王殳凹

男， 苏州大学放射医学与防护学院

专业领域

放射化学

学习/工作经历

2003-2007: 中国科学技术大学材料科学与工程系，本科学生
2007-2012: 美国圣母大学土木工程与地质系&化学系，博士研究生
2012-2013: 加州大学伯克利分校化学系&劳伦斯伯克利国家实验室核化学中心，博士后
2013至今: 苏州大学放射医学与防护学院，教授
2023至今: 苏州大学放射医学与辐射防护国家重点实验室，主任

学术成就和学术贡献简述

王殳凹教授多年来面向我国核能可持续发展和核安全重大战略需求，在核能放射化学领域取得了一批重要成果。他主持承担了科技部重点研发计划项目、基金委杰出青年基金项目、基金委重大仪器研制项目等科研项目，提出了放射性核素精准识别理念，并应用于乏燃料后处理、核污水处理、核事故应急等领域中，为解决镧锕分离、含氚废水处理、铀骨骼促排等放射化学领域难题提供了科学依据和技术方案，并已初步在中核集团、中广核集团、军事医学研究院等单位实现应用，作为通讯作者在Nature (1篇，为我国在该刊发表的核能放射化学领域的首篇论文)、Nat. Commun. (8篇)、J. Am. Chem. Soc. (15篇)、Angew. Chem. Int. Ed. (15篇)、CCS Chem. (4篇)、ACS Cent. Sci. (2篇)、Chem (4篇)等学术期刊发表论文180篇，全部论文被Science、Nature等期刊论文引用评价超过14000次，授权国际专利3项，中国专利21项，曾获中国青年五四奖章、中国青年科技奖等，入选教育部长江学者特聘教授。

化学公益贡献简述

王殳凹教授在苏州大学组建了一支年轻的放射化学研究团队，面向我国核能发展及核安全重大战略需求，取得了一批科研成果，为我国多个重大涉核工程和任务中瓶颈问题的解决提供了科学依据。在教学科研过程中培养了一批我国现阶段紧缺的放射化学青年人才。曾作为我国唯一的大会报告人参加国际权威放射化学会议（APSORC-2017），向国际同行详细介绍了我国放射化学学科的研究进展。入选中国化学会中国青年化学家元素周期表代言人（代言94号放射性元素钚）和国际纯粹与国际纯粹与应用化学联合会青年化学家元素周期表代言人（代言92号放射性元素铀）。多次作为主讲人参加放射医学与辐射防护国家重点实验室科普基地组织的大型科普活动，向民众讲授放射化学基础知识，旨在消除”谈核色变“传统观念。2021年入选中国青年五四奖章后，多次参加共青团青年宣讲活动，向青年学生团体讲授新时代两弹一星精神并详细介绍了放射化学学科发展史。

代表性成果

(1) H. Zhang, A. Li, K. Li, Z. Wang, X. Xu, Y. Wang*, M. V. Sheridan, H.-S. Hu, C. Xu*, E. V. Alekseev, Z. Zhang, P. Yan, K. Cao, Z. Chai, T. E. Albrecht-Schönzart*, S. Wang*, “Ultrafiltration separation of Am(VI)-polyoxometalate from lanthanides” Nature, 2023, 616, 482-487.

(2) N. Shen, Z. Yang, S. Liu, X. Dai, C. Xiao*, K. Taylor-Pashow, D. Li, C. Yang, J. Li, Y. Zhang, M. Zhang, R. Zhou*, Z. Chai, S. Wang*. “99TcO4- Removal from Legacy Defense Nuclear Waste by an Alkaline-Stable 2D Cationic Metal-Organic Framework” Nat. Commun., 2020, 11, 5571.

(3) X. Wang, X. Dai, C. Shi, J. Wan, M. A. Silver, L. Zhang, L. Chen, X. Yi, B. Chen, D. Zhang, K. Yang, J. Diwu*, J. Wang, Y. Xu, R. Zhou*, Z. Chai, S. Wang*. “A 3,2-Hydroxypyridinone-based Decorporation Agent that Removes Uranium from Bones in vivo” Nat. Commun., 2019, 10, 2570 (Highlighted in ChemistryWorld).

