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肖丰收

男, 浙江大学化工与生物工程学院

专业领域

沸石分子筛;催化化学;纳米材料;环境化学

学习/工作经历

1979-1983年在吉林大学获得理学学士学位;
1983-1986年在吉林大学获得理学硕士学位;
1986-1990年获得理学博士学位(吉林大学、大连化物所以及日本北海道大学联合培养)。
1990-1992年吉林大学讲师;
1992-1996年吉林大学副教授;
1993-1994年美国加州大学Davis分校博士后;
1996-2009年吉林大学教授
2009-至今浙江大学教授

学术成就和学术贡献简述

本人长期致力于沸石分子筛的合成与催化性能研究。在分子筛合成过程中,有机模板剂和大量的水的使用往往导致大量的三废排放。被提名人发现,沸石成核活化能远高于生长活化能,有机模板的主要功能是诱导自发成核,因此提出了无有机模板合成沸石的新概念,即起始凝胶中加入微量目标沸石分子筛晶种,替代成本昂贵且污染环境的有机模板剂合成沸石。采用该路线,实现了无有机模板条件下制备出优质富铝Beta沸石的工业化生产。为了解决沸石合成中大量溶剂带来的问题,提出了原料直接固相晶化的方法:即使用固体起始原料,在合成过程中完全不加入水,在适当温度下晶化。按照该理论,实现了无溶剂合成工业上广泛应用的沸石分子筛。另外,金属纳米颗粒但苛刻的反应条件往往导致颗粒聚集,从而失去它们的催化活性。针对该难题,被提名人通过金属纳米颗粒与沸石晶体作用的调控,将金属纳米颗粒镶嵌在沸石晶体的内部,沸石结构的刚性阻止了金属纳米颗粒的聚集,制备出高稳定性和长寿命的全新催化材料。将这些催化材料疏水化,引入“分子围栏”的新概念,实现了甲烷到甲醇的低温转化。将孤立金属物种引入到沸石结构中,金属物种与沸石协同催化,实现了低碳烷烃向低碳烯烃的高效转化。

化学公益贡献简述

从2004年至今作为亚太催化协会的秘书长,参与并组织亚太催化协会的学术交流;作为会议主席,组织了2014年在杭州举办的第十七届全国催化大会;作为会议主席,组织了2019年在杭州举办的第20届全国分子筛大会;作为会议主席,组织了2017年在杭州举办的全国环境催化与环境材料学术会议。

代表性成果

发表论文500余篇,下面为代表性论文40篇和10篇国内代表性论文:

1. H. Zhou, X. F. Yi, Y. Hui, L. Wang*, W. Chen, Y. C. Qin, M. Wang, J. B. Ma, X. F. Chu, Y. Q. Wang, X. Hong, Z. F. Chen, X. J. Meng*, H. Wang, Q. Y. Zhu, L. J. Song, A. M. Zheng*, F.-S. Xiao*, Isolated boron in zeolite for oxidative dehydrogenation of propane, Science, 372, 2021, 76-80.

2. Z. Jin, L. Wang*, E. Zuidema, K. Mondal, M. Zhang, J. Zhang, C. T. Wang, X. J. Meng, Q. H. Yang, C. Mesters, F.-S. Xiao*, Hydrophobic zeolite modification for in situ peroxide formation in methane oxidation to methanol, Science, 367, 2020, 193-197.

3. J. Zhang, L. Wang*, B. Zhang, H. Zhao, U. Kolb, Y. Zhu, L. Liu, Y. Han, G. Wang, C. Wang, D. S. Su, B. C. Gates & F.-S. Xiao*, Sinter-resistant metal nanoparticle catalysts achieved by immobilization within zeolite crystals via seed-directed growth, Nature Catal. 1, 2018, 540-546.

4. H. Wang, L. Wang*, D. Lin, X. Feng, Y. M. Niu, B. S. Zhang, F.-S. Xiao*, Strong metal-support interactions on gold nanoparticle catalysts achieved through Le Chatelier's principle, Nature Catal., 4, 2021, 418-424.

5. Z. Y. Yang, H. Li, H. Zhou, L. Wang,* L. X. Wang, Q. Y. Zhu, J. P. Xiao*, X. J. Meng, J. X. Chen, F.-S. Xiao*, Coking-resistant iron catalyst in ethane dehydrogenation achieved through siliceous zeolite modulation, J. Am. Chem. Soc., 142, 2020,16429-16436.

