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刘彩明

男, 中国科学院化学研究所, 教授/研究员/教授级高工或同等级别

学习/工作经历

1986.09-1990.07 赣南师范学院(现赣南师范大学)化学系化学专业大学本科
1990.09-1993.01 江西师范大学化学系有机化学专业硕士研究生
1993.05-1995.02 南昌大学化学系助教、讲师
1995.02-1997.11 南京大学化学化工学院无机化学专业博士研究生
1997.11-1998.09 南京大学配位化学国家重点实验室研究助理
1998.09-1999.12 瑞典Lund University化学化工学院无机化学专业博士后
2000.01-2000.12 北京大学稀土化学材料及应用国家重点实验室高级访问学者
2001.01-现在 中国科学院化学研究所有机固体重点实验室副研究员、研究员

研究领域和兴趣

功能配合物、晶态分子材料、多功能分子材料

主要业绩

刘彩明,藉贯:江西省龙南市(杨村镇),主要从事光、电、磁功能配合物分子材料和多功能分子材料等领域的研究(以功能为导向,通过化学反应合成新的物质,研究其晶体结构、性能以及结构-性质的相关性); 研究对象包括分子磁体、分子纳米磁体、有机-无机杂化固体材料、金属-有机框架分子材料(MOF)或配位聚合物、纯手性分子材料等。近期重点研究含稀土离子的配合物分子材料,致力于构筑新型分子(纳米)磁体特别是手性单分子磁体,通过手性附加上非线性光学倍频效应(SHG)、铁电、磁手征二色性等性质,在纳米尺度分子中实现多种性能的集成和耦合(或关联,如磁光效应)。此外,在研究过程中还涉及到手性起源、绿色环保(例如,通过对空气中二氧化碳的自动捕获,使其固定产物成为功能分子材料的重要组成部分)等领域。在这些研究领域取得了系列阶段性成果,已经正式发表 SCI 研究论文二百四十多篇 (见https://webofscience.clarivate.cn/wos/author/record/985132; Web of Science Researcher ID:D-6937-2013; https://sciprofiles.com/profile/526397)。其中一作 SCI 论文九十篇, 发表在 J. Am. Chem. Soc., Angew. Chem. Int. Ed., Chem. Comm., Chem.-Eur. J., Sci. China Chem., Chin. J. Chem., Inorg. Chem., Inorg. Chem. Front.等国际顶级或著名化学杂志上。合作论文发表在 Nature Commun.;Adv. Mater.;Chem. Mater.; J. Mater. Chem. A; J. Mater. Chem. C; Chemical Engineering Journal 等著名杂志上。 部分论文已经被SCI杂志他引 6900 多次(引用总次数 7900 多次, H-index: 48)。出版一作专著两章。现担任国际SCI期刊《Magnetochemistry》等的编委,是中国化学会永久会员。 被欧洲研究理事会European Research Council 选为Synthetic Chemistry and Materials 领域的项目评审专家。

