐Wu Zhong*, A Star‐Shaped Solvatofluorochromic Pyrene‐Triarylamine Derivative as a Fluorescent Thermometer over a Wide Temperature Range. Chin.J.Chem. 2020, 38, 1515-1520.
(12) Qing Hao, Zhi-Juan Li, Cheng Lu, Bing Sun, Yu-Wu Zhong*, Li-Jun Wan and Dong Wang*, Oriented Two-Dimensional Covalent Organic Framework Films for Near-Infrared Electrochromic Application, J. Am. Chem. Soc. 2019, 141, 19831–19838.
(13) Jian-Hong Tang‡, Yueqi Li‡, Qingqing Wu‡, Zixiao Wang‡, Songjun Hou, Kun Tang, Yue Sun, Hui Wang, Heng Wang, Cheng Lu, Xiang Wang, Xiaopeng Li, Dong Wang, Jiannian Yao, Colin J. Lambert*, Nongjian Tao*, Yu-Wu Zhong* and Peter J. Stang*, Single-molecule level control of host-guest interactions in metallocycle-C60 complexes, Nat. Commun. 2019, 10, 4599.
(14) Meng-Jia Sun‡, Yingying Liu‡, zeng wei, Yong Sheng Zhao*, Yu-Wu Zhong* and Jiannian Yao*, Photoluminescent Anisotropy Amplification in Polymorphic Organic Nanocrystals by Light-Harvesting Energy Transfer. J. Am. Chem. Soc. 2019, 141, 6157-6161.
(15) Zhi-Juan Li, Chang-Jiang Yao and Yu-Wu Zhong*, Near-infrared electrochromism of multilayer films of a cyclomet-alated diruthenium complex prepared by layer-by-layer deposi-tion on metal oxide substrates, Sci. China Chem. 2019, 62, 1675–1685.
(16) Jian-Hong Tang, Zhenfeng Cai, Dong Yan, Kun Tang, Jiang-Yang Shao, Chuanlang Zhan, Dong Wang, Yu-Wu Zhong,* Li-Jun Wan, and Jiannian Yao, A Molecular Quadripod as a Noncovalent Interfacial Coupling Reagent for Forming Immobilized Coordination Assemblies. J. Am. Chem. Soc. 2018, 140, 12337-12340.
(17) Qian-Qing Ge‡, Jiang-Yang Shao‡,*, Jie Ding, Li-Ye Deng, Wen-Ke Zhou, Yao-Xuan Chen, Jing-Yuan Ma, Li-Jun Wan, Jiannian Yao, Jin-Song Hu*, and Yu-Wu Zhong*, A Two‐Dimensional Hole‐Transporting Material for High‐Performance Perovskite Solar Cells with 20% Average Efficiency. Angew. Chem. Int. Ed. 2018, 57, 10959-10965.
(18) Jian-Hong Tang‡, Yue Sun‡, Zhong-Liang Gong, Zhong-Yu Li, Zhixuan Zhou, Heng Wang, Xiaopeng Li, Manik Lal Saha*, Yu-Wu Zhong* and Peter J. Stang*, Temperature-Responsive Fluorescent Organoplatinum(II) Metallacycles. J. Am. Chem. Soc. 2018, 140, 7723-7729.
(19) Meng-Jia Sun, Yu-Wu Zhong* and Jiannian Yao*, Thermal-Responsive Phosphorescent Nanoamplifiers Assembled from Two Metallophosphors. Angew. Chem. Int. Ed. 2018, 57, 7820-7825.
(20) Meng-Jia Sun, Yingying Liu, Yaming Yan, Rui Li, Qiang Shi*, Yong Sheng Zhao*, Yu-Wu Zhong* and Jiannian Yao*, In Situ Visualization of Assembly and Photonic Signal Processing in a Triplet Light-Harvesting Nanosystem. J. Am. Chem. Soc. 2018, 140, 4269−4278.
