张俊良

男， 复旦大学化学系

专业领域

有机合成反应方法学，不对称催化，手性配体的设计

学习/工作经历

• 1993年9月－1997年7月，天津大学化学系学习，应用化学专业，理学学士
• 1997年9月－2002年7月，中国科学院上海有机化学研究所, 有机化学专业, 理学博士, 师从麻生明院士
• 2002年8月-2003年10月, 中国科学院上海有机化学研究所工作, 研究助理。
• 2003年11月－2005年1月，德国科隆大学化学系，洪堡学者, 师从H. G. Schmalz教授
• 2005年2月－2006年10月，美国芝加哥大学化学系，研究助理。师从何川教授
• 2006年12月－2017年9月，华东师范大学化学系，教授，博导。
• 2017年10月－至今，复旦大学化学系，教授，博导。

学术成就和学术贡献简述

研究方向聚焦有机合成方法学，涵盖烯炔与小环化学及不对称催化领域。基于理想催化剂IDEAL设计理念，开发出非C2对称性、刚柔并济的新型自适应性手性催化剂Sadphos（赛德福仕）。目前400余种Sadphos已在国内外试剂公司销售，被30多个国家的200余个课题组借鉴使用。项目紧扣国家科技强国战略，与百余家院校科研单位、化工企业开展合作，从源头打破技术壁垒，助力手性医药、农药及材料等领域发展。 凭借手性催化剂与不对称反应等开创性成果，发表论文280余篇，其中70余篇发表于JACS、ACIE等顶刊，撰写英文章节8章，主编及联合主编英文专著2本。同时，获授权发明专利30余项，转让11项。 个人荣获上海市自然科学一等奖、国家杰出青年基金资助，入选科技部中青年创新领军人才、教育部创新团队学术带头人、上海市东方学者（跟踪）、上海市领军人才等计划。兼任中国化学会第三届手性化学专业委员会、第一届磷化学及工艺化学专业委员会委员，《Green Synthesis & Catalysis》副主编，《有机化学》《化学学报》编委。先后主持科技部重点研发项目1项、基金委重点项目1项及973项目子课题等。

化学公益贡献简述

本研究团队深耕化学领域十数年，以学术创新为核心，在学科发展、科学传播、学会建设及国际交流中成效卓著。
在科学传播与形象提升方面，通过“名师名家讲坛"等平台开展学术报告，向师生普及不对称催化前沿知识，分享科研思路与突破历程，激发青年科研热情。主编学术专著《Chiral Phosphorous Based Ligand In Earth-Abundant Transition Metal Catalysi》，担任《Green Synthesis & Catalysis》副主编，《有机化学》和《化学学报》编委，将复杂化学原理系统化呈现，助力化学学科的知识传承与普及。
作为会议主席，牵头举办十余场化学、化工与医药领域全国性及区域性学术会议（含中西部地区场次），如2025化学化工新质生产力高峰论坛、2025药物与合成化学前沿论坛、第一届全国有机化学化工产学研会议等。每场会议均汇聚院士、长江学者、国家杰青等顶尖专家学者，参会人数超200人，成功搭建高效学术研讨与交流平台。
在中国化学会发展中，作为手性化学、磷化学及工艺化学专业委员，积极参与学科规划与学术交流组织，推动学科领域的协同发展。

代表性成果

一、论文：
1. Chun Ma, Xinyue Wang, Tibor Soós, Junliang Zhang*, Junfeng Yang*. Ligand-controlled regiodivergent and enantioselective hydrophosphorylation of styrenes by palladium. Nat. Commun. 2025, 16, 5436.
2. Yin Yuan, Xinyu Tian, Hongxia Zheng, Yuze Li, Junliang Zhang,* and Junfeng Yang.* Catalvtic Enantioselective Reductive Arvlation and Alkenylationof sulfinylamines to Access Sulfinamides Enabled by CobaltCatalysis. Angew, Chem. Int. Ed. 2025, 64, e202506243.
3. Chenghao Zhu, Zihao Ye, Haining Wang, Da Ma, Zhiming Li*, Chao-Jun Li, Junliang Zhang*. Chiral ruthenium complex/Ph2P(2-furyl)-catalyzedasymmetric nucleophilitc addition of ary aldehydehydrazones to simple ketones. Sci. Adv. 2025, 11, eadv0095.
