杨四海

男， 北京大学， 教授/研究员/教授级高工或同等级别

学习/工作经历

2023 – 今 北京大学化学与分子工程学院 教授
2015 – 2023 曼彻斯特大学化学院 副教授、教授
2011 – 2015 诺丁汉大学化学院 研究员、助理教授
2007 – 2010 诺丁汉大学 无机化学博士
2003 – 2007 北京大学 化学学士

研究领域和兴趣

多孔材料，配位化学，吸附，催化，中子散射

主要业绩

申请人围绕功能导向多孔材料的化学调控这一核心科学问题，开展了系统性的研究，创制了系列新型多孔材料并拓展了其在环境及低碳领域中的应用，发展并完善了基于中子散射的吸附催化表征技术，对多种小分子的吸附、活化及转化过程进行深入系统探索，取得系列原创性重要成果。例如，首次发现基于羟基的CO2吸附捕集新材料；探索了锂离子对氢气的吸附性能提升机制；在生物质及其衍生物的活化与转化机理方面取得新的认识，揭示了C-C键、C-O键的断裂机制；提出基于超分子作用力捕集腐蚀性气体的方法，实现对污染物NOx、SO2的高效吸附分离；实现重要低碳烯烃的高效分离，揭示了活性位点对烯烃、炔烃及烷烃的选择性识别机制；设计仿生催化体系，高效活化甲烷C-H键一步制备甲醇燃料；采用分子筛材料，在无贵金属、无氢气、无溶剂条件下将废弃聚乙烯塑料转化为高品质汽油，收率达到80%，揭示了复杂反应中的氢转移机制。作为通讯作者发表论文130篇，通讯作者论文包括Science (1), Nature Chemistry (4), Nature Materials (6), Nature Chemical Engineering (1), Journal of American Chemical Society (28), Nature Communications (12), Angewandte Chemie International Edition/Advanced Materials/Chem/PNAS (17)，并获得多个国际重要奖项。申请人的研究推动了化学材料与能源环境交叉领域的发展，研究成果对‘减污降碳’绿色技术开发、实现“双碳”目标具有重要意义。

代表成果

1. Trace benzene capture by decoration of structural defects in metal-organic framework materials. Trace benzene capture by decoration of structural defects in metal-organic framework materials. Y. Han, W. Huang, M. He, B. An, Y. Chen, X. Han, L. An, M. Kippax-Jones, J. Li, Y. Yang, M. D. Frogley, C. Li, D. Crawshaw, P. Manuel, S. Rudić, Y. Cheng, I. Silverwoord, L. L. Daemen, A. J. Ramirez-Cuesta, S. J. Day, S. P. Thompson, B. F. Spencer, M. Nikiel, D. Lee, M. Schröder* and S. Yang*. Nature Materials 2024, 23, in press.
2. Upcycling of polyethylene to gasoline through a self-supplied hydrogen strategy in a layered self-pillared zeolite. Z. Cen, X. Han*, L. Lin*, S. Yang*, W. Han, W. Wen, W. Yuan, M. Dong, Z. Ma, F. Li, Y. Ke, J. Dong, J. Zhang, S. Liu, J. Li, Q. Li, N. Wu, J. Xiang, H. Wu, L. Cai, Y. Hou, Y. Cheng, L. L. Daemen, A. J. Ramirez-Cuesta, P. Ferrer, D. C. Grinter, G. Held, Y. Liu and B. Han*. Nature Chemistry 2024, 16, 871-880. Journal Cover Article.
3. Direct photo-oxidation of methane to methanol over a mono-iron-hydroxyl site. B. An, Z. Li, Z. Wang, X. Zeng, X. Han, Y. Cheng, A. M. Sheveleva, Z. Zhang, F. Tuna, E. J. L. McInnes, M. D. Frogley, A. J. Ramirez-Cuesta, L. Natrajan, C. Wang, W. Lin, S. Yang* and M. Schröder*. Nature Materials 2022, 21, 932-938.
4. Control of zeolite pore interior for chemoselective alkyne/olefin separations. Y. Chai, X. Han, W. Li, S. Liu, S. Yao, C. Wang, W. Shi, I. da-Silva, P. Manuel, Y. Cheng, L. D. Daemen, A. J. Ramirez-Cuesta, C. C. Tang, L. Jiang, S. Yang*, N. Guan and L. Li*. Science 2020, 368, 1002-1006.
5. Quantitative production of butenes from biomass-derived γ-valerolactone over a new hetero-atomic MFI zeolite. L. Lin, A. M. Sheveleva, I. da Silva, C. M.A. Parlett, Z. Tang, Y. Liu, M. Fan, X. Han, J. H. Carter, F. Tuna, E. J. L. McInnes, Y. Cheng, L. L. Daemen, S. Rudić, A.J. Ramirez-Cuesta, C.C. Tang and S. Yang*. Nature Materials 2020, 19, 86-93.
6. Capture of nitrogen dioxide and conversion to nitric acid in a porous metal-organic framework. J. Li, X. Han, X. Zhang, A. M. Sheveleva, Y. Cheng, F. Tuna, E. J. L. Mcinnes, L. McCormick, S. J. Teat, L. L. Daeman, A. J. Ramirez-Cuesta, M. Schröder* and S. Yang*. Nature Chemistry 2019, 11, 1085-1090. Journal Cover Article.
7. Reversible coordinative binding and separation of sulphur dioxide in a robust metal-organic framework with open copper sites. G. L. Smith, J. E. Eyley, X. Han, X. Zhang, J. Li, N. M. Jacques, H. G.W. Godfrey, S. P. Argent, L. J. McCormick, S. J. Teat, Y. Cheng, M. D. Frogley, G. Cinque, S. J. Day, C. C. Tang, T. L. Easun, S. Rudić, A. J. Ramirez-Cuesta, S. Yang* and M. Schröder*. Nature Materials 2019, 18, 1358-1366.
8. Reversible adsorption of nitrogen dioxide within a robust metal-organic framework. X. Han, H. G.W. Godfrey, L. Briggs, A. J. Davies, Y. Cheng, L. L. Daemen, A. M. Sheveleva, F. Tuna, E. J.L. McInnes, J. Sun, C. Drathen, M. W. George, A. J. Ramirez-Cuesta, K. M. Thomas, S. Yang* and M. Schröder*. Nature Materials 2018, 17, 691-696.
9. Supramolecular Binding and Separation of Hydrocarbons within a Functionalised Porous Metal-Organic Framework. S. Yang*, A.J. Ramirez-Cuesta, R. Newby, V. Garcia-Sakai, P. Manuel, S.K. Callear, S.I. Campbell, C.C. Tang and M. Schröder*. Nature Chemistry 2015, 7, 121-129. Journal Cover Article.
10. Selectivity and Direct Visualisation of Carbon Dioxide and Sulphur Dioxide in a Decorated Porous Host. S. Yang*, J. Sun, A.J. Ramirez-Cuesta, S.K. Callear, W.I.F. David, D.P. Anderson, R. Newby, A.J. Blake, J.E. Parker, C.C. Tang and M. Schröder*. Nature Chemistry 2012, 4, 887-894. Journal Cover Article.

*以上信息由高级会员个人更新和维护。