(21) Ce Zhou‡, Xingxing Li‡, Zhongliang Gong‡, Chuancheng Jia, Yuanwei Lin, Chunhui Gu, Gen He, Yuwu Zhong*, Jinlong Yang* and Xuefeng Guo*, Direct observation of single-molecule hydrogen-bond dynamics with single-bond resolution. Nat. Commun. 2018, 9, 807.
(22) Rui Li, Zhong-Liang Gong, Jian-Hong Tang, Meng-Jia Sun, Jiang-Yang Shao, Yu-Wu Zhong* and Jiannian Yao, Triarylamines with branched multi-pyridine groups: modulation of emission properties by structural variation, solvents, and tris(pentafluorophenyl)borane. Sci. China Chem. 2018, 61, 545-556.
(23) Zhong-Liang Gong, Chang-Jiang Yao, Jiang-Yang Shao, Hai-Jing Nie, Jian-Hong Tang, Yu-Wu Zhong*, Redox-responsive carbometalated ruthenium and osmium complexes, Sci. China Chem. 2017, 60, 583-590.
(24) Lin Wang+, Zhong-Liang Gong+, Shu-Ying Li, Wenjing Hong*, Yu-Wu Zhong*, Dong Wang*, Li-Jun Wan, Molecular Conductance through a Quadruple-Hydrogen-Bond-Bridged Supramolecular Junction, Angew. Chem. Int. Ed. 2016, 55, 12393-12397.
(25) Bin-Bin Cui, Jian-Hong Tang, Jiannian Yao, and Yu-Wu Zhong*, A Molecular Platform for Multistate Near-Infrared Electrochromism and Flip-Flop, Flip-Flap-Flop, and Ternary Memory, Angew. Chem. Int. Ed. 2015, 54, 9192-9197.
(26) Zhong-Liang Gong, Yu-Wu Zhong,* Urea-bridged diferrocene: structural, electrochemical, and spectroelectrochemical studies, Sci. China Chem. 2015, 58, 1444-1450.
(27) Bin-Bin Cui, Yu-Wu Zhong*, Jiannian Yao, Three-State Near-Infrared Electrochromism at the Molecular Scale, J. Am. Chem. Soc. 2015, 137 , 4058-4061.
(28) Bin-Bin Cui, Chang-Jiang Yao, Jiannian Yao, Yu-Wu Zhong,* Electropolymerized films as a molecular platform for volatile memory devices with two near-infrared outputs and long retention time, Chem. Sci. 2014, 5, 932-941.
(29) Chang-Jiang Yao，Yu-Wu Zhong*，Hai-Jing Nie，Hector D. Abruna，Jiannian Yao*，Near-IR Electrochromism in Electropolymerized Films of a Biscyclometalated Ruthenium Complex Bridged by 1.2.4.5-Tetra(2-pyridyl)benzene Ligand，J. Am. Chem. Soc. 2011, 133, 20720-20723.
(30) Chang-Jiang Yao，Yu-Wu Zhong*，Jiannian Yao*，Charge Delocalization in a Cyclometalated Bisruthenium Complex Bridged by a Noninnocent 1.2.4.5-Tetra(2-pyridyl)benzene Ligand, J. Am. Chem. Soc. 2011, 133, 15697-15706.

专利：
(1) 钟羽武; 王宇端; 邵将洋, 一种芴改性锌卟啉空穴传输材料及其制备方法与应用, 批准年份2022，专利号ZL202110466415.8
(2) 钟羽武; 龚忠亮, 一种咔唑桥联双核金属铂配合物及其制备方法和应用, 批准年份2022，专利号ZL202110349575 .4
(3) 钟羽武; 李仲秋，一种白色圆偏振发光有机微纳晶体材料及其制备方法，批准年份2022，专利号ZL202110303685.7
(4) 钟羽武; 李仲秋; 唐健洪; 龚忠亮，一种深蓝色发光有机微纳晶体材料及其制备方法，批准年份2022，专利号ZL202110127950.0
(5) 钟羽武; 龚忠亮, 一种离子型手性单核金属铂配合物、制备方法及其应用, 批准年份2022，专利号ZL202010239489.3

著作：
Yu-Wu Zhong, Chun Y. Liu and Jeffrey R. Reimers, Mixed‐Valence Systems: Fundamentals, Synthesis, Electron Transfer, and Applications, Wiley-VCH GmbH, 2023, Weinheim, Germany.

*以上信息由高级会员个人更新和维护。