杨恩翠

女， 天津师范大学化学学院， 教授/研究员/教授级高工或同等级别

学习/工作经历

1993.9-2000.6 天津师范大学 本科和硕士
2000.7-今 天津师范大学 教师
2002.7-2005.7 南开大学 物理化学专业博士
2007.7-2008.6 日本甲南大学 博士后

研究领域和兴趣

功能配位化学

主要业绩

本人长期从事功能配合物的构效关系研究，围绕着光学、磁学和催化解水等功能导向的多氮唑/核酸碱基-多羧基混合配体过渡金属、多羧酸-稀土以及多羧酸-过渡-稀土混金属等多个自组装体系开展了配位聚合物的设计、合成以及性能调控等方面的基础研究。研究发现在多氮唑−多羧基混合配体配位聚合物的定向组装中，配体中羧基以及杂环氮给体的数目、位置、取代基电子结构以及分步去质子等因素关键性地决定着配位聚合物的维度和核簇子结构的形成，为高核簇为建筑块的配位聚合物的可控合成提供了经验积累。通过唑基-羧基过渡金属配位聚合物分子磁学性能研究揭示了其宏观磁学性能与微观功能基元的相关性，丰富了唑基-羧基混桥过渡金属配合物的磁构关系。提出了晶态核酸碱基配位聚合物的合成新方法，解决了核酸碱基类配位聚合物的制备瓶颈。获得了首个高维核酸碱基配位聚合物，首次在分子水平上证明了腺嘌呤与金属离子前所未有的四齿配位模式，完善了生物活性配体与金属离子的键合模式。报道了第一个基于核酸碱基的三维铜(II)配合物的铁磁有序行为，拓展了核酸碱基配位聚合物在分子基磁性材料领域的应用。本人已经主持完成国家自然科学基金4项及省部级科研项目10余项，在Chem. Commun., Inorg. Chem., Chem. Eur. J., J. Mater. Chem.等专业刊物上发表研究论文70余篇。研究成果具有重要的科学意义和潜在的应用价值，被Chem. Rev.，Chem. Soc. Rev.，J. Am. Chem. Soc.，Angew. Chem. Int. Ed.，Adv. Mater.等期刊大篇幅地正面评述和引用，受到国际同行的广泛关注和高度评价。本人已获授权中国发明专利14项，培养研究生50余名，获得2013年度天津市自然科学一等奖（第2完成人）、第十三届天津青年科技奖和第五届中国侨界(创新成果)贡献奖。

代表成果

1. Lei Li, Yan Zhao, Qian Wang, Zheng-Yu Liu, Xiu-Guang Wang, En-Cui Yang, Xiao-Jun Zhao, Boosting photocatalytic hydrogen production activity by a microporous CuII-MOF nanoribbon decorated with Pt nanoparticles, Inorganic Chemistry Frontiers, 8 (2021), https://doi.org/10.1039/D1QI00516B;
2. Lei Li, Yan Zhao, Xiu-Guang Wang, Wei-Chao Song, Zheng-Guo Huang, Xiao-Jun Zhao, En-Cui Yang, The first 2,6-di(1,6-naphthyridin-2-yl)pyridine-based redox photochromic coordination polymer platform with selective vapochromism for trolamine, Inorganic Chemistry Frontiers, 8(2021), https://doi.org/10.1039/D1QI00683E;
3. Yu-Feng Qi, Qian Wang, Xiu-Guang Wang, Zheng-Yu Liu, Xiao-Jun Zhao and En-Cui Yang, Self-supported Co-doped FeNi carbonate hydroxide nanosheet array as a highly efficient electrocatalyst towards the oxygen evolution reaction in alkaline solution, Nanoscale, 11(2019). https://doi.org/10.1039/C9NR01735F;
4. En-Cui Yang, Yuan-Yuan Zhang, Zhong-Yi Liu, Xiao-Jun Zhao, Diverse Self-Assembly from Predesigned Conformationally Flexible Pentanuclear Clusters Observed in a Ternary Copper(II)–Triazolate–Sulfoisophthalate System: Synthesis, Structure, and Magnetism, Inorganic Chemistry, 53(2014), https://doi.org/10.1021/ic402280p;
5. Han-Wen Yang, Ping Xu, Bo Ding, Xiu-Guang Wang, Zheng-Yu Liu, Hong-Kun Zhao, Xiao-Jun Zhao, En-Cui Yang, Isostructural Lanthanide Coordination Polymers with High Photoluminescent Quantum Yields by Effective Ligand Combination: Crystal Structures, Photophysical Characterizations, Biologically Relevant Molecular Sensing, and Anti-Counterfeiting Ink Application, Crystal Growth & Design, 20 (2020), https://doi.org/10.1021/acs.cgd.0c00544;
6. Zhong-Yi Liu, Hong Zhao, Wei-Chao Song, Xiu-Guang Wang, Zheng-Yu Liu, Xiao-Jun Zhao, En-Cui Yang, A dynamic microporous magnet exhibiting room-temperature thermal hysteresis, variable magnetic ordering temperatures and highly selective adsorption for CO2, Journal of Materials Chemistry C, 7(2019), https://doi.org/10.1039/C8TC03356K;
7. En-Cui Yang, Zhong-Yi Liu, Xiao-Yun Wu, Xiao-Jun Zhao, A 3D CoII framework with alternating vertex- and edge-sharing Δ-ribbons showing a two-step field-induced magnetic transition, Chemical Communications, 47(2011), https://doi.org/10.1039/C1CC12796A;
8. Yan Li, Qiu Shang, Yi-Quan Zhang, En-Cui Yang, and Xiao-Jun Zhao, Fine Tuning of the Anisotropy Barrier by Ligand Substitution Observed in Linear {Dy2Ni2} Clusters, Chemistry-A European Journal, 22(2016), https://doi.org/10.1002/chem.201603800;
9. Jianshuai Mu, Xin Zhao, Jie Li, En-Cui Yang, Xiao-Jun Zhao, Novel hierarchical NiO nanoflowers exhibiting intrinsic superoxide dismutase-like activity, Journal of Materials Chemistry B, (4)2016, https://doi.org/10.1039/C6TB01390B;
10. 杨恩翠，赵小军，张超，刘瑞；近红外发光稀土配合物材料及其制备方法与应用; 2015年、CN201510805569.X；2017年、CN201510805569.X;

*以上信息由高级会员个人更新和维护。