毕锡和

男， 东北师范大学化学学院， 教授/研究员/教授级高工或同等级别

学习/工作经历

1996-09~2000-07 东北师范大学化学系 本科生
2000-09~2006-07 东北师范大学化学学院 研究生
2006-08~2006-09 德国波恩歌德学院 学生
2006-10~2008-12 德国波恩大学凯库勒研究所 博士后
2006-07~2008-12 东北师范大学化学学院 讲师
2009-01~2013-12 东北师范大学化学学院 副教授
2014-01~至今 东北师范大学化学学院 教授

研究领域和兴趣

银催化有机合成与机理研究

主要业绩

2019药明康德生命化学研究奖
2019 英国皇家协会牛顿高级学者
2018 吉林省科学技术奖自然科学一等奖（排名第一）
2018英国皇家化学会会士（FRSC）
2016教育部“长江学者奖励计划”青年学者
2015 国家自然科学基金委“优秀青年科学基金”
2014 Thieme Chemistry Journals Award
2013 入选教育部新世纪优秀人才支持计划
2006 获得德国洪堡基金会研究奖学金

代表成果

论文：
1. Xinyu Zhang, Chunqi Tian, Zhanjing Wang, Paramasivam Sivaguru, Steven P. Nolan, and Xihe Bi*, Fluoroalkyl N-Triftosylhydrazones as Easily Decomposable Diazo Surrogates for Asymmetric [2 + 1] Cycloaddition: Synthesis of Chiral Fluoroalkyl Cyclopropenes and Cyclopropanes. ACS Catal.2021. DOI:10.1021/acscatal.1c01483
2. Zikun Wang, Linxuan Li, Xueying Zhang, and Xihe Bi*, Silver-catalyzed Unstrained C(CO)–alkyl Bond Scission via [3+2]/retro-[3+2] Cycloaddition of Ketones with N-isocyanoiminotriphenylphosphorane
Sci. China Chem.2021, 64, 1157-1163. DOI: 10.1007/s11426-021-1000-8
3. Yong Wu, Shanshan Cao, Iskander Douair, Laurent Maron*, and Xihe Bi*, Computational Insights into Different Mechanisms for Ag‐, Cu‐, and Pd‐Catalyzed Cyclopropanation of Alkenes and Sulfonyl Hydrazones. Chem. Eur. J.2021, 67, 5999-6006.DOI: 10.1002/chem.202005193
4.Zhaohong Liu, Shanshan Cao, Weijie Yu, Jiayi Wu, Fanhua Yi, Edward A.Anderson and Xihe Bi*, Site-Selective C–H Benzylation of Alkanes with N-Triftosylhydrazones Leading to Alkyl Aromatics. Chem 2020, 6, 2110–2124. DOI: 10.1016/j.chempr.2020.06.031
5. Yongquan Ning, Paramasivam Sivaguru, Giuseppe Zanoni, Edward A. Anderson and Xihe Bi*, Synthesis of β-DifluoroalkylAzides via Elusive 1,2-Azide Migration. Chem 2020, 6, 486–496. DOI: 10.1016/j.chempr.2019.12.004
6. Zikun Wang, Zhansong Zhang, Wanjun Zhao, Paramasivam Sivaguru, Giuseppe Zanoni,Yingying Wang, Edward A. Anderson and Xihe Bi*, Synthetic exploration of sulfinyl radicals using sulfinyl sulfones. Nat. Commun. 2021, in revision.
7. Xinyu Zhang, Zhaohong Liu, Xiangyu Yang, Yuanqing Dong, MatteoVirelli, Giuseppe Zanoni, Edward A. Anderson and Xihe Bi*, Trifluoroacetaldehyde N-tfsylhydrazone (TFHZ-Tfs): A new trifluorodiazoethane surrogate. Nat. Commun. 2018, 10, 284.