4. Li-Zhi Zhang, Pei-Chao Zhang, QianWang, Min Zhou*, and Junliang Zhang*. Enantioselective Heck/Tsuji-Trost reaction of flexible vinylic halides with 1,3-dienes. Nat Commun. 2025, 16, 930.
5. Zhaoqiang Chen, Huanan Wang, Ping Du, Jiaao Zhao, Xue Zhang,* Hui Qian,* Junliang Zhang,* and Shengming Ma*. DACH-ZYC-Phos/Pd-Catalyzed Enantioselective Allenylation of Secondary Phosphine Oxides via Ligand Relay. J. Am. Chem. Soc. 2025, 147, 24958−24968.
6. Bing Xu, Danting Ji, Zhan-Ming Zhang,* Junliang Zhang*. Remote C-H Bond Activation via Enantioselective Carbopalladation and 1,4-Pd Migration Cascade Process. Adv. Sci. 2024, 11, 2406443.
7. Kangning Cao, jie Han, Wenshao Ye, Dejun Hu, Zihao Ye, Junfeng Yang,* Junliang Zhang,* and Fener Chen*. Enantioselective Aminosilylation of Alkenes by Palladium/Ming-Phos-Catalyzed Tandem Narasaka-Heck/silylation Reaction. Adv. Sci. 2024, 11. 2403470.
8. Jinrong Wang, Bing Xu, Yibo Wang, Guangzhen Xia, Zhan-Ming Zhang*, and Junliang Zhang*. Pd-Catalyzed Enantioselective Three-Component Carboaminationof 1,3-Cyclohexadiene. J Am. Chem. Soc. 2024, 146, 21231-21238.
9. Yin Yuan, Yidan Han, Zhi-kun Zhang, Shilin Sun, Ke Wu, Junfeng Yang*, and Junliang Zhang*. Enantioselective Arylation of Sulfenamides to Access SulfiliminesEnabled by Palladium Catalysis. Angew. Chem. Int. Ed. 2024, 63, e202409541.
10. Yixiang Shi, Yin Yuan, Jianhui Li, Junfeng Yang*, and Junliang Zhang*. Catalytic Asymmetric synthesis of sulfinamides via Cu-Catalyzed Asymmetric Addition of Aryl Boroxines to sulfinylamines. J. Am. Chem. Soc. 2024, 146, 17580-17586.
11. Qiaojing Meng, Yinggao Meng, Qinglin Liu, Bing Yu, Zhong-Jun Li, Er-Qing Li*, Junliang Zhang*. Enantioselective Synthesis of Oxazocines via MQ-Phos Enabled Palladium-Catalyzed Asymmetric Formal [4+4]-Cycloadditions. Adv Sci. 2024, 11, 2402170.
12. Jin-Lan Zhou, Yuaniu Xiao, Linke He, Xin-yu Gao, Xue-Chun Yang, Wen-Biao Wu, Guogiang Wang, Junliang Zhang*, and Jian-Jun Feng*. Palladium-Catalyzed ligand-Controlled switchable Hetero-(5+3)/Enantioselective [2σ+2σ] Cycloadditions of Bicyclobutanes with Vinyl Oxiranes. J. Am. Chem. Soc. 2024, 146, 19621-19628.
13. Qi Pan, Kuai Wang, Weipeng Xu, Yugi Ai, yuanyuan Ping, chuhan Liu, Minyan Wang*, Junliang Zhang*, and Wangging Kong*. Ligand-Controlled, Nickel-Catalyzed Stereodivergent Construction of 1,3-Nonadjacent Stereocenters. J. Am. Chem. Soc. 2024, 146, 15453-15463.
14. Genwei Zhang, Bin Yang, Junfeng Yang*, and Junliang Zhang*. Pd-Catalyzed Asymmetric Larock Indole Synthesis to Access Axially Chiral N-Arylindoles. J. Am. Chem. Soc. 2024, 146, 5493-5501.
15. Lei Wang*, Yingiang Wang, Shualie Wu, Chao-Guo Yan, Chaoshen Zhang*, Junliang Zhang*, and Ying Han*. Enantioselective synthesis of lsoindolinone by Palladium-Catalyzed Aminoalkynylation of 0-Phenyl Hydroxamic Ethers with Alkynes. J. Am. Chem. Soc. 2024, 146, 4320-4326.
