徐国海

男， 赣南师范大学化学化工学院， 教授/研究员/教授级高工或同等级别

学习/工作经历

1998年9月-2002年7月，东北师范大学化学教育专业，获学士学位；
2003年9月-2006年7月，东北师范大学无机化学专业，获硕士学位(导师：马建方教授)；
2006年9月-2010年1月，中国科学院长春应用化学研究所无机化学专业，获博士学位(导师：王成研究员)；
2015年12月-2016年7月，美国德州大学圣安东尼奥分校(University of Texas at San Antonio)，访问学者(合作导师：陈邦林教授)；
2016年8月-2016年12月，美国国家标准与技术研究院(National Institute of Standards and Technology)，访问学者(合作导师：陈邦林教授、周炜研究员)。
2020年9月-2021年8月，中国科学院长春应用化学研究所稀土资源利用国家重点实验室，“西部之光”访问学者(合作导师：张洪杰院士)。
2010年4月-至今，赣南师范大学化工学院，教师（2013年获副教授，2016年获教授）。

研究领域和兴趣

MOFs，晶体学，功能配合物

主要业绩

主持国家自然科学基金两项，其他省厅级项目五项，至今以第一作者或通讯作者发表论文28篇，其中包含两篇JACS。授权国家发明专利1项。获江西省自然科学奖二等（第一完成人），入选江西省杰青人才资助计划，入库江西省高等教育教学专家，获批江西省一流课程《无机化学》。

代表成果

1) Tian Wang, Junan Duan, Hongliu Shi, Minmin Wang, Ping Lian*, Guohai Xu*, “Tuning topological networks in MOFs by secondary-building-unit connection: syntheses, structures and luminescent properties of two Zn4-cluster coordination polymers” Z. Anorg. Allg. Chem, 2022, 648(3), e202100315.
2) Jian-Fang Li, Peng Du, Ying-Ying Liu,* Guo-Hai Xu,* and Jian-Fang Ma,* “Three thiacalix[4]arene-based Cu(I) coordination polymers: catalytic activities for azide-alkyne cycloaddition reaction and luminescent properties’’ Dalton Trans, 2020, 49, 3715-3722.
3) Liu-Juan Yue, Ying-Ying Liu,* Guo-Hai Xu,* and Jian-Fang Ma,* “Calix[4]arene-based polyoxometalate organic-inorganic hybrid and coordination polymer as heterogeneous catalysts for azide-alkyne cycloaddition and Knoevenagel condensation reaction’’ New. J. Chem, 2019, 43, 15871-15878.
4) Li Wang, Ting-Ting Guo, Ji-Cheng Ma, Ying-Ying Liu,* Guo-Hai Xu,* and Jian-Fang Ma*. “Three Coordination Polymers Based on Resorcin[4]arene as Effective Catalysts for the Knoevenagel Condensation Reaction and as Multifunctional Luminescent Sensors’’ ChemistrySelect, 2019, 4, 7351-7357.
5) Xue Han, Jin Yang*, Ying-Ying Liu, Guo-Hai Xu*, Jian-Fang Ma*. “Metal ion induced single-crystal-to-single-crystal transformation and luminescent sensing properties of resorcin[4]arene-based metal–organic frameworks” Polyhedron, 2019, 161,145-153.
6) Yan-Li Liu, Lei Yan, Ying-Ying Liu*, Guo-Hai Xu*, Wen-Jing Shi, Jian-Fang Ma*. “Cu(I) coordination polymer based on pyridyl-functionalized resorcin[4]arene: selective detection of Cr2O72-, MnO4- and nitrobenzene and efficient catalyst” Polyhedron, 2019, 158,499-505.
7) Lei Xu, Jin Yang, Ying-Ying Liu*, Guo-Hai Xu*, Jian-Fang Ma*. “Structures and luminescent properties of five Cd(II) metal-organic frameworks assembled by imidazole-based thiacalix[4]arene ligand and ancillary dicarboxylic acids” Journal of Luminescence, 2019, 209, 398-403.
8) Yao Wang, Minghui He, Xiaoxia Gao, Xia Wang, Guohai Xu,* Zhengyi Zhang and Yabing He *. “A ligand conformation preorganization approach to construct a copper-hexacarboxylate framework with a novel topology for selective gas adsorption” Inorg. Chem. Front, 2019, 6, 263-270.
9) Guanghui Sun, Weilian Xie, Hong Xiao* and Guohai Xu*. “Controlled interpenetration of 44 networks: syntheses and structures of two Cu3-cluster coordination polymers” Acta Cryst. 2018, C74, 1540-1546.
10) Wenyuan Pei, Guohai Xu(共同一作), Jin Yang*, Hui Wu, Banglin Chen, Wei Zhou*, and Jianfang Ma*. “Versatile Assembly of Metal-Coordinated Calix[4]resorcinarene Cavitands and Cages through Ancillary Linker Tuning”