8. Shanshan Cao, Qinghe Ji, Huaizhi Li, Maolin Pang*, Haiyan Yuan, Jingping Zhang* and Xihe Bi*, AgN3-Catalyzed Hydroazidation of Terminal Alkynes and Mechanistic Studies. J. Am. Chem. Soc. 2020, 142, 7083–7091. DOI: 10.1021/jacs.0c00836
9. Yang Li, Yujie Liang, Junchao Dong, Yi Deng, Chunyang Zhao, Zhongmin Su, Wei Guan*, Xihe Bi*, Qun Liu, Junkai Fu*, Directed Copper-Catalyzed Intermolecular Aminative Difunctionalization of Unactivated Alkenes. J. Am. Chem. Soc. 2019, 141, 18475–18485. DOI: 10.1021/jacs.9b07607
10. Binbin Liu, Yongquan Ning, Matteo Virelli, Giuseppe Zanoni, Edward A. Anderson and Xihe Bi*, Direct Transformation of Terminal Alkynes into Amidines by a Silver-Catalyzed Four-Component Reaction. J. Am. Chem. Soc. 2019, 141, 1593–1598. DOI: 10.1021/jacs.8b11039
11. Chunlin Tang, Ran Zhang, Bo Zhu, Junkai Fu*, Yi Deng, Li Tian, Wei Guan* and Xihe Bi*, Directed Copper-Catalyzed Intermolecular Heck-Type Reaction of Unactivated Olefins and Alkyl Halides. J. Am. Chem. Soc. 2018, 140, 16929–16935. DOI: 10.1021/jacs.8b10874
12. Yongquan Ning, Xinyu Zhang, Yi Gai, Yuanqing Dong, Paramasivam Sivaguru, Yingying Wang, Bhoomireddy Rajendra Prasad Reddy, Giuseppe Zanoni and Xihe Bi*, Difluoroacetaldehyde N-Triftosylhydrazone (DFHZ-Tfs) as a Bench-Stable Crystalline Diazo Surrogate for Diazoacetaldehyde and Difluorodiazoethane. Angew. Chem. Int. Ed. 2020, 59, 6473–6481. DOI: 10.1002/anie.202000119
13. Zhaohong Liu, Paramasivam Sivaguru, Giuseppe Zanoni, Edward A. Anderson and Xihe Bi*, Catalyst-Dependent Chemoselective Formal Insertion of Diazo Compounds into C−C or C−H Bonds of 1,3-Dicarbonyl Compounds. Angew. Chem. Int. Ed. 2018, 57, 8927–8931. DOI: 10.1002/anie.201802834
14. Yongquan Ning, Qinghe Ji, Peiqiu Liao, Edward A. Anderson and Xihe Bi*, Silver-Catalyzed Stereoselective Aminosulfonylation of Alkynes, Angew. Chem. Int. Ed. 2017, 56, 13805–13808. DOI: 10.1002/anie.201705122
15. Jianquan Liu, Zhenhua Liu, Peiqiu Liao, Lin Zhang, Tao Tu and Xihe Bi*, Silver-Catalyzed Cross-Coupling of Isocyanides and Active Methylene Compounds by a Radical Process. Angew. Chem. Int. Ed. 2015, 54, 10618–10622. DOI: 10.1002/anie.201504254
16. Zhenhua Liu, Jianquan Liu, Lin Zhang, Peiqiu Liao, Jinna Song and Xihe Bi*, Silver(I)-Catalyzed Hydroazidation of Ethynyl Carbinols: Synthesis of 2-Azidoallyl Alcohols. Angew. Chem. Int. Ed. 2014, 53, 5305–5309. DOI: 10.1002/anie.201310264
17. Zhongxue Fang, Jianquan Liu, Qun Liu and Xihe Bi*, [3+2] Cycloaddition of Propargylic Alcohols and α-Oxo Ketene Dithioacetals: Synthesis of Functionalized Cyclopentadienes and Further Application in a Diels–Alder Reaction. Angew. Chem. Int. Ed. 2014, 53, 7209–7213. DOI: 10.1002/anie.201403014