16. Wenbo Li and Junliang Zhang*. Sadphos as Adaptive Ligands in Asymmetric Palladium Catalysis. Acc. Chem. Res. 2024, 57, 489-513.
17. Shuai Zhu, Zihao Ye, Ming-Jie Chen, Lei Wang, Yu-Zhuo Wang, Ke-Nan Zhang, Wen-Bo Li, Han-Ming Ding, Zhiming Li*, Junliang Zhang*. Mechanistic study on the side arm effect in a palladium/Xu-Phos-catalyzed enantioselective alkoxyalkenvlation of γ-hvdroxvalkenes. Nat. Commun. 2023, 14, 7611.
18. Shutao Qi, Wenshao Ye, Yunkai Hua, Liangkai Pan, Junfeng Yang*, and Junliang Zhang*. Ligand-enabled palladium-catalysed enantioselective synthesis of a-quaternary amino and glycolic acids derivatives. Nat. Synth. 2024, 3, 357–367.
19. Jie Han, Siyuan Liu, Huanan Wang, Jie Wang, Hui Qian, Zhiming Li*, Shengming Ma*, Junliang Zhang*. Pd/Xu-Phos-catalyzed asymmetric elimination of fully substituted enol triflates into axially chiral trisubstituted allenes. Sci. Adv. 2023, 9, 1002.
20. Shuting Zhang, shuaiie Wu, Qiang Wang, shii Xu, Ying Han, Chao-Guo Yan, Junliang Zhang*, Lei Wang*. Enantioselective Synthesis of Dihydropyrazoles by Palladium/Xu-Phos-Catalyzed Aleneamination of ,γ-Unsaturated Hydrazones with Propargylic Acetates. Angew Chem. Int. Ed. 2023, 62, e202300309.
21. Shiquan Gao, Chen Wang, Junfeng Yang* and Junliang Zhang*. Cobalt-catalyzed enantioselective intramolecular reductive cyclization via electrochemistry. Nat. Commun. 2023, 14, 1301.
22. Youshao Tu, Bing Xu, Qian Wang, Honglin Dong, Zhan-Ming Zhang*, Junliang Zhang*. Palladium/TY-Phos-Catalyzed Asymmetric Heck/Tsuji-Trost Reaction of o-Bromophenols with 1,3-Dienes. J. Am. Chem. Soc. 2023, 145, 4378–4383.
23. Ronghua Zhang, Shan Xu, Zhou Luo, Yuanyuan Liu,* and Junliang Zhang*. Enantiodivergent Hvdrogenation of Exocyclic ,-Unsaturated Lactams Enabled by switching the N-chirality of lridium Catalyst. Angew. Chem. Int. Ed. 2023, e202213600.
24. Chun Ma, Yue Sun, Junfeng Yang*, Hao Guo*, and Junliang Zhang*. Catalytic Asymmetric Synthesis of Tröger’s Base Analogues with Nitrogen Stereocenter. ACS Cent. Sci. 2023, 9, 64–71.
25. Juan Feng, jiayi Shi, Lan Wei, Mingqing Liu, Zhiming Li,* Yuanjing Xiao* and Junliang Zhang*. Palladium/PC-Phos-Catalyzed Asymmetric Heck/Tsuji-Trost Reactions of Amino-Tethered 1,3-Cyclohexadiene with Aryl and Alkenyl Halides. Angew. Chem. Int. Ed. 2022, e202215407.
26. Wenge Zhang, Pei-Chao Zhang, Yin-Lin Li, Hai-Hong Wu, and Junliang Zhang*. PC-Phos Enabled Catalytic Palladium-heteroallyl Asymmetric Cycloaddition. J. Am. Chem. Soc. 2022, 144, 19627-19634.
27. Wenya Feng, Yuanjing Xiao, Chuanfang Zhao, Zhanming Zhang, Wei liu, juan Ma, Tomas Ganz, Junliang Zhang*, Sijin Liu*. New Deferric Amine Compounds Efficiently Chelate Excess lron to Treat lron Overload Disorders and to Prevent Ferroptosis. Adv Sci, 2022, 9, 2202679.