(4) J. Li, X. Dai, L. Zhu, C. Xu, D. Zhang, M. A. Silver, P. Li, L. Chen, Y. Li, D. Zuo, H. Zhang, C. Xiao*, J. Chen, J. Diwu, O. K. Farha, T. E. Albrecht-Schmitt, Z. Chai, S. Wang*. “99TcO4- Remediation by a Cationic Polymeric Network” Nat. Commun., 2018, 9, 3007.

(5) Y. Li, Z. Yang, Y. Wang, Z. Bai, Z. Tao, X. Dai, S. Liu, D. Gui, W. Liu, M. Chen, L. Chen, J. Diwu, L. Zhu, R. Zhou*, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “A Mesoporous Cationic Thorium-Organic Framework that Rapidly Traps Anionic Persistent Organic Pollutants” Nat. Commun., 2017, 8, 1354.

(6) T. Zheng, Z. Yang, Z. Liu, D. Gui, X. Dai, S. Liu, L. Zhang, Y. Gao, L. Chen, D. Sheng, Y. Wang, J. Diwu, J. Wang, R. Zhou*, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Overcoming the Crystallization and Designability Issues in the Ultrastable Zirconium Phosphonate Framework System” Nat. Commun., 2017, 8, 15369.

(7) X. Yin, Y. Wang, X. Bai, Y. Wang, L. Chen, C. Xiao, J. Diwu, S. Du*, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Rare Earth Separations by Selective Borate Crystallization” Nat. Commun., 2017, 8, 14438.

(8) J. Chen, M. Zhang, J. Shu, S. Liu, X. Dong, C. Li, L. He, M. Yuan, Y. Wu, J. Xu, D. Zhang, F. Ma, G. Wu, Z. Chai, S. Wang*, “Radiation-Induced De Novo Defects in Metal–Organic Frameworks Boost CO2 Sorption” J. Am. Chem. Soc., 2023, 145, 23651-23658.

(9) Y. Zhang, F. Li, Z. Cui, K. Li, J. Guan, L. Tian*, Y. Wang*, N. Liu, W. Wu, Z. Chai, S. Wang*, “A Radioluminescent Metal–Organic Framework for Monitoring 225Ac in Vivo” J. Am. Chem. Soc., 2023, 145, 13161-13168.

(10) Y. Zhang, X. Wang, K. Xu, F. Zhai, J. Shu, Y. Tao, J. Wang, L. Jiang, L. Yang, Y. Wang, W. Liu*, J. Su*, Z. Chai, S. Wang*, “Near-Unity Energy Transfer from Uranyl to Europium in a Heterobimetallic Organic Framework with Record-Breaking Quantum Yield” J. Am. Chem. Soc., 2023, 145, 13161-13168.

(11) X. Wang, F. Ma, S. Liu, L. Chen, S. Xiong, X. Dai, B. Tai, L. He, M. Yuan, P. Mi, S. Gong, G. Li, Y. Tao, J. Wan, L. Chen, X. Sun, Q. Tang, L. He, Z. Yang*, Z. Chai, S. Wang*, “Thermodynamics-Kinetics-Balanced Metal-Organic Framework for In-Depth Radon Removal under Ambient Conditions” J. Am. Chem. Soc., 2022, 144, 13634-13642.

(12) B. Chen, S. Hong, X. Dai, X. Li, Q. Huang, T. Sun, D. Cao, H. Zhang, Z. Chai, J. Diwu*, S. Wang*, “In Vivo Uranium Decorporation by a Tailor-Made Hexadentate Ligand” J. Am. Chem. Soc., 2022, 144, 11054-11058.

(13) C. Liang, L. Cheng, S. Zhang, S. Yang, W. Liu, J. Xie, M. Li*, Z. Chai, Y. Wang*, S. Wang*, “Boosting the Optoelectronic Performance by Regulating Exciton Behaviors in a Porous Semiconductive Metal-Organic Framework” J. Am. Chem. Soc., 2022, 144, 2189-2196.