代表成果

1. Liu Cai-Ming*; Xiong Ren-Gen; Zhang De-Qing; Zhu Dao-Ben; Nanoscale Homochiral C-3-Symmetric Mixed-Valence Manganese Cluster Complexes with Both Ferromagnetic and Ferroelectric Properties. Journal of the American Chemical Society, 2010, 132(12): 4044,DOI: 10.1021/ja910310p;
2. Liu Cai-Ming*; Gao Song; Zhang De-Qing*; Huang Yong-Hong; Xiong Ren-Gen; Liu Zhi-Liang; Jiang Feng-Chi; Zhu Dao-Ben*; A unique 3D alternating ferro- and antiferromagnetic manganese azide system with threefold interpenetrating (10,3) nets. Angewandte Chemie International Edition, 2004, 43(8): 990, DOI: 10.1002/anie.200352780;
3. Liu Cai-Ming*; Zhang De-Qing*; Xiong Ren-Gen*; Hao Xiang; Zhu Dao-Ben; A homochiral Zn-Dy heterometallic left-handed helical chain complex without chiral ligands: anion-induced assembly and multifunctional integration. Chemical Communications, 2018, 54(95): 13379, DOI: 10.1039/c8cc07468b;
4. Liu Cai-Ming*; Zhang De-Qing; Zhu Dao-Ben; A 3D MOF constructed from dysprosium(III) oxalate and capping ligands: ferromagnetic coupling and field-induced two-step magnetic relaxation. Chemical Communications, 2016, 52(26): 4804, DOI: 10.1039/c6cc00498a;
5. Liu Cai-Ming*; Zhang De-Qing*; Zhu Dao-Ben; Solvatomagnetic effect and spin-glass behavior in a 1D coordination polymer constructed from EE-azido bridged (Mn3O)-O-III units. Chemical Communications, 2008, (3): 368, DOI: 10.1039/b715080f;
6. Liu Cai-Ming; Gao Song*; Kou Hui-Zhong; Dehydrogenative coupling of phenanthroline under hydrothermal conditions: crystal structure of a novel layered vanadate complex constructed of 4,8,10-net sheets: [(2,2 '-biphen)Co]V3O8.5. Chemical Communications, 2001, 1(17): 1670, DOI: 10.1039/b103304m;
7.Liu Cai-Ming; Gao Song*; Hu Huai-Ming; Wang Ze-Ming; A novel bimetallic cage complex constructed from six V4Co pentatomic rings: hydrothermal synthesis and crystal structure of [(2,2 '-Py2NH)(2)Co](3)V8O23. Chemical Communications, 2001, 1(17): 1636, DOI: 10.1039/b104273b;
8. Liu Cai-Ming; Restorp P; Nordlander E*; Pierpont CG*; Oxo-deficient dioxylene complexes of Mo(VI) containing 3,6-di-tert-butylcatechol. Chemical Communications, 2001, 24(24): 2686, DOI: 10.1039/b108220e;
9. Liu Cai-Ming*; Zhang De-Qing; Hao Xiang; Zhu Dao-Ben; Nestlike C-4-Symmetric [Co-24] Metallamacrocycle Sustained by p-tert-Butylsulfonylcalix[4]arene and 1,2,4-Triazole. Chemistry - A European Journal, 2011, 17(44): 12285, DOI: 10.1002/chem.201101607;
10. Liu Cai-Ming, Hou Yang-Long, Zhang Jing Zhang, Gao Song,* GaoHydrothermal Synthesis and Crystal Structure of a Novel Two-Dimensional Vanadium Oxide Complex with a 6,14-Net Sinusoidal Ruffling Anionic Layer:  [Ni(phen)2V4O11] (phen = 1,10-Phenanthroline). Inorganic Chemistry 2002, 41, 140. DOI: 10.1021/ic010735k.
11. Liu Cai-Ming, Nordlander Ebbe,* Schmeh Derek, Shoemaker Richard, Pierpont Cortlandt G.*, Coordination Complexes of Molybdenum with 3,6-Di-tert-butylcatechol. Addition Products of DMSO, Pyridine N-oxide, and Triphenylarsine Oxide to the Putative [MoVIO(3,6-DBCat)2] Monomer and Self-Assembly of the Chiral [{MoVIO(3,6-DBCat)2}4] Square. Inorganic Chemistry 2004, 43, 2114. DOI: 10.1021/ic0354264.