28. Huanan Wang, Hui Qian*, Junliang Zhang*, and Shengming Ma*. Catalytic Asymmetric Axially Chiral Allenyl C-P Bond Formation. J. Am. Chem. Soc. 2022, 144, 12619-12626.
29. Bin Yang, Kangning Cao, Guofeng Zhao, Junfeng Yang*, and Junliang Zhang*. Pd/Ming-Phos-Catalvzed Asymmetric Three-Component Arylsilvlation of N-sulfonyhydrazones: nantioselective synthesis of gem-Diarylmethine silanes. J. Am. Chem. Soc. 2022, 144, 15468-15474.
30. Wenjun Luo, Li-Ming Zhang, Zhan-Ming Zhang, Junliang Zhang*. Synthesis of W-Phos ligand and Its Application in the Copper-Catalyzed Enantioselective Addition of linear Grignard Reagents to Ketones. Angew. Chem. Int. Ed. 2022, 61, e202204443.
31. Sanliang Lit, Qiaoyu Chent, Junfeng Yang*, Junliang Zhang*. Palladium-Catalyzed Enantioselective y-Arylation of β,γ-Unsaturated Butenolides. Angew. Chem. Int. Ed. 2022, 61, e202202046.
32. Bing Xu, Danting Ji, Lizuo Wu, Lujia Zhou, Yu Liu, Zhan-Ming Zhang*, Junliang Zhang*. Palladium/Xu-Phos-catalyzed enantioselective cascade Heck/remote C(Sp2)-H alkylation reaction. Chem. 2022, 8, 836-849.
33. Qiang Dai, Lu Liu,* Junliang Zhang*. Palladium/Xiao-Phos-Catalyzed Kinetic Resolution of sec-Phosphine Oxides by P-Benzylation. Angew. Chem. Int. Ed. 2021, 60, 27247.
34. Guofeng Zhao, Yi Wu, Hai-Hong Wu, Junfeng Yang*, and Junliang Zhang*. Pd/GF-Phos-Catalyzed Asymmetric Three-Component Coupling Reaction to Access chiral Diarylmethyl Alkynes. J. Am. Chem. Soc. 2021, 143, 17983-17988.
35. Yin-Lin Li, Pei-Chao Zhang, Hai-Hong Wu and junliang Zhang*. Palladium-Catalyzed Asymmetric Tandem Denitrogenative Heck/Tsuji-Trost of Benzotriazoles with 1,3-Dienes. J. Am. Chem. Soc. 2021, 143, 13010-13015.
36. Pei-Chao Zhang, Yin-Lin Li, jiafeng He, Hai-Hong Wu,* Zhiming Li* and Junliang Zhang*. Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation. Nat. Commun. 2021, 12, 4609.
37. Zhangjin Pan, Wenbo Li, Shuai Zhu, Feng Liu, Hai-Hong Wu, Junliang Zhang*. Palladium/TY-Phos-Catalyzed Asymmetric Intermolecular a-Arylation of Aldehydes with Aryl Bromides. Angew. Chem. Int. Ed. 2021, 60, 18542-18546.
38. Deyun Qian and Junliang Zhang*. Yne-Enones Enable Diversity-0riented Catalytic Cascade Reactions: A Rapid Assembly of Complexity. Acc. Chem. Res. 2020, 53, 2358-2371.
39. Tao-Yan Lin, Zhangjin Pan, Youshao Tu, shuai Zhu, Hai-Hong Wu, yu Liu, Zhiming Li,* Junliang Zhang*. Design and Synthesis of TY-Phos and Application in Palladium-Catalyzed Enantioselective fluoroarylation of gem-Difluoroalkenes. Angew. Chem., Int. Ed. 2020, 59, 22957-22962.
40. Haoke Chu, Jie Cheng, Junfeng Yang, Yin-Long Guo*, Junliang Zhang*. Asymmetric Dearomatization of Indole via Palladium/PC-Phos-Catalyzed Dynamic Kinetic Transformation. Angew. Chem. Int. Ed. 2020, 59, 21991-21996.