18. Lin Zhang, Xihe Bi*, Xiaoxue Guan, Xingqi Li, Qun Liu*, Badru-Deen Barry and Peiqiu Liao, Chemoselective Oxidative C(CO)C(methyl) Bond Cleavage of Methyl Ketones to Aldehydes Catalyzed by CuI with Molecular Oxygen. Angew. Chem. Int. Ed. 2013, 52, 11303–11307. DOI: 10.1002/anie.201305010
19. Jianquan Liu, Zhongxue Fang, Qian Zhang*, Qun Liu and Xihe Bi*, Silver-Catalyzed Isocyanide-Alkyne Cycloaddition: A General and Practical Method to Oligosubstituted Pyrroles. Angew. Chem. Int. Ed. 2013, 52, 6953–6957.DOI: 10.1002/anie.201302024
20. Tao Xiong, Yan Li, Xihe Bi* and Qian Zhang*, Copper-catalyzed Dehydrogenative cross-coupling reactions of N-para-tolylamides through successive C–H activation: synthesis of 4H-3,1-benzoxazines. Angew. Chem. Int. Ed. 2011, 50, 7140–7143. DOI: 10.1002/anie.201101391
21. Xinyu Zhang, Chunqi Tian, Zhanjing Wang, Paramasivam Sivaguru, Steven P. Nolan and Xihe Bi*, Fluoroalkyl N-Triftosylhydrazones as Easily Decomposable Diazo Surrogates for Asymmetric [2 + 1] Cycloaddition: Synthesis of Chiral Fluoroalkyl Cyclopropenes and Cyclopropanes. ACS Catal. 2021, accepted. DOI:10.1021/acscatal.1c01483
22. Zhaohong Liu, Shanshan Cao, Jiayi Wu, Giuseppe Zanoni, Paramasivam Sivaguru and Xihe Bi*, Palladium(II)-Catalyzed Cross-Coupling of Diazo Compounds and Isocyanides to Access Ketenimines. ACS Catal. 2020, 10, 12881–12887. DOI: 10.1021/acscatal.0c02867
23. Yongquan Ning, Aroonroj Mekareeya, Kaki Raveendra Babu, Edward A. Anderson* and Xihe Bi*, Silver-Catalyzed C-to N-Center Remote Arene Migration. ACS Catal. 2019, 9, 4203–4210.DOI: 10.1021/acscatal.9b00500
24. Pin Xiao, Haiyan Yuan, Jianquan Liu, Yiying Zheng, Xihe Bi* and Jingping Zhang*, Radical Mechanism of Isocyanide-Alkyne Cycloaddition by Multicatalysis of Ag2CO3, Solvent, and Substrate. ACS Catal. 2015, 5, 6177–6184.DOI: 10.1021/acscatal.5b01703
25. Zhaohong Liu, Xinyu Zhang, Matteo Virelli, Giuseppe Zanoni, Edward A. Anderson and Xihe Bi*, Silver-Catalyzed Regio- and Stereoselective Formal Carbene Insertion into Unstrained C−C σ-Bonds of 1,3-Dicarbonyls. iScience 2018, 8, 54–60. DOI: 10.1016/j.isci.2018.09.006
26. Zikun Wang, Linxuan Li , Xueying Zhang and Xihe Bi*, Silver-catalyzed unstrained C(CO)–alkyl bond scission via [3+2]/retro-[3+2] cycloaddition of ketones with N-isocyanoiminotriphenylphosphorane, Sci. China Chem. 2021, 64,1157-1163. DOI: 10.1007/s11426-021-1000-8
27. Yi Gai, Yongquan Ning, Paramasivam Sivaguru, Xiaomeng Li, Yue Zhao, Jiayi Wu and Xihe Bi*, Neighbouring carbonyl group-assisted sequential 1,2-azide and 1,4-oxygen migrations of vinyl azides leading to α-azido ketones. Sci. China Chem. 2020, 63, 460–466. DOI: 10.1007/s11426-019-9686-x