(14) L. Cheng, C. Liang; W. Liu, Y. Wang, B. Chen, H. Zhang, Y. Wang*, Z. Chai, S. Wang*. “Three-Dimensional Polycatenation of a Uranium-Based Metal-Organic Cage: Structural Complexity and Radiation Detection” J. Am. Chem. Soc., 2020, 142, 16218-16222.

(15) M. Zhang, J. Chen, S. Zhang, X. Zhou, L. He, M. V. Sheridan, M. Yuan, M. Zhang, L. Chen, X. Dai, F. Ma, J. Wang, J. Hu, G. Wu, X. Kong, R. Zhou, T. E. Albrecht-Schmitt, Z. Chai, S. Wang*. “Electron Beam Irradiation as a General Approach for the Rapid Synthesis of Covalent Organic Frameworks under Ambient Conditions” J. Am. Chem. Soc., 2020, 142, 9169-9174.

(16) Y. Wang, X. Liu, X. Li, F. Zhai, S. Yan, N. Liu, Z. Chai, Y. Xu*, X. Ouyang*, S. Wang*. “Direct Radiation Detection by a Semiconductive Metal-Organic Framework” J. Am. Chem. Soc., 2019, 141, 8030-8034.

(17) D. Gui, X. Dai, Z. Tao, T. Zheng, X. Wang, M. A. Silver, J. Shu, L. Chen, Y. Wang, T. Zhang, J. Xie, L. Zou, Y. Xia, J. Zhang, J. Zhang, L. Zhao*, J. Diwu, R. Zhou*, Z. Chai, S. Wang*. “Unique Proton Transportation Pathway in a Robust Inorganic Coordination Polymer Leading to Intrinsically High and Sustainable Anhydrous Proton Conductivity” J. Am. Chem. Soc., 2018, 140, 6146-6155.

(18) L. Zhu, D. Sheng, C. Xu, X. Dai, M. A. Silver, J. Li, P. Li, Y. Wang, Y. Wang, C. Xiao*, J. Chen, R. Zhou, C. Zhang, O. K. Farha, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Identifying the Recognition Site for Selective Trapping of 99TcO4- in a Hydrolytically Stable and Radiation Resistant Cationic Metal-Organic Framework” J. Am. Chem. Soc., 2017, 139, 14873-14876.

(19) Y. Wang, Z. Liu, Y. Li, Z. Bai, W. Liu, Y. Wang, X. Xu, C. Xiao, D. Sheng, J. Diwu*, J. Su*, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions” J. Am. Chem. Soc., 2015, 137, 6144-6147.

(20) Y. Zhang, L. He, T. Pan, J. Xie, F. Wu, X. Dong, X. Wang, L. Chen, S. Gong, W. Liu, L. Kang, J. Chen, L. Chen, L. Chen*, Y. Han*, S. Wang*. “Superior Iodine Uptake Capacity Enabled by an Open Metal-Sulfide Framework Composed of Three Types of Active Sites” CCS Chem., 2023, 5, 1540-1548.

(21) Y. Wang, S. Hu, L. Cheng, C. Liang, X. Yin, H. Zhang, A. Li, D. Sheng, J. Diwu, X. Wang*, J. Li*, Z. Chai, S. Wang*. "Stabilization of Plutonium(V) within a Crown Ether Inclusion Complex" CCS Chem., 2020, 2, 425-431.

(22) D. Gui, W. Duan, J. Shu, F. Zhai, N. Wang, X. Wang, J. Xie, H. Li, L. Chen, J. Diwu, Z. Chai, S. Wang*. “Persistent Superprotonic Conductivity in the Order of 10-1 S•cm-1 Achieved through Thermally Induced Structural Transformation of a Uranyl Coordination Polymer” CCS Chem., 2019, 1, 197-206.

(23) S. Mei, L. Chen, H. Zhang, Z. Li, L. Cheng, J. Lu, X. Li, Q. Yang, Y. Wang*, Z. Liu, Z. Chai, S. Wang*, “Assembling a Heterobimetallic Actinide Metal-Organic Framework by a Reaction-Induced Preorganization Strategy” Angew. Chem. Int. Ed., 2023, 62, e202306360.

(24) Y. Wang, M. Li, Z. Chai, Y. Wang*, S. Wang*, “Perovskite Scintillators for Improved X-ray Detection and Imaging” Angew. Chem. Int. Ed., 2023, 62, e202304638.

