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欢迎 叶书艳 会员加入中国化学会
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点击申请中国化学会会员

胡征

男, 南京大学化学化工学院

专业领域

能源纳米材料物理化学

学习/工作经历

1981/09 - 1985/07 南京大学,物理系,本科/学士
1985/09 - 1991/07 南京大学,物理系,研究生/硕士、博士
1991/09 - 1993/09 南京大学,化学化工学院,博士后
1993/12 - 1999/03 南京大学,化学化工学院,副教授
1999/03 - 至今 南京大学,化学化工学院,教授、博导

学术成就和学术贡献简述

长期围绕纳米/介观结构新材料的制备科学、能源存储/转化功能及其调控机制开展研究工作,取得特色成果:创制了介观结构碳纳米笼新材料,这类新材料在物质/电荷协同输运、活性物种高效利用等方面有独特优点,成为能源存储/转化的新平台材料,形成了纳米碳材料领域一个新的分支;设计原位实验定量揭示了苯生长碳纳米管的六元环生长机理,据此设计制备了新型的氮掺杂碳纳米管,并利用氮上孤对电子的配位作用制得了系列负载型催化剂,在诸如醇氧化、氧还原、氢析出、费托合成等反应中具优异性能;揭示了生长纳米线的经典VLS模型的相平衡主导本质,据此成功地用相图预测并实现了多个纳米线的生长;发现了结构新颖、截面呈六边形的AlN角面纳米管,确立了角面形貌与晶体结构的对应关系,将纳米管研究从层状材料拓展到非层状材料。

化学公益贡献简述

积极参与中国化学会的学术组织活动,担任第29、30、31、32届中国化学会学术年会能源纳米材料物理化学分会主席,多次获得优秀分会组织奖;
担任第十一届中美华人纳米论坛中方主席(2016)、第二届全国能源化学学术大会(2019)等会议主席;
被中国化学会推荐担任Pacifichem 2015、2020领域评审专家(Materials & Nanoscience);
担任《FlatChem》编辑、《化学学报》等化学及材料类刊物编委;
担任中国真空学会常务理事、中国微米纳米学会理事、江苏省材料学会理事长(2021~);
担任介观化学教育部重点实验室主任(2003-2015)、江苏省纳米技术重点实验室副主任(2002-2012);南京大学化学化工学院学位委员会主任(2015~至今);
作为王基铭院士、刘忠范院士率领的中国化学会代表团成员,2009年3月28日~4月3日访问日本化学会,参加系列学术活动,获时任日本化学会理事长中西宏幸签署的 “Award for Promotion of Japan-China Relationship”。