28. Huaizhi Li, Bhoomireddy Rajendra Prasad Reddy and Xihe Bi*, Transformation of Alkynes into α- or β-Difluorinated Alkyl Azides by an Efficient One-Pot Two-Step Procedure, Org. Lett.2019, 21, 9358-9362. DOI: 10.1021/acs.orglett.9b03593
29. Yan Wang, Rui Guan, Paramasivam Sivaguru, Xuefeng Cong and Xihe Bi*, Silver-Catalyzed anti-Markovnikov Hydroboration of C–C Multiple Bonds, Org. Lett.2019, 21, 4035–4038. DOI: 10.1021/acs.orglett.9b01217
30. Yan Wang, Baobiao Dong, Zikun Wang*, Xuefeng Cong and Xihe Bi*, Silver-Catalyzed Reduction of Quinolines in Water, Org. Lett. 2019, 21, 3631–3634. DOI: 10.1021/acs.orglett.9b01055
31. Fanhua Yi, Wanjun Zhao, Zikun Wang* and Xihe Bi*, Silver-Mediated [3 + 2] Cycloaddition of Alkynes and N-Isocyanoiminotriphenylphosphorane: Access to Monosubstituted Pyrazoles, Org. Lett. 2019, 21, 3158–3161. DOI: 10.1021/acs.orglett.9b00860
32. Jian-Quan Liu, Xuanyu Shen, Yihan Wang, Xiang-Shan Wang* and Xihe Bi*, [3 + 2] Cycloaddition of Isocyanides with Aryl Diazonium Salts: Catalyst-Dependent Regioselective Synthesis of 1,3- and 1,5-Disubstituted 1,2,4-Triazoles, Org. Lett.2018, 20, 6930–6933. DOI: 10.1021/acs.orglett.8b03069
33. Yang Li, Ran Zhang, Xihe Bi* and Junkai Fu*, Multifunctionalization of Unactivated Cyclic Ketones via Synergistic Catalysis of Copper and Diarylamine: Access to Cyclic α-Enaminone, Org. Lett. 2018, 20, 1207–1211.DOI: 10.1021/acs.orglett.8b00125
34. Zhaohong Liu, Xinyu Zhang, Giuseppe Zanoni and Xihe Bi*, Silver-Catalyzed Cyclopropanation of Alkenes Using N-Nosylhydrazones as Diazo Surrogates, Org. Lett.2017, 19, 6646–6649. DOI: 10.1021/acs.orglett.7b03374
35. Yongquan Ning, Xue-Feng Zhao, Yan-Bo Wu* and Xihe Bi*, Radical Enamination of Vinyl Azides: Direct Synthesis of N-Unprotected Enamines, Org. Lett. 2017, 19, 6240–6243.DOI: 10.1021/acs.orglett.7b03204
36. Hannan Wang, Pengbing Mi, Wanjun Zhao, Ravi Kumar and Xihe Bi*, Silver-Mediated Direct C–H Cyanation of Terminal Alkynes with N-Isocyanoiminotripheny lphosphorane, Org. Lett. 2017, 19, 5613–5616. DOI: 10.1021/acs.orglett.7b02743
37. Jiawei Tang, Paramasivam Sivaguru, Yongquan Ning, Giuseppe Zanoni and Xihe Bi*, Silver-Catalyzed Tandem C≡C Bond Hydroazidation/Radical Addition/Cyclization of Biphenyl Acetylene: One-Pot Synthesis of 6-Methyl Sulfonylated Phenanthridines, Org. Lett. 2017, 19, 4026–4029. DOI: 10.1021/acs.orglett.7b01771