6. Lei, C., Dong, Z., Martinez, C., Martinez-Triguero, J., Chen, W., Wu, Q.*, Meng, X., Parvulescu, A.-N.*, De Baerdemaeker, T., Muller, U., Zheng, A., Ma, Y.*, Zhang, W., Yokoi, T., Marler, B., De Vos, D.E., Kolb, U., Corma, A. and Xiao, F.-S.*, A cationic oligomer as an organic template for direct synthesis of aluminosilicate ITH zeolite, Angewandte Chemie International Edition, 59, 2020,15649-15655.

7. Wang, C.; Zhang, J.; Qin, G.; Wang, L.*; Zuidema, E.; Yang, Q.; Dang, S.; Yang, C.; Xiao, J.; Meng, X.; Mesters, C.; Xiao, F.-S. Direct Conversion of Syngas to Ethanol within Zeolite Crystals, Chem 6 (3), 2020, 646–657..

8. Wang, S.; Sun, Q.; Chen, W.; Tang, Y.; Aguila, B.; Pan, Y.; Zheng, A.; Yang, Z.; Wojtas, L.; Ma, S.*; Xiao, F.-S.*, Programming Covalent Organic Frameworks for Photocatalysis: Investigation of Chemical and Structural Variations, Matter 2(2), 2020, 416–427.

9. Wang, L.; Guan, E.; Wang, Y.; Wang, L.*; Gong, Z.; Cui, Y.; Meng, X.; Gates, B. C.*; Xiao, F.-S.*, Silica Accelerates the Selective Hydrogenation of CO2 to Methanol on Cobalt Catalysts. Nat Commun, 11 (1), 2020,1-9.

10. Dong, K.; Sun, Q.*; Tang, Y.; Shan, C.; Aguila, B.; Wang, S.; Meng, X.; Ma, S.; Xiao, F.-S.*, Bio-Inspired Creation of Heterogeneous Reaction Vessels via Polymerization of Supramolecular Ion Pair, Nat. Commun. 10(1), 2019, 3059.

11. Wang, C.; Guan, E.; Wang, L.*; Chu, X.; Wu, Z.; Zhang, J.; Yang, Z.; Jiang, Y.; Zhang, L.; Meng, X.; Gates, B. C.*; Xiao, F.-S.*, Product Selectivity Controlled by Nanoporous Environments in Zeolite Crystals Enveloping Rhodium Nanoparticle Catalysts for CO2 Hydrogenation. J. Am. Chem. Soc. 141 (21), 2019, 8482-8488.

12. Zhang, J.; Wang, H.; Wang, L.*; Ali, S.; Wang, C.; Wang, L.; Meng, X.; Li, B.; Su, D. S.; Xiao, F.-S.*, Wet-Chemistry Strong Metal–Support Interactions in Titania-Supported Au Catalysts. J. Am. Chem. Soc. 141 (7), 2019, 2975–2983.

13. Q. Wu, X. Meng*, X. Gao, F.-S. Xiao*, Solvent-Free Synthesis of Zeolites: Mechanism and Utility, Acc. Chem. Res. 51, 2018, 1396-1403.

14. L. Wang, E. Guan, J. Zhang, J. Yang, Y. Zhu, Y. Han, M. Yang, C. Cen, G. Fu*, B. C. Gates*, F.-S. Xiao*, Single-site catalyst promoters accelerate metalcatalyzed nitroarene hydrogenation, Nature Commun. 9, 2018, 1362.

15. Q. Sun, S. Wang, B. Aguila, X. Meng, S. Ma*, F.-S. Xiao*, Creating solvation environments in heterogeneous catalysts for efficient biomass conversion, Nature Commun. 9, 2018, 3236.

16. L. Wang, S. Xu, S. He, F.-S. Xiao*, Rational construction of metal nanoparticles fixed in zeolite crystals as highly efficient heterogeneous catalysts, Nano Today, 20, 2018, 74-83.

17. L. Wang, L. Wang*, X. Liu, H. Wang, W. Zhang, Q. Yang, J. Ma, X. Dong, S. J. Yoo, J.-G. Kim, X. Meng, and F.-S. Xiao*, Selective hydrogenation of CO2 into ethanol over cobalt catalysts, Angew. Chem. Int. Ed., 57, 2018, 6104-6108.