(25) J. Chen, M. Zhang, S. Zhang, K. Cao, X. Mao, M. Zhang, L. He, X. Dong, J. Shu, H. Dong, F. Zhai, R. Shen, M. Yuan, X. Zhao, G. Wu, Z. Chai, S. Wang*, “Metal-Organic Framework@Metal Oxide Heterostructures Induced by Electron-Beam Radiation” Angew. Chem. Int. Ed., 2022, 61, e202212532.

(26) M. Li, Y. Wang, L. Yang, Z. Chai, Y. Wang, S. Wang*. “Circularly Polarized Radioluminescence from Chiral Perovskite Scintillators for Improved X-ray Imaging” Angew. Chem. Int. Ed., 2022, 61, e202208440.

(27) M. Yuan, F. Ma, X. Dai, L. Chen, F. Zhai, L. He, M. Zhang, J. Chen, J. Shu, X. Wang, Y. Zhang, X. Fu, Z. Li, C. Guo, L. Chen, Z. Chai, S. Wang*. “Deuterated Covalent Organic Framework with Significant Enhanced Luminescence” Angew. Chem. Int. Ed., 2021, 60, 20970-20976.

(28) J. Chen, M. Zhang, J. Shu, M. Yuan, W. Yan, P. Bai, L. He, N. Shen, S. Gong, D. Zhang, J. Li, J. Hu, R. Li, G. Wu, Z. Chai, J. Yu, S. Wang*. “Electron Beam Irradiation Induced Formation of Defect‐Rich Zeolites under Ambient Condition with Minutes” Angew. Chem. Int. Ed., 2021, 60, 14858-14863.

(29) M. Zhang, C. Liang, G. Cheng, J. Chen, Y. Wang, L. He, L. Cheng, S. Gong, D. Zhang, J. Li, S. Hu*, J. Diwu, G. Wu, Y. Wang*, Z. Chai, S. Wang*. “Intrinsic Semiconducting Behavior in a Large Mixed-Valent Uranium (V/VI) Cluster”. Angew. Chem. Int. Ed., 2021, 60, 9886-9890.

(30) H. Liu, H. Qin, N. Shen, S. Yan, Y. Wang, X. Yin, X. Chen, C. Zhang, X. Dai*, R. Zhou, X. Ouyang, Z. Chai, S. Wang*. “Emergence of Radical-Stabilizing Metal-Organic Framework as a New Type of Radio-Photoluminescence Dosimeter” Angew. Chem. Int. Ed., 2020, 59, 15209-15214.

(31) C. Liang, S. Zhang, L. Cheng, J. Xie, Y. He, F. Zhai, Y. Wang*, Z. Chai, S. Wang*. “Thermoplastic Membranes Incorporating Semiconductive Metal-Organic Frameworks: an Advance on Flexible X-ray Detectors” Angew. Chem. Int. Ed., 2020, 59, 11856-11860.

(32) H. Zhang, W. Liu, A. Li, D. Zhang, X. Li, F. Zhai, L. Chen, L. Chen, Y. Wang, S. Wang*. “Three Mechanisms in One Material: Uranium Capture by a Polyoxometalate-Organic Framework through Combined Complexation, Chemical Reduction, and Photocatalytic Reduction” Angew. Chem. Int. Ed., 2019, 58, 16110-16114 (VIP Paper; Highlighted in ChemistryViews).

(33) D. Sheng, L. Zhu, X. Dai, C. Xu, P. Li, Carolyn I. Pearce, C. Xiao*, J. Chen, R. Zhou, T. Duan, O. K. Farha, Z. Chai, S. Wang*. “Successful Decontamination of 99TcO4− in Groundwater at Legacy Nuclear Sites by a Cationic Metal-Organic Framework with Hydrophobic Pockets” Angew. Chem. Int. Ed., 2019, 58, 4968-4972.

(34) Y. Wang, W. Liu, Z. Bai, T. Zheng, M. A. Silver, Y. Li, Y. Wang, X. Wang, J. Diwu, Z. Chai, S. Wang*. “Employing a Unique Unsaturated Th4+ Site in a Porous Thorium-Organic Framework for Kr/Xe Uptake and Separation” Angew. Chem. Int. Ed., 2018, 57, 5783-5787.