38. Yang Li, Ran Zhang, Arshad Ali, Jing Zhang, Xihe Bi*and Junkai Fu*, Synthesis of 6-Substituted Piperidin-3-ones via Rh(II)-Catalyzed Transannulation of N-Sulfonyl-1,2,3-triazoles with Electron-Rich Aromatic Nucleophiles, Org. Lett. 2017, 19, 3087–3090.DOI: 10.1021/acs.orglett.7b01180
39. Rui Wang, Wei Guan, Zheng-Bo Han, Fushun Liang*, Takeo Suga, Xihe Bi* and Hiroyuki Nishide*, Ambient-Light-Promoted Three-Component Annulation: Synthesis of Perfluoroalkylated Pyrimidines, Org. Lett. 2017, 19, 2358–2361.DOI: 10.1021/acs.orglett.7b00894
40. Guichun Fang, Jianquan Liu, Junkai Fu*, Qun Liu and Xihe Bi*, Silver-Catalyzed Cascade Reaction of β-Enaminones and Isocyanoacetates to Construct Functionalized Pyrroles, Org. Lett. 2017, 19, 1346–1349. DOI: 10.1021/acs.orglett.7b00201
41. Pengbing Mi, Rapolu Kiran Kumar, Peiqiu Liao and Xihe Bi*, Tandem O–H Insertion/[1,3]-Alkyl Shift of Rhodium Azavinyl Carbenoids with Benzylic Alcohols: A Route To Convert C–OH Bonds into C–C Bonds, Org. Lett. 2016, 18, 4998–5001. DOI: 10.1021/acs.orglett.6b02459
42. Zhaocheng Zhang, Rapolu Kiran Kumar, Guangzhi Li, Dongmei Wu* and Xihe Bi*, Synthesis of 4-Ynamides and Cyclization by the Vilsmeier Reagent to Dihydrofuran-2(3H)-ones, Org. Lett. 2015, 17, 6190-6193.DOI: 10.1021/acs.orglett.5b03189
43. Zhongxue Fang, Ying Liu, Badru-Deen Barry, Peiqiu Liao and Xihe Bi*, Formation of Benzo[f]-1-indanone Frameworks by Regulable Intramolecular Annulations of gem-DialkylthioTrienynes, Org. Lett. 2015, 17, 782–785.DOI: 10.1021/ol5034332
44. Yongquan Ning, Nannan Wu, Haifeng Yu, Peiqiu Liao, Xingqi Li and Xihe Bi*, Silver-Catalyzed Tandem Hydroazidation/Alkyne-Azide Cycloaddition of Diynes with TMS-N3: An Easy Access to 1,5-Fused 1,2,3-Triazole Frameworks, Org. Lett. 2015, 17, 2198–2201. DOI: 10.1021/acs.orglett.5b00784
45. Jianquan Liu, Zhenhua Liu, Peiqiu Liao and Xihe Bi*, Modular Synthesis of Sulfonyl Benzoheteroles by Silver-Catalyzed Heteroaromatization of Propargylic Alcohols with p-Toluenesulfonylmethyl Isocyanide (TosMIC): Dual Roles of TosMIC, Org. Lett. 2014, 16, 6204–6207.DOI: 10.1021/ol5031316
46. Zhenhua Liu, Peiqiu Liao and Xihe Bi*, General Silver-Catalyzed Hydroazidation of Terminal Alkynes by Combining TMS-N3 and H2O: Synthesis of Vinyl Azides, Org. Lett. 2014, 16, 3668–3671.DOI: 10.1021/ol501661k
47. Zhongxue Fang, Yongquan Ning, Pengbing Mi, Peiqiu Liao and Xihe Bi*, Catalytic C–H α-Trifluoromethylation of α,β-Unsaturated Carbonyl Compounds, Org. Lett. 2014, 16, 1522–1525.DOI: 10.1021/ol5004498
48. Guichun Fang, Jichun Li, Yeming Wang, Mingyu Gou, Qun Liu, Xingqi Li* and Xihe Bi*, An Atom-Economic Route to Thiophenes and 2,2’-Bithiophenes by Intramolecular Transannulation of gem-Dialkylthio Enynes, Org. Lett. 2013, 15, 4126–4129. DOI: 10.1021/ol4017854