41. Lujia Zhou, Saniang Li, Bing Xu, Danting Ji, Lizuo Wu, Yu Liu, Zhan-Ming Zhang,* and Junliang Zhang*. Enantiselective Difunctionalization of Alkenes by a Palladium-Catalyzed Heck/Sonogashira Sequence. Angew. Chem. Int. Ed. 2020, 59, 2769-2775.
42. Qiang Dai, Lu Liu, Yanyan Qian, Wenbo Li, Junliang Zhang*. Construction of p-chiral Alkenylphosphine Oxides through Highly chemo-, Regio-, and Enantioselective Hydrophosphinylation of Alkynes. Angew. Chem. Int. Ed. 2020, 59, 20645-20650.
43. Lei Wang, Kenan Zhang, Yuzhuo Wang, Wenbo Li, Mingjie Chen, and Junliang Zhang*. Enantioselective synthesis of lsoxazolines Enabled by Palladium-Catalyzed Carboetherification of Alkenyl Oximes. Angew. Chem. Int. Ed. 2020, 59, 4421-4427.
44. Huanan Wang, Hongwen Luo, Zhan-Ming zhang, Wei-feng Zheng, Yu Yin, Hui Qian,* Junliang zhang*, and Shengming Ma*. Pd-Catalyzed Enantioselective Syntheses of Trisubstituted Allenes via Coupling of Propargylic Benzoates with Organoboronic Acids. J. Am. Chem. Soc. 2020, 142, 9763-9771.
45. Qiang Dai, Wenbo Li, Zhiming Li, Junliang Zhang*. P-Chiral Phosphines Enabled by Paladium/Xiao-Phos-Catalyzed Asymmetric P-C Cross-Coupling of secondary Phosphine Oxides and Aryl Bromides. J. Am. Chem, Soc. 2019, 141, 20556-20564.
46. Chenghao Zhu, Haoke Chu, Gen Li, Shengming Ma*, Junliang Zhang*. Pd-Catalyzed Enantioselective Heck Reaction of Aryl Triflates and Alkynes. J. Am. Chem. Soc. 2019, 141, 19246-19251.
47. Zhan-Ming Zhang, Bing Xu, Lizuo Wu, Yuanqi Wu, Yanyan Qian, Lujia Zhou, Yu Liu, Junliang Zhang*. Enantioselective Dicarbofunctionalization of Unactivated Alkenes by Palladium-Catalyzed Tandem Heck/Suzuki Coupling Reaction. Angew. Chem. Int. Ed. 2019, 58, 14653-14659.
48. Pei-Chao Zhang, Jie Han and Junliang Zhang*. Pd/PC-Phos-Catalyzed Enantioselective intermolecular Denitrogenative Cyclization of Benzotriazoles with Allenes and N-Allenamides. Angew. Chem. Int. Ed. 2019, 58, 11444-11448.
49. Zhan-Ming Zhang, Bing Xu, Lizuo Wu, Lujia Zhou, Danting ji, Yu Liu, Zhiming Li* and Junliang Zhang*. Palladium/XuPhos-Catalyzed Enantioselective Carboiodination of Olefin-Tethered Aryl lodides. J. Am. Chem, Soc. 2019, 141, 8110-8115.
50. Huamin Wang, Junyou Zhang, Youshao Tu and Junliang Zhang*. Phosphine-Catalyzed Enantioselective Dearomative [3+2]-Cycloaddition of 3-Nitroindoles and 2-Nitrobenzofurans. Angew. Chem. Int. Ed. 2019, 58, 5422-5426.
51. Huamin Wang, Li Zhang, Youshao Tu, Ruiqi Xiang, Yin-Long Guo* and Junliang Zhang*. Phosphine-Catalyzed Difunctionalization of B-fluoroalky a,p-Enones: A Direct Approach to -Amino -Diazo Carbonyl Compounds. Angew. Chem. Int. Ed. 2018, 57, 15787-15791.
52. Zhan-Ming Zhang, Bing Xu, Yanyan Qian, Lizuo Wu, Yuangi Wu, Lujia Zhou, Yu Liu and Junliang Zhang*. Palladium-Catalyzed Enantioselective Reductive Heck Reactions: Convenient Access to 3, 3-Disubstituted 2,3-Dihydrobenzofuran. Angew. Chem. Int. Ed. 2018, 57, 10373-10377.