(35) Y. Wang, X. Yin, W. Liu, J. Chen, M. A. Silver, D. Sheng, L. Chen, J. Diwu, N. Liu, Z. Chai, T. E. Albrecht-Schmitt, S. Wang*. “Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X-ray Scintillators” Angew. Chem. Int. Ed., 2018, 57, 7883-7887 (Selected as Journal Inside Cover Art).

(36) J. Xie, Y. Wang, W. Liu, X. Yin, L. Chen, Y. Zou, J. Diwu, Z. Chai, T. E. Albrecht-Schmitt, G. Liu, S. Wang*. “Highly Sensitive Detection of Ionizing Radiations by a Photoluminescent Uranyl Organic Framework” Angew. Chem. Int. Ed., 2017, 56, 7500-7004.

(37) Y. Wang, G. Chen, Z. Zhu, H. Qin, L. Yang, D. Zhang, Y. Yang, M. Qiu, K. Liu, Z. Chai, W. Yin*, Y. Wang*, S. Wang*, “Manipulation of Shallow-Trap States in Halide Double Perovskite Enables Real-Time Radiation Dosimetry” ACS Cent. Sci., 2023, 9, 1827-1834.

(38) J. Li, B. Li, N. Shen, L. Chen, Q. Guo, L. Chen, L. He, X. Dai, Z. Chai, S. Wang*. “Task-Specific Tailored Cationic Polymeric Network with High Base-Resistance for Unprecedented 99TcO4– Cleanup from Alkaline Nuclear Waste” ACS Cent. Sci., 2021, 7, 1441-1450.

(39) S. Zhang, L. Chen, Z. Qu, F. Zhai, X. Yin, D. Zhang, Y. Shen, H. Li*, W. Liu, S. Mei, G. Ji, C. Zhang, X. Dai*, Z. Chai, S. Wang*. “Confining Ti-oxo clusters in covalent organic framework micropores for photocatalytic reduction of the dominant uranium species in seawater” Chem, 2023, 9, 3172-3184.

(40) Y. Bai, L. Chen, L. He, B. Li, L. Chen, F. Wu, L. Chen, M. Zhang, Z. Liu, Z. Chai, S. Wang*, “Precise Recognition of Palladium through Interlaminar Chelation in a Covalent Organic Framework” Chem, 2022, 8, 1442-1459.

(41) L. He, L. Chen, X. Dong, S. Zhang, M. Zhang, X. Dai, X. Liu, P. Lin, K. Li, C. Chen, T. Pan, F. Ma, J. Chen, M. Yuan, Y. Zhang, L. Chen, R. Zhou, Y. Han*, Z. Chai, S. Wang*. “A Nitrogen-Rich Covalent Organic Framework for Simultaneous Dynamic Capture of Iodine and Methyl Iodide” Chem, 2021, 7, 699-714.

(42) J. Zhang, L. Chen, X. Dai, L. Zhu, C. Xiao, L. Xu, Z. Zhang, E. V. Alekseev, Y. Wang, C. Zhang, H. Zhang, Y. Wang, J. Diwu*, Z. Chai, S. Wang*. “Distinctive Two-Step Intercalation of Sr2+ into a Coordination Polymer with Record High 90Sr Uptake Capabilities” Chem, 2019, 5, 977-994.

代表性奖励荣誉情况

2023年，腾讯科学探索奖；
2021年，中国青年五四奖章；
2020年，中国青年科技奖；
2019年，中国化学会中国青年化学家元素周期表代言人（94号元素钚）；
2018年，第一届中国环境科学学会青年科学家奖金奖；
2018年，国际纯粹与应用化学联合会青年化学家元素周期表代言人（92号元素铀）；
2018年，江苏省教育教学与研究成果奖二等奖（排名第一）；
2017年，中国化学会分子筛专业委员会第一届中国分子筛新秀奖；
2012年，美国化学会无机化学学部青年科学家奖；
2012年，国际衍射数据中心Ludo Frevel晶体学奖。

*以上信息由会士个人更新和维护。