代表性成果

1. Q. Wu, L. J. Yang, X. Z. Wang, and Z. Hu, “From carbon-based nanotubes to nanocages for advanced energy conversion and storage” Acc. Chem. Res. 50 (2017) 435;
2. Z. Y. Lyu, Y. Zhou, W. R. Dai, X. H. Cui, M. Lai, L. Wang, F. W. Huo, W. Huang, Z. Hu, and W. Chen, “Recent advances in understanding of the mechanism and control of Li2O2 formation in aprotic Li–O2 batteries” Chem. Soc. Rev. 46(2017) 6046;
3. X. Y. Cheng, Z. Shen, L. Jiao, L. J. Yang, X. Z. Wang, Q. Wu, and Z. Hu, “Nitrogen-doped nanocarbons tune metal catalysts for energy chemistry: from high dispersion to single sites” EnergyChem (2021) web-released;
4. Z.Q. Zhang, Y.G. Chen, L.Q. Zhou, C. Chen, Z. Han, B.S. Zhang, Q. Wu, L.J. Yang, L.Y. Du, Y.F. Bu, P. Wang, X.Z. Wang, H. Yang, and Z. Hu, “The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring” Nat. Commun. 10 (2019) 1657;
5. G. C. Li, K. Mao, M. Liu, M. L. Yan, J. Zhao, B. X. Wang, L. J. Yang, Q. Wu, X. Z. Wang, and Z. Hu, Achieving Ultrahigh-volumetric energy storage by compressing nitrogen and sulphur co-doped carbon nanocages via capillarity. Adv. Mater. 32(2020) 2004632;
6. Q. Wu, L. J. Yang, X. Z. Wang, Z. Hu, “Carbon-based nanocages: a new platform for advanced energy storage and conversion” Adv. Mater. 32(2020)1904177;
7. L. J. Yang, J. L. Shui, L. Du, Y. Y. Shao, J. Liu, L. M. Dai, and Z. Hu, “Carbon-based metal-free ORR electrocatalysts for fuel cells: past, present, and future” Adv. Mater. 31(2019)1804799;
8. Y. F. Bu, T. Sun, D. Q. Li, L. Y. Du, O. Zhuo, L. J. Yang, Q. Wu, X. Z. Wang, and Z. Hu, “Compressing carbon nanocages by capillarity for optimizing porous structures towards ultrahigh-volumetric-performance supercapacitors” Adv. Mater. 29 (2017) 1700470;
9. J. Zhao, Y. F. Jiang, H. Fan, M. Liu, O. Zhuo, X. Z. Wang, Q. Wu, L. J. Yang, Y. W. Ma, and Z. Hu, “Porous 3D few-layer graphene-like carbon for ultrahigh-power supercapacitors with well-defined structure-performance relationship” Adv. Mater. 29 (2017) 1604569;
10. J. Zhao, H. W. Lai, Z. Y. Lyu,Y. F. Jiang, K. Xie, X. Z. Wang, Q. Wu, L. J. Yang, Z. Jin, Y. W. Ma, J. Liu and Z. Hu, “Hydrophilic nitrogen-doped hierarchical carbon nanocages for ultrahigh performance supercapacitor”Adv. Mater. 27 (2015) 3541;
11. S. Chen, J. Y. Bi, Y. Zhao, L. J. Yang, C. Zhang, Y. W. Ma, Q. Wu, X. Z. Wang, and Z. Hu, “Nitrogen-doped carbon nanocages as efficient metal-free electrocatalyst for oxygen reduction reaction” Adv. Mater. 24 (2012) 5593;
12. K. Xie, X. T. Qin, X. Z. Wang, Y. N. Wang, H. S. Tao, Q. Wu, L. J. Yang, and Z. Hu, “Carbon nanocages as supercapacitor electrode materials” Adv. Mater. 24 (2012) 347;
13. X. B. Wang, J. H. Song, F. Zhang, C. Y. He, Z. Hu, and Z. L. Wang, “Electricity generation based on one-dimensional group-III nitride nanomaterials” Adv. Mater. 22 (2010) 2155;
14. S. J. Jiang, Y. W. Ma, G. Q. Jian, H. S. Tao, X. Z. Wang, Y. N. Fan, Y. N. Lu, Z. Hu and Y. Chen, “Facile construction of Pt-Co/CNx nanotube electrocatalysts and their application to oxygen reduction reaction”Adv. Mater. 21 (2009) 4953;
15. Y. Zhao, L. J. Yang, S. Chen, X. Z. Wang, Y. W. Ma, Q. Wu, Y. F. Jiang, W. J. Qian, and Z. Hu, “Can boron and nitrogen codoping improve oxygen reduction reaction activity of carbon nanotubes?” J. Am. Chem. Soc. 135 (2013)1201;