18. L. Wang*, G. Wang, J. Zhang, C. Bian, X. Meng, and F.-S. Xiao*, Controllable cyanation of carbon-hydrogen bonds by zeolite crystals over manganese oxide catalyst, Nature Commun., 8, 2017,15240.

19. J. Zhang, L. Wang*, Y. Shao, Y. Wang, B. C. Gates, F.-S. Xiao*, Product Selectivity Controlled by Steric Adsorption in Zeolite Micropores over a Pd@Zeolite Catalyzed Hydrogenation of Nitroarene, Angew. Chem. Int. Ed. 56, 2017, 9747-9751.

20. Q. Sun, H. He, W.-Y. Gao, B. Aguila, L. Wojtas, Z. Dai, J. Li, Y.-S. Chen, F.-S. Xiao*, S. Ma*, Imparting Amphiphobicity on Single-Crystalline Porous Materials, Nature. Commun. 7, 2016, 13300.

21. C. Wang, L. Wang*, J. Zhang, H. Wang, J. P. Lewis, and F.-S. Xiao*, Product Selectivity Controlled by Zeolite Crystals in Biomass Hydrogenation over a Palladium Catalyst, J. Am. Chem. Soc. 138, 2016, 7880-7883.

22. N. Sheng, Y. Chu, S. Xin, Q. Wang, X. Yi, Z. Feng, X. Meng*, X. Liu*, F. Deng, and F.-S. Xiao*, Insights of the Crystallization Process of Molecular Sieve AlPO4-5 Prepared by Solvent-free Synthesis, J. Am. Chem. Soc. 138, 2016, 6171-6176.

23. L. Wang, Y. Zhu, J.-Q. Wang, F. Liu, J. Huang, X. Meng, J.-M. Basset, Y. Han, F.-S. Xiao*, Two-dimensional gold nanostructures with high activity for selective oxidation of carbon-hydrogen bonds, Nature Commun. 6, 2015, 6957.

24. Q. Wu, X. Liu, L. Zhu, L. Ding, P. Gao, X. Wang, S. Pan, C. Bian, X. Meng*, J. Xu, F. Deng, S. Maurer, U. Müller, F.-S. Xiao*, Solvent-free Synthesis of Zeolites from Anhydrous Starting Raw Solids, J. Am. Chem. Soc. 137, 2015, 1052-1055.

25. Q. Sun, Z. Dai, X. Liu, N. Sheng, F. Deng, X. Meng, and F.-S. Xiao*, Highly Efficient Heterogeneous Hydroformylation over Rh-Metalated Porous Organic Polymers: Synergistic Effect of High Ligand Concentration and Flexible Framework, J. Am. Chem. Soc. 137, 2015, 5204-5209.

26. X., Meng, F.-S. Xiao*, Green Routes for Synthesis of Zeolites, Chem. Rev. 114, 2014, 1521-1543

27. J. Zhu, Y. Zhu, L. Zhu, M. Rigutto, A. van der Made, C. Yang, S. Pan, L. Wang, L. Zhu, Y. Jin, Q. Sun, Q. Wu, X. Meng*, D. Zhang, Y. Han*, J. Li, Y. Chu, A. Zheng, S. Qiu*, X. Zheng, and F.-S. Xiao*, Highly Mesoporous Single-Crystalline Zeolite Beta Synthesized Using a Non-surfactant Cationic Polymer as a Dual-Function Template, J. Am. Chem. Soc. 136, 2014, 2503-2510.

28. Q. Wu, X. Wang, G. Qi, Q. Guo, S. Pan, X. Meng*, J. Xu, F. Deng, F. Fan, Z. Feng, C. Li*, S. Maurer, U. Müller, F.-S. Xiao*, Sustainable Synthesis of Zeolites without Addition of both Organotemplates and Solvents, J. Am. Chem. Soc. 136, 2014, 4019-4025.

29. Y. Jin, Q. Sun, G. Qi, C. Yang, J. Xu, F. Chen, X., Meng*, F. Deng, F.-S. Xiao*, Solvent-Free Synthesis of Silicoaluminophosphate Zeolites, Angew Chem. Int. Ed. 52, 2013, 9172-9175.