12. Liu Cai-Ming*, Zhang De-Qing, and Zhu Dao-Ben, Field-Induced Single-Ion Magnets Based on Enantiopure Chiral β-Diketonate Ligands, Inorganic Chemistry 2013, 52, 15, 8933, DOI: 10.1021/ic4011218;
13. Liu Cai-Ming*, Zhang De-Qing, and Zhu Dao-Ben, 1D Coordination Polymers Constructed from anti−anti Carboxylato-Bridged MnIII3O(Brppz)3 Units: From Long-Range Magnetic Ordering to Single-Chain Magnet Behaviors, Inorganic Chemistry 2009, 48(11), 4980, DOI: 10.1021/ic900345s;
14. Liu Cai-Ming Liu*, Zhang De-Qing, and Zhu Dao-Ben, Ferromagnetic Disklike MnIVMnII3NaI3 Heptanuclear Complex with a S = 9 Ground State, Inorganic Chemistry 2009, 48(3), 792, DOI: 10.1021/ic8018474;
15. Liu Cai-Ming*; Zhang De-Qing; Hao Xiang, Zhu Dao-Ben. Arraying Octahedral {Cr2Dy4} Units into 3D Single-Molecule-Magnet-Like Inorganic Compounds with Sulfate Bridges. Inorganic Chemistry, 2018, 57(12): 6803,DOI: 10.1021/acs.inorgchem.8b01210;
16. Liu Cai-Ming*, Zhang De-Qing, Su Jing-Bu, Zhang Yi-Quan*, Zhu Dao-Ben, Single-Molecule Magnet Behavior of 1D Coordination Polymers Based on DyZn2(salen)2 Units and Pyridin-N-Oxide-4-Carboxylate: Structural Divergence and Magnetic Regulation. Inorganic Chemistry, 2018, 57(17): 11077, DOI: 10.1021/acs.inorgchem.8b01653;
17. Liu Cai-Ming*, Zhang De-Qing, Zhao Yong-Sheng, Hao Xiang and Zhu Dao-Ben, Two-step warming solvothermal syntheses, luminescence and slow magnetic relaxation of isostructural dense LnMOFs based on nanoscale 3-connected linkers. Inorganic Chemistry Frontiers, 2016, 3, 1076, DOI: 10.1039/C6QI00137H;
18. Liu Cai-Ming*; Zhang De-Qing; Hao Xiang, Zhu Dao-Ben; Assembly of chiral 3d-4f wheel-like cluster complexes with achiral ligands: single-molecule magnetic behavior and magnetocaloric effect. Inorganic Chemistry Frontiers, 2020, 7(18): 3340, DOI: 10.1039/d0qi00632g.
19. Liu Cai-Ming,*Zhang De-Qing, Hao Xiang, Zhu Dao-Ben, Simultaneous assembly of mononuclear and dinuclear dysprosium(III) complexes behaving as single-molecule magnets in a one-pot hydrothermal synthesis. Science China Chemistry. 2017, 60, 358. DOI:10.1007/s11426-016-0359-x.
20. Liu Cai-Ming*; Sun Rong; Wang Bing-Wu, Hao Xiang, Li Xi-Li, Effects of Counterions, Coordination Anions, and Coordination Solvent Molecules on Single-Molecule Magnetic Behaviors and Nonlinear Optical Properties of Chiral Zn2Dy Schiff Base Complexes, Inorganic Chemistry, 2022, 61(46): 18545, DOI:10.1021/acs.inorgchem.2c02743.
21.Cai-Ming Liu,* Hua-Hong Zou,* Yi-Quan Zhang,* Xiang Hao and Xiao-Ming Ren, Homochiral Dy2 Schiff Base Complexes Based on (R)/(S)-Chlocyphos: Single-Molecule Magnet Behaviours, Proton Conductivities and MCD Effects. Chin. J. Chem. 2025, 43, 1051. DOI: 10.1002/cjoc.202401318.
22. 刘彩明, 刘志亮, 张德清, 朱道本, 第二章 分子磁体的研究进展,《功能材料化学进展》(化学进展丛书之一),朱道本主编,化学工业出版社,2005年,北京, PP69-112。
23.刘彩明, 张德清, 朱道本, 田金磊, 卜显和, 第二章 分子晶体: 晶体工程与功能,《分子科学前沿》,白春礼主编,科学出版社,2007年,北京, PP15-87。

*以上信息由高级会员个人更新和维护。