16. C. Y. He, X. Z. Wang, Q. Wu, Z. Hu, Y. W. Ma, J. J. Fu and Y. Chen, “Phase-equilibrium-dominated vapor-liquid-solid growth mechanism” J. Am. Chem. Soc. 132 (2010)4843;
17. C. Liu, Z. Hu, Q. Wu, X. Z. Wang, Y. Chen, H. Sang, J. M. Zhu, S. Z. Deng and N. S. Xu, “Vapor-solid growth and characterization of aluminum nitride nanocones” J. Am. Chem. Soc. 127 (2005)1318;
18. X. Chen, J. Ma, Z. Hu, Q. Wu, and Y. Chen, “AlN nanotube: round or faceted?” J. Am. Chem. Soc. 127 (2005)7982;
19. Y. J. Tian, Z. Hu, Y. Yang, X. Z. Wang, X. Chen, H. Xu, Q. Wu, W. J. Ji and Y. Chen, “In situ TA-MS study on the six-membered-ring-based growth of carbon nanotubes with benzene precursor” J. Am. Chem. Soc. 126 (2004)1180;
20. Q. Wu, Z. Hu, X. Z. Wang, Y. N. Lu, X. Chen, H. Xu and Y. Chen, “Synthesis and characterization of faceted hexagonal aluminum nitride nanotubes” J. Am. Chem. Soc. 125 (2003) 10176;
21. L. J. Yang, S. J. Jiang, Y. Zhao, L. Zhu, S. Chen, X. Z. Wang, Q. Wu, J. Ma, Y. W. Ma, Z. Hu, “Boron-doped carbon nanotubes as metal-free electrocatalysts for oxygen reduction reaction” Angew. Chem. Int. Ed. 50(2011)7132; Angew. Chem. 123(2011) 7270;
22. O. Zhuo, L. J. Yang, F. J. Gao, B. L. Xu, Q. Wu, Y. N. Fan, Y. Zhang, Y. F. Jiang, R. S. Huang, X. Z. Wang and Z. Hu, “Stabilizing the active phase of iron-based Fischer–Tropsch catalysts for lower olefins: mechanism and strategy” Chem. Sci. 10 (2019) 6083;
23. Y. L. Zhang, J. Cai, Q. Wu, L. J. Yang, C. Y. He, X. Z. Wang, Z. Hu, “Predicting the growth of Si3N4 nanowires by phase-equilibrium-dominated vapor-liquid-solid mechanism” Phys. Rev. Mater. 1 (2017) 046001;
24. W. L Liu, L. Y. Du, S. L. Ju, X. Y. Cheng, Q. Wu, Z. Hu, and X. B. Yu, “Encapsulation of red phosphorus in carbon nanocages with ultrahigh content for high-capacity and long cycle life sodium-ion batteries” ACS NANO 15 (2021) 5679;
25. C. Y. He, Q. Wu, X. Z. Wang, Z. Hu, N. Liu, Y. Y. Zhang, Y. Zhao, L. J. Yang and Y. N. Lu, “Growth and characterization of ternary AlGaN alloy nanocones across the entire composition range”ACS Nano 5 (2011) 1291;
26. X. Xu, S. J. Jiang, Z. Hu, S. Q. Liu, “Nitrogen-doped carbon nanotubes: high electrocatalytic activity toward the oxidation of hydrogen peroxide and its application for biosensing” ACS Nano 4 (2010) 4292;
27. J. Zhao, C. X. Ge, Z. Y. Zhao, Q. Wu, M. Liu, M. L. Yan, L. J. Yang, X. Z. Wang and Z. Hu, “Sub-nanometer-scale fine regulation of interlayer distance in Ni-Co layered double hydroxides leading to high-rate supercapacitors” Nano Energy 76 (2020)105026;
28. M. Liu, H. Fan, O. Zhuo, J. C. Chen, Q. Wu, L. J. Yang, L. M. Peng, X. Z Wang, R. C. Che, Z. Hu, “A general strategy to construct yolk-shelled metal oxides inside carbon nanocages for high-stable lithium-ion battery anodes” Nano Energy 68 (2020) 104368;
29. L. Y. Du, Q. Wu, L. J. Yang, X. Wang, R.C. Che, Z. Y. Lyu, W. Chen, X. Z. Wang, Z. Hu, “Efficient synergism of electrocatalysis and physical confinement leading to durable high-power lithium-sulfur batteries”Nano Energy 57 (2019) 34 ;
30. Z. Y. Lyu, D. Xu, L. J. Yang, R. C. Che, R. Feng, J. Zhao, Y. Li, Q. Wu, X. Z. Wang, and Z. Hu, “Hierarchical carbon nanocages confining high-loading sulfur for high-rate lithium–sulfur batteries” Nano Energy 12 (2015) 657;