53. Lei Wang, Mingjie Chen, Pei-chao Zhang, Wenbo Li and Junliang Zhang*. Palladium/PC-Phos-Catalyzed Enantioselective Arylation of General sulfenate Anions: Scope and Synthetic Applications. J. Am. Chem. Soc. 2018, 140, 3467-3473.
54. Shan Xu, Zhan-Ming Zhang, Bing Xu, Bing Liu, Yuanyuan Liu,* and Junliang Zhang*. Enantioselective Regiodivergent synthesis of Chiral pyrolidines with Two Quaterary Stereocenters via ligand-Controled Copperl-Catalyzed Asymmetric 1 3-Dipolar Cycloadditions. J. Am. Chem. Soc. 2018, 140, 2272-2283.
55. Yidong Wang, Pei-Chao Zhang, Xiaoyu Di, Qiang Dai, Zhan-Ming Zhang and junliang Zhang*. Gold-Catalyzed Asymmetric ntramolecular Cyclization of N-Allenamides for the Synthesis of chiral Tetrahydrocarbolines. Angew. Chem. Int. Ed., 2017, 56, 15905-15909.
56. Ben Ma, Zhaowei Chu, Ben Huang, Zhenli Liu, Lu Liu* and Junliang Zhang*. Highly para-Selective C-H Alkylation of Benzene Derivatives with 2,2,2-Trifluoroethyl -Aryl--Diazoesters. Angew. Chem. Int. Ed., 2017, 56, 2749-2753.
57. Chao-Ze Zhu, Jian-Jun Feng,* and Junliang Zhang*. Functionalized Azepines. Rhodium(l)-Catalyzed Intermolecular Aza-[4+3] Cycloaddition of vinyl Aziridines and Dienes: Atom-Economical synthesis of Enantiomerically Enriched. Angew. Chem. Int. Ed. 2017, 56, 1351-1355.
58. Yuanyuan Liu, Wenbo Li, Junliang Zhang*. Chiral ligands designed in China. Natl. Sci. Rev 2017, 4, 326-358.
59. Zhunzhun Yu, Yongfeng Li, Jiameng Shi, Ben Ma, Lu Liu and Junliang Zhang*. (C6F5)3B -Catalyzed Highly Chemoselective and Ortho-selective C-H Bond Functionalization of Phenols Oriented by Hydrogen Bonds. Angew. Chem. Int. Ed. 2016, 55, 14807-14811.
60. Peng Chen, Zhenting Yue, Junyou Zhang, Xi Ly, Lei Wang and Junliang Zhang*. Phosphine-Catalyzed Asymmetric Umpolung Addition of Trifluoromethyl Ketimines to Morita-Bavlis-Hillman Carbonates. Angew. Chem. Int. Ed. 2016, 55. 13316-13320.
61. Tao-Yan Lin, chao-Ze Zhu, Pei-Chao Zhang, Yidong Wang, Hai-Hong Wu, jian-Jun Feng*, Junliang Zhang*. Regiodivergent intermolecular [3 +2] Cycloadditions of Vinyl Aziridines and Allenes: stereospecific synthesis of Chiral PyrrolidinesAngew Chem. Int. Ed. 2016,55, 10844-10848.
62. Zhan-Ming Zhang, Bing Xu, Shan Xu, Hai-Hong Wu and Junliang Zhang*. Diastereo- and Enantioselective Copper(l-Catalyzed intemolecular [3+2] Cycloaddition of Azomethine Ylides with -Triuoromethyl, ,-Disubstituted Enones. Angew. Chem. Int. Ed, 2016, 55, 6324-6328.
63. Jian-Jun Feng, Tao-Yan Lin, Chao-Ze Zhu, Huamin Wang, Hai-Hong Wu and Junliang Zhang*. The Divergent synthesis of Nitrogen Heterocycles by Rhodium(I)-Catalyzed Intermolecular Cycloadditions of Vinyl Aziridines and Alkynes. J. Am. Chem. Soc. 2016, 138, 2178-2181.
64. Wenbo Li and Junliang Zhang*. Recent developments in the synthesis and utilization of chiral β-aminophosphine derivatives as catalysts or ligands. Chem. Soc. Rev. 2016, 45, 1657-1677.