49. Ying Liu, Badru-Deen Barry, Haifeng Yu, Jianquan Liu, Peiqiu Liao* and Xihe Bi*, Regiospecific 6-endo-Annulation of in situ Generated 3,4-Dienamides/acids: Synthesis of δ-Lactams and δ-Lactones, Org. Lett. 2013, 15, 2608–2611. DOI: 10.1021/ol4007772
50. Lin Zhang, Zhenhua Liu, Huiqin Li, Guichun Fang, Badru-Deen Barry, Tuemay Abadi Belay, Xihe Bi*, and Qun Liu*, Copper-Mediated Chelation-Assisted Ortho Nitration of (Hetero)arenes, Org. Lett. 2011, 13, 6536–6539. DOI: 10.1021/ol2028288
51. Yeming Wang, Xihe Bi*, Wei-Qi Li, Dehua Li, Qian Zhang, Qun Liu and Brim Stevy Ondon,
Iron-catalyzedaminolysis of β-carbonyl 1,3-dithianes: synthesis of stereodefined β-enaminones and 3,4-disubstituted pyrazoles, Org. Lett. 2011, 13, 1722–1725. DOI: 10.1021/ol200246x
52. Zhaohong Liu, Qiangqiang Li, Yang Yang and Xihe Bi*, Silver(I)-Promoted Insertion Into X–H (X = Si, Sn, And Ge) Bonds with N-Nosylhydrazones, Chem. Commun. 2017, 53, 2503–2506.DOI: 10.1039/C6CC09650F
53. Xiaoshan Huang, Xuefeng Cong, PengbingMi and Xihe Bi*, Azomethine-Isocyanide [3+2] Cycloaddition to Imidazoles Promoted by Silver and DBU, Chem. Commun. 2017, 53, 3858–3861.DOI: 10.1039/C7CC00772H
54. Zonglian Yang, Rapolu Kiran Kumar, Peiqiu Liao, Zhaohong Liu, Xingqi Li and Xihe Bi*, Chemo- and Regioselective Reductive Deoxygenation of 1-En-4-Yn-Ols Into 1,4-Enynes Through FeF3 and TfOH Co-Catalysis, Chem. Commun. 2016, 52, 5936–5939. DOI: 10.1039/C5CC10518H
55. Rapolu Kiran Kumara and Xihe Bi*, Catalytic σ-Activation of Carbon–Carbon Triple Bonds: Reactions of Propargylic Alcohols and Alkynes, Chem. Commun. 2016, 52, 853–868. DOI: 10.1039/C5CC08386A
56. Xianyu Meng, Peiqiu Liao, Jianquan Liu and Xihe Bi*, Silver-Catalyzed Cyclization of 2-Pyridyl Alkynyl Carbinols with Isocyanides: Divergent Synthesis of Indolizines and Pyrroles, Chem. Commun. 2014, 50, 11837–11839. DOI: 10.1039/C4CC04905E
57. Zikun Wang, Xihe Bi*, Peiqiu Liao, Xu Liu and Dewen Dong*, Cu(II)-Catalyzed Cyclization of α-Diazo-β-Oxoamides with Amines Leading to Pyrrol-3(2H)-Ones, Chem. Commun. 2013, 49, 1309–1311.DOI: 10.1039/C2CC38473F
58. Zhongxue Fang, Haiyan Yuan, Ying Liu, Zixun Tong, Huiqin Li, Jin Yang, Badru-Deen Barry, Jianquan Liu, Peiqiu Liao, Jingping Zhang*, Qun Liu* and Xihe Bi*, gem-Dialkylthiovinylallenes: alkylthio-regulated reactivity and application in the divergent synthesis of pyrroles and thiophenes, Chem. Commun. 2012, 48, 8802–8804.DOI: 10.1039/C2CC33857B