31. H. Pang, Y. Z. Zhang, W. L. Lai, Z. Hu, and W. Huang, “Lamellar K2Co3(P2O7)2•2H2O nanocrystal whiskers: High-performance flexible all-solid-state asymmetric micro-supercapacitors via inkjet printing” Nano Energy 15 (2015) 303;
32. H. W. Lai, Q. Wu, J. Zhao, Z. Y. Lyu, J. F. Xiong, S. Chen, L. J. Yang, X. Z. Wang, and Z. Hu, “Mesostructured NiO/Ni Composites for High-Performance Electrochemical Energy Storage” Energy Environ. Sci. 9 (2016) 2053 ;
33. Y. W. Ma, S.J. Jiang, G.Q. Jian, H.S. Tao, L.S. Yu, X.B. Wang, X.Z. Wang, J.M. Zhu, Z. Hu and Y. Chen, “CNx nanofibers converted from polypyrrole nanowires as platinum support for methanol oxidation” Energy Environ. Sci. 2 (2009) 224;
34. B. X. Wang, X. Wang, X. Y. Cheng, J. Zhang, M. L. Yan, G. C. Li, L. J. Yang, Q. Wu, X. Z. Wang, and Z. Hu, “Non-macrocyclic iron(II) soluble redox mediators leading to high-rate Li-O2 battery” CCS Chem. 2(2020)1350;
35. Z.Q. Zhang, Q. Wu, K. Mao, Y.G. Chen, L.Y. Du, Y. F. Bu, O. Zhuo, L.J. Yang,X.Z. Wang, Z. Hu, “Efficient ternary synergism of platinum/tin oxide/nitrogen-doped carbon leading to high-performance ethanol oxidation” ACS Catal. 8 (2018) 8477;
36. Y. F. Jiang, L. J. Yang, T. Sun, J. Zhao, Z. Y. Lyu, O. Zhuo, X. Z. Wang, Q. Wu, J. Ma, and Z. Hu, “Significant contribution of intrinsic carbon defects to oxygen reduction activity” ACS Catal. 5 (2015) 6707;
37. T. Sun, Q. Wu, R. C. Che, Y. Y. Bu, Y. F. Jiang, Y. Li, L. J. Yang, X. Z. Wang, and Z. Hu, “Alloyed Co−Mo nitride as high-performance electrocatalyst for oxygen reduction in acidic medium” ACS Catal. 5 (2015) 1857;
38. J. Z. Lu, L.J. Yang, B.L. Xu, Q. Wu, D. Zhang, S.J. Yuan, Y. Zhai, X.Z. Wang, Y.N. Fan, and Z. Hu, “Promotion effects of nitrogen doping into carbon nanotubes on supported iron Fischer−Tropsch catalysts for lower olefins” ACS Catal. 4 (2014) 613;
39. J. Zhao, H. Fan, G. C. Li, Q. Wu, L. J. Yang, Y. W. Ma, X. Z. Wang and Z. Hu, “Enlarging ion-transfer micropore channels of hierarchical carbon nanocages for ultrahigh energy and power densities” Sci. China Mater. 64(2021)2173;
40. Q. Wu, L. J. Yang, X. Z. Wang, Z. Hu, “Mesostructured carbon-based nanocages: an advanced platform for energy chemistry” Sci. China Chem. 65(2020)665;
41. Q. M. Ma, Y. J. Yao, M. L. Yan, J. Zhao, C. X. Ge, Q. Wu, L. J. Yang, X. Z. Wang, Z. Hu, “Effective enhancement of electrochemical energy storage of cobalt-based nanocrystals by hybridization with nitrogen-doped carbon nanocages” Sci. China Mater. 62(2019)1393;
42. Y. L. Zhang, J. Cai, Q. Wu, X. Z. Wang, L. J. Yang, C. Y. He, Z. Hu, “Phase-equilibrium-dominated vapor-liquid-solid mechanism: further evidence” Sci. China Mater. 59(2016)20;
43. S. Chen, L. W. Wang, Q. Wu, X. Li, Y. Zhao, H. W. Lai, L. J. Yang, T. Sun, Y. Li, X. Z. Wang, Z. Hu, “Advanced non-precious electrocatalyst of the mixed valence CoOx nanocrystals supported on N-doped carbon nanocages for oxygen reduction” Sci. in China B 58(2015)180.

代表性奖励荣誉情况

1,施毅; 潘力佳; 王欣然; 胡征; 濮林,“若干低维半导体表界面调控及器件基础研究”, 国家自然科学奖二等奖 (证书号:2017-Z-107-2-04-R04), 2017年,中华人民共和国国务院授奖。
2,胡征,江苏省青年科学家奖,2006年,青团江苏省委、中共江苏省委组织部、江苏省科技厅、江苏省人事厅、江苏省信息产业厅、中科院南京分院、江苏省青年联合会 联合授奖。
3,陈懿,胡征、沈俭一、范以宁、夏元复、夏文生、李智渝,“纳米非晶合金催化剂的化学制备、表征及性能研究”,江苏省科学技术进步奖二等奖(证书号:2-68-2 ),2000年,江苏省科学技术进步奖评审委员会授奖。
4,胡征,中国化学会青年化学奖(证书号:化奖字第107号),1997年,中国化学会授奖。

*以上信息由会士个人更新和维护。