65. Lu Liu* and Junliang Zhang*. Gold-catalyzed transformations of -diazocarbonyl compounds: selectivity and diversity. Chem. Soc. Rev 2016, 45, 506-516.
66. Jian-Jun Feng, Tao-Yan Lin, Hai-Hong Wu, and Junliang Zhang*. Modular Access to the tereoisomers of fused Bicyclic Azepines; Rhodium-CataNzed lintramolecular stereospecific Hetero-[5+2]addition of viny Aziridines and Alkenes. Angew. Chem. Int. Ed. 2015, 54, 15854-15858.
67. Wei Zhou, Xiao Su, Mengna Tao, Chaoze Zhu, Qingiie Zhao* and Junliang Zhang*. A Novel Chiral sulfinamide Bisphosphine catalysts: Design, synthesis, and Application in Highly Enantioselective intermolecular Cross Rauhut-Curier Reactions. Angew. Chem. Int. Ed. 2015, 54, 14853-14857.
68. Yidong Wang, Pei-Chao Zhang, Deyun Qian and Junliang Zhang*. Highly Regio-, Diastereo-, and Enantioselective Gold(l)-Catalyzed intermolecular Annulations with N-Allenamides at the Proximal C=C Bond. Angew. Chem. Int. Ed. 2015, 54, 14849-14852.
69. Liejin Zhou, Bing Xu and Junliang Zhang*. Metal-free Dehydrogenative Diels-Alder Reactions of 2-Methy, 3-Ary-methyl-indoles and Dienophiles: A Rapid Access to Tetrahydrocarbazoles, Carbazoles and Heteroacenes. Angew. Chem. Int. Ed. 2015, 54, 9092-9096.
70. Xiao Su, Wei Zhou, Yangyan Li, and Junliang Zhang*. Design, Synthesis, and Application of a Chiral sulfinamide Phosphine Catalyst for the Enantioselective lntramolecular Rauhut-Currier Reaction. Angew. Chem. Int. Ed. 2015, 54, 6874-6877.
71. Jian-Jun Feng, Tao-Yan Lin, Hai-Hong Wu and Junliang Zhang*. Transfer of Chirality in the Rhodium-Catalyzed intramolecular formal Hetero-[5+2] Cycloaddition of vinyl Azinidines and Alkynes: stereoselective synthesis of Fused Azepine Derivatives. J. Am. Chem. Soc. 2015, 137, 3787-3790.
72. Deyun Qian and Junliang Zhang*. Gold-Catalyzed Cyclopropanation Reactions by Carbenoid Precursor Toolbox. Chem. Soc. Rev. 2015, 44, 677-698.
73. Deyun Qian, Haoxiang Hu, Feng Liu, Bin Tang, Weimin Ye, Yidong Wang and Junliang Zhang*. Gold(l)-Catalyzed Highly Diastereo- and Enantioselective Alkyne Oxidation/Cyclopropanation of 1,6-Enynes. Angew. Chem. Int. Ed. 2014, 53, 13751-13755.
74. Lieiin Zhou, Mingrui Zhang, Wenbo Li and Junliang Zhang*. Furan-Based o-Quinodimethanes by Gold-Catalyzed Dehydrogenative Heterocyclization of 2-(1-Alkynyl-2-aken-1-ones: A Modular Entry to 2,3-furan-fused Carbocycles. Angew. Chem. int. Ed. 2014, 53, 6542-6545.
75. Zhunzhun Yu, Ben Ma, Mingjin Chen, Hai-Hong Wu, Lu Liu* and Junliang Zhang*. J. Am. Chem. Soc. 2014, 136, 6904-6907.
76. Zhan-Ming Zhang, Peng Chen, Wenbo Li, Yanfei Niu, Xiao-Li Zhao and Junliang Zhang*. A New Type of Chiral sulfinamide Monophosphine ligands: Stereodivergent Synthesis and Application in Enantioselective Gold(I)-Catalyzed Cycloaddition Reactions. Angew. Chem. Int. Ed. 2014, 53, 4350-4354.
77. Hui Qian, Xiuzhao Yu, Junliang Zhang* and Jianwei Sun*. Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes. J. Am. Chem. Soc. 2013, 135, 18020-18023.