59. Zikun Wang, Xihe Bi*, Peiqiu Liao, Rui Zhang, Yongjiu Liang and Dewen Dong*, Intramolecular hydrogen bonding-assisted cyclocondensation of α-diazoketones with various amines: a strategy for highly efficient Wolff 1,2,3-triazole synthesis, Chem. Commun. 2012, 48, 7076–7078.DOI: 10.1039/C2CC33157H
60. Yinqiao Hu, Xiaolan Fu, Badru-Deen Barry, Xihe Bi* and Dewen Dong*, Regiospecific β-lactam ring-opening/recyclization reactions of N-aryl-3-spirocyclic-β-lactams catalyzed by a Lewis–Brønsted acids combined superacid catalyst system: a new entry to 3-spirocyclicquinolin-4(1H)-ones, Chem. Commun. 2012, 48, 690–692.DOI: 10.1039/C1CC15881C
61. Yeming Wang, Xihe Bi*, Dehua Li, Peiqiu Liao, Yidong Wang, Jin Yang, Qian Zhang* and Qun Liu, Iron-catalyzed synthesis of polysubstitutedpyrrolesvia [4C+1N] cyclization of 4-acetylenic ketones with primary amines, Chem. Commun. 2011, 47, 809–811. DOI: 10.1039/C0CC03802D
62. Yeming Wang, Wei-Qi Li, Guangbo Che, Xihe Bi*, Peiqiu Liao, Qian Zhang and Qun Liu*, Catalytic intramolecular aromatic C–H alkenylation of arenes with non-activated ketones: synthesis of 4-alkylene quinolin-2-ones, Chem. Commun. 2010, 46, 6843–6845.DOI: 10.1039/C0CC01758B
63. Yang Yang, Zhaohong Liu, Alessio Porta, Giuseppe Zanoni and Xihe Bi*, Alkynyl N-Nosylhydrazones: Easy Decomposition to Alkynyl Diazomethanes and Application in Allene Synthesis, Chem. Eur. J. 2017, 23, 9009–9013.DOI: 10.1002/chem.201701462
64. Zhaohong Liu, Qiangqiang Li, Peiqiu Liao and Xihe Bi*, Silver-Catalyzed [2+1] Cyclopropenation of Alkynes with Unstable Diazoalkanes: N-Nosylhydrazones as Room-Temperature Decomposable Diazo Surrogates, Chem. Eur. J. 2017, 23, 4756–4760. DOI: 10.1002/chem.201605335
65. Pengbing Mi, Peiqiu Liao, Tao Tu and Xihe Bi*, Decarbonylative C-C Bond-Forming Reactions of Saccharins by Nickel Catalysis: Homocoupling and Cycloaddition, Chem. Eur. J. 2015, 21, 5332–5336. DOI: 10.1002/chem.201406227
66. Zhaohong Liu, Peiqiu Liao and Xihe Bi*, Lewis and Brønsted Acid Cocatalyzed Reductive Deoxyallenylation of Propargylic Alcohols with 2-Nitrobenzenesulfonylhydrazide, Chem. Eur. J. 2014, 20, 17277–17281.DOI: 10.1002/chem.201404692
67. Jianquan Liu, Zhenhua Liu, Nannan Wu, Peiqiu Liao and Xihe Bi*, Silver-Catalyzed Cross-Coupling of Propargylic Alcohols with Isocyanides: An Atom-Economical Synthesis of 2,3-Allenamides, Chem. Eur J. 2014, 20, 2154–2158. DOI: 10.1002/chem.201304255
68. Zhaohong Liu, Kaki Raveendra Babu, Feng Wang, Yang Yang and Xihe Bi*, Influence of Sulfonyl Substituents on the Decomposition of N-Sulfonylhydrazones at Room Temperature, Org. Chem. Front. 2019, 6, 121–124. DOI: 10.1039/C8QO00802G