30. Q. Sun, Y. Jin, L. Zhu, L. Wang, X. Meng*, F.-S. Xiao*, Superhydrophobic, Chiral, and Mesoporous TsDPEN Copolymer Coordinated to Ruthenium Species as an Efficient Catalyst for Asymmetric Transfer Hydrogenation, Nano Today 8, 2013, 342-350.

31. T. Tang*, L. Zhang, W. Fu, Y. Ma, J. Xu, J. Jiang, G. Fang, F.-S. Xiao*, Design and Synthesis of Metal Sulfide Catalysts Supported on Zeolite Nanofiber Bundles with Unprecedented Hydrodesulfurization Activities, J. Am. Chem. Soc. 135, 2013, 11437-11440.

32. F. Liu, L. Wang, Q. Sun, L. Zhu, X. Meng, and F.-S. Xiao*, Transesterification Catalyzed by Ionic Liquids on Superhydrophobic Mesoporous Polymers: Heterogeneous Catalysts That Are Faster than Homogeneous Catalysts, J. Am. Chem. Soc. 134, 2012,16948-16950.

33. L. Ren, Q. Wu, C. Yang, L. Zhu, C. Li, P. Zhang, H. Zhang, X. Meng*, and F.-S. Xiao*, Solvent-Free Synthesis of Zeolites from Solid Raw Materials, J. Am. Chem. Soc. 134, 2012,15173-15176.

34. F. Liu, T. Willhammar, L. Wang, L. Zhu, Q. Sun, X. Meng, W. Carrillo-Cabrera, X. Zou*, and F.-S. Xiao*, ZSM-5 Zeolite Single Crystals with b-Axis-Aligned Mesoporous Channels as an Efficient Catalyst for Conversion of Bulky Organic Molecules, J. Am. Chem. Soc. 134, 2012, 4557-4560.

35. W. Fu, L. Zhang, T. Tang*, Q. Ke, S. Wang, J. Hu, G. Fang, J. Li, F.-S. Xiao*, Extraordinarily High Activity in the Hydrodesulfurization of 4,6-Dimethyldibenzothiophene over Pd Supported on Mesoporous Zeolite Y, J. Am. Chem. Soc. 133, 2011, 15346-15349.

36. Y. Zhang, L. Guo, S. Wei, Y. He, H. Xia, Q. Chen, H.-B. Sun, F.-S. Xiao*, Direct imprinting of microcircuits on graphene oxides film by femtosecond laser reduction, Nano Today 5, 2010, 15-20.

37. B. Xie, J. Song, L. Ren, Y. Ji, J. Li, F.-S. Xiao*, Organotemplate-free and fast route for synthesizing Beta zeolite, Chem. Mater. 20, 2008, 4533-4535.

38. F.-S. Xiao*, L. Wang, C. Yin, K. Lin, Y. Di, J. Li, R. Xu, D. Su, R. Schlogl, T. Yokoi, T. Tatsumi, Catalytic properties of hierarchical mesoporous zeolites templated with a mixture of small organic ammonium salts and mesoscale cationic polymers, Angew. Chem. Int. Ed. 45, 2006, 3090-3093.

39. Y. Han, D. Li, L. Zhao, J. Song, N. Li, Y. Di, C. Li, S. Wu, X. Xu, X. Meng, K. Lin, and F.-S. Xiao*, High-temperature generalized synthesis of stable ordered mesoporous silica-based materials by using fluorocarbon-hydrocarbon surfactant mixtures, Angew. Chem. Int. Ed. 43, 2004, 3633-3637.

40. F.-S. Xiao*, Y. Han, Y. Yu, X. Meng, M. Yang, and S. Wu, Hydrothermally stable ordered mesoporous titanosilicates with highly active catalytic sites, J. Am. Chem. Soc. 124, 2002, 888-889.

41. L. Ren, Y. B. Zhang, S. J. Zeng, L. F. Zhu, Q. Sun, H. Y. Zhang, C. G. Yang, X. J. Meng, F.-S. Xiao*, Design and Synthesis of a Catalytically Active Cu-SSZ-13 Zeolite from a Copper-Amine Complex Template, Chinese J. Catal., 33, 2012, 92-105.