78. Jian-Jun Feng, Junliang Zhang*. An Atom-Economic synthesis of Bicyclo[3.1.0]hexanes by Rhodium N-Heterocycic Carbene-Catalyzed Diastereoselective Tandem Hetero-[5+2] Cycloaddition/Claisen Rearrangement Reaction of Vinylic Oxiranes with Alkynes. J. Am. Chem. Soc. 2011, 133, 7304-7307.
79. Feng Liu, Deyun Qian, Lei Li, Xiaoli Zhao, Junliang Zhang*. Diastereo- and Enantioselective Gold(l)-Catalyzed Intermolecular Tandem Cycization/[3+3] Cycloadditions of 2-(1-Alkynyl)-2-alken-1-ones with Nitrones. Angew. Chem. Int. Ed. 2010, 49, 6669-6672.
80. Lu Liu, Junliang Zhang*. Selectivity Control in Lewis Acid Catalyzed Regiodivergent Tandem Cationic Cycization/Ring Expansion Terminated by Pinacol Rearrangement. Angew. Chem. Int. Ed. 2009, 48, 6093-6096.
81. Feng Liu, Yihua Yu, and Junliang Zhang*. Highly substituted furol 3,4-d[1,2]oxazines: Gold-Catalyzed Regiospecific and Diastereoselective 1,3-Dipolar Cycladdition of 2-(1-Akynyl)-2-aken-1-ones with Nitrones. Angew. Chem. Int. Ed. 2009, 48, 5505-5508.
二、专利：
1、 张俊良，罗文俊，李恒，葛晨宇，杨俊锋，李志铭；手性膦氮膦三齿配体、制备方法及其应用；2021，CN202011273102；
2、 张俊良，张荣华，徐杉；一类手性双齿氮膦配体Rong-Phos及其制备方法和应用；2021，CN202010223130；
3、 肖元晶，胡岸靖，张展鸣，张俊良；一种手性亚磺酰胺单膦配体的大量制备方法；2021，CN201910831293；
4、 张俊良,陈晓峰,周璐佳;一类吡啶骨架的手性单膦配体 CF-Phos及其制备方法和应用；2021，CN201811586531；
5、 张俊良,邱海乐,陈晓峰;一类环状膦骨架的手性单膦催化剂Le-Phos及其全构型的制备方法和应用；2020，CN201811587183;
6、 张俊良,韩杰,潘长进;一类二苯醚骨架的手性单膦配体 HP-Phos及制备方法和应用；2020， CN201811587169；
7、 张俊良,底晓煜;手性单膦配体Yu-Phos及其全构型的制备方法和应用，2020，CN201811586698；
8、 张俊良,张培超,王以栋,王磊;基于氧杂蒽骨架的手性单膦配体PC-Phos及其全构型的制备方法和应用；2019，CN201710541779
9、 张俊良,宿晓,周伟,李杨燕;一种手性叔膦化合物及其全构型、其制备方法和应用；2018，CN201510107308;
10、 张俊良,刘路,唐斌;基于吲哚骨架的中心手性亚磺酰胺类单膦配体及制备方法；2017，CN201510039784;
11、 张俊良,张展鸣,王以栋,陈鹏,唐斌;手性亚磺酰胺类单膦配体、其全构型制备方法及应用；2017，CN201310671902；
三、专著：
1、Junliang Zhang and Wenbo Li，Chiral Phosphorous Based Ligands in Earth-Abundant Transition Metal Catalysis，Elsevier，2023.

代表性奖励荣誉情况

1、张俊良、张展鸣、张培超、许冰、王磊；上海市自然科学一等奖；2024年、上海市人民政府。
2、张俊良；上海市领军人才；2021年、上海市人民政府。
3、张俊良；教育部创新团队跟踪计划学术带头人；2016年、教育部。
4、张俊良；科技部中青年创新领军人才；2016年、科技部。
5、张俊良；国家杰出青年基金；2014年、国家自然科学基金委。
6、张俊良；上海市优秀学科带头人；2012年、上海市人民政府。
7、张俊良；Thieme Chemistry Journal Award；2012年、Thieme学术集团。
8、张俊良；东方学者计划；2010年、东方学者。
9、张俊良；中国化学会青年化学奖；2009年、中国化学会。

*以上信息由会士个人更新和维护。