69. Jian-Quan Liu, Xinyi Chen, Xuanyu Shen, Yihan Wang, Xiang-Shan Wang and Xihe Bi*, Silver-Catalyzed Sequential Cascade Reaction of Isocyanides with 1-(2-Ethynyl-phenyl)-prop-2-yn-1-ol: Access to Benzo[b]fluorenes and Benzofuran-Pyrroles, Adv. Synth. Catal. 2019, 361, 1543–1548. DOI: 10.1002/adsc.201801344
70. Ran Zhang, Yang Li, Arshad Ali, Jiamin Hao, Xihe Bi* and Junkai Fu*, Rh(II)-Catalyzed Tandem Cyclization of Aliphatic N-Sulfonyl-1,2,3-triazoles and Alcohols for the Synthesis of 6-Alkoxy Piperidin-3-ones, Adv. Synth. Catal. 2017, 359, 4057–4061.DOI: 10.1002/adsc.201700882
71. Shijie Xu, Jianquan Liu, Donghua Hu* and Xihe Bi*, Metal-Free Hydroacyloxylation and Hydration Reactions of Ynamides: Synthesis of Α-Acyloxyenamides and N-Acylsulfonamides, Green Chem. 2015, 17, 184–187. DOI: 10.1039/C4GC01328J
72. Kai Wang, Xihe Bi*, Shuangxi Xing, Peiqiu Liao, Zhongxue Fang, Xianyu Meng, Qian Zhang*, Qun Liu and Yu Ji, Cu2O acting as a robust catalyst in CuAAC reactions: water is the required medium, Green Chem. 2011, 13, 562–565. DOI: 10.1039/C0GC00848F
专利：
1、毕锡和; 张欣宇; 一种氟烷基磺酰腙的制备方法;2018,CN201810237625.8;2020, CN108484452A
2、毕锡和; 季庆贺; 曹姗姗;大量制备α-乙烯基叠氮类化合物的合成方法;2017, CN201711471861.8;2020, CN108178736B
3、毕锡和; 宁永泉; 张欣宇;一种氟叠氮取代的四元杂环化合物的制备和应用;2019, CN201910937348.6;2020, CN110759843A
4、毕锡和; 孙越; 张欣宇;新型三氟甲基吡唑类化合物合成方法;2019, CN201910490572.5;2019, CN110183382A
5、毕锡和; 宁永泉; 张欣宇;一种β-偕二氟叠氮化合物及其制备和应用;2019, CN201910490666.2;2019, CN110105237A
6、毕锡和; 刘兆洪; 刘宾宾; 张欣宇;一种全氟烷基重氮甲烷的制备方法及其应用;2017, CN201711136096.4;2020, CN107739317B
7、毕锡和; 宁永泉; 张欣宇;一种α-偕二氟叠氮化合物及其制备方法和应用;2019, CN201910349196.8;2019, CN110015973A
8、毕锡和; 刘兆洪; 杨旸; 李强强;一种温和的重氮甲烷衍生物的制备方法;2016, CN201611024920.2;2019, CN106608788B
9、毕锡和; 王宏伟; 张林; 刘兆洪; 唐春霖;一种三取代咪唑类化合物的合成方法;2016, CN201610400867.5;2019, CN106045914B
10、毕锡和; 张欣宇; 杨翔宇;制备三氟甲基高烯丙基或联烯基硫醚的新方法;2018, CN201810679626.8;2018, CN108727235A
11、毕锡和; 张欣宇;一种氟烷基磺酰腙的制备方法;2018, CN201810237625.8;2018, CN108484452A
12、毕锡和; 季庆贺; 曹姗姗;大量制备α-乙烯基叠氮类化合物的合成方法;2017, CN201711471861.8;2018, CN201711471861.8
13、毕锡和; 刘兆洪; 刘宾宾; 张欣宇;一种全氟烷基重氮甲烷的制备方法及其应用; 2017,CN201711136096.4;2018, CN201711136096.4
14、毕锡和; 刘兆洪; 杨旸; 李强强;一种温和的重氮甲烷衍生物的制备方法;2016, CN201611024920.2;2017, CN106608788A
15、毕锡和; 王宏伟; 张林; 刘兆红; 唐春霖;一种三取代咪唑类化合物的合成方法;2016, CN201610400867.5;2016, CN106045914A
16、毕锡和; 张林; 孙莉;一种双核银三联吡啶配合物的制备方法;2016, CN201610314469.1;2016, CN105949223A
17、李兴奇; 毕锡和; 弥鹏兵; 孟宪宇;一价银催化苯基、杂环硼酸的脱硼化的方法及其应用;2014, CN201410151823.4;2014, CN103910591A
18、毕锡和; 房忠雪; 宋金娜;一类有机小分子荧光染料的制备方法及其应用;2014, CN201410139908.0;2014, CN103897427A
19、毕锡和; 刘振华;α-羟基烯基叠氮类化合物的合成方法;2013, CN201310585444.1;2014, CN103664686A
20、毕锡和; 刘振华;一种合成烯基叠氮孕酮的方法;2013, CN201310585722.3;2014, CN103613631A
21、毕锡和; 方桂春; 张林; 廖沛球;铜催化的咪唑并[1, 2-a]吡啶

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