42. H. M. Luan, C. Lei, Y. Ma, Q. M. Wu*, L. F. Zhu, H. Xu, S. C. Han, Q. Y. Zhu, X. L. Liu*, X. J. Meng, F.-S. Xiao*, Alcohol-assisted synthesis of high-silica zeolites in the absence of organic structure-directing agents, Chinese J. Catal., 42, 2021, 563-570.

43. H. Wang, Q. S. Luo, L. Wang*, Y. Hui, Y. C. Qin, L. J. Song, F.-S. Xiao*, Product selectivity controlled by manganese oxide crystals in catalytic ammoxidation, Chinese J. Catal., 42, 2021, 2164-2172.

44. J. Zhang, Y. Y. Chu, X. L. Liu, H. Xu, X. J. Meng*, Z. C. Feng*, F.-S. Xiao*, Interzeolite transformation from FAU to CHA and MFI zeolites monitored by UV Raman spectroscopy, Chinese J. Catal., 40, 2019, 1854-1859.

45. L. Wang, X. J. Meng, F.-S. Xiao*, Au Nanoparticles Supported on a Layered Double Hydroxide with Excellent Catalytic Properties for the Aerobic Oxidation of Alcohols, Chinese J. Catal., 31, 2010, 943-947.

46. B. Sun, X. J. Meng, S. C. Wang, S. Q. Sun, F.-S. Xiao*, High-throughput screening in heterogeneous reaction using chemical indicators, Chinese J. Catal., 26, 2005, 349-351.

47. L. Zhang, Y. X. Peng, J. Zhang, L. Chen, X. J. Meng*, F.-S. Xiao*, Adsorptive and catalytic properties in the removal of volatile organic compounds over zeolite-based materials, Chinese J. Catal., 37, 2016, 800-809.

48. C. T. Wang, W. Fang, L. Wang*, F.-S. Xiao*, Fischer-Tropsch reaction within zeolite crystals for selective formation of gasoline-ranged hydrocarbons, J. Energy Chem., 54, 2021, 429-433.

49. L. Wang, J. Zhang, L. F. Zhu, X. J. Meng, F.-S. Xiao*, Efficient conversion of fructose to 5-hydroxymethylfurfural over sulfated porous carbon catalyst, J. Energy Chem., 22, 2013, 241-244.

50. Q. Sun, L. F. Zhu, Z. H. Sun, X. J. Meng*, F.-S. Xiao*, Porous polymer supported palladium catalyst for cross coupling reactions with high activity and recyclability, Sci. China Chem., 55, 2012, 2095-2103.


授权专利60余项,下面给出代表性专利3项:

1. 孟祥举,孙琦,肖丰收;多孔聚三苯基膦材料的制备方法;申请年份:2013年、申请号: CN201310235002.4;批准年份:2015、专利号:CN201310235002。

2. 肖丰收,任利敏,朱龙凤,杨承广,孟祥举;以铜胺络合物作为模板剂合成硅基分子筛的方法;申请年份:2010年、
申请号: CN201010280650.8;批准年份:2012、专利号:CN201010280650。

3. 肖丰收,任利敏,吴勤明,孟祥举,杨承广,朱龙凤;通过固相原料研磨无溶剂条件下合成分子筛的方法;申请年份:2012年、申请号: CN201210118788.7;批准年份:2014年、专利号:CN201210118788。


3篇代表性专著如下:

1. Feng-Shou Xiao and Xiangju Meng, Zeolites in Sustainable Chemistry, Springer, 2016, Berlin.

2. Feng-Shou Xiao and Liang Wang, Nanoporous catalysts for biomass conversion, Wiley, 2018, Oxford.

3. 肖丰收、孟祥举, 沸石分子筛的绿色合成,科学出版社, 2019, 北京。

代表性奖励荣誉情况

1. 肖丰收;第三届中国分子筛成就奖;2021、中国分子筛专业委员会。

2. 肖丰收、孟祥举、王亮;分子筛催化材料的设计合成与绿色制备,浙江省技术发明一等奖;2019、浙江省。

3. 肖丰收、孟祥举、孙建敏、孙印勇、王利丰;高水热稳定和高催化活性的介孔材料及其功能化的研究,教育部自然科学二等奖;2008、教育部。

4. 肖丰收、徐如人;由羰基原子簇化合物制备的担载高分散金属催化材料研究,国家教育委员会科技进步二等奖;1996、国家教育委员会。

*以上信息由会士个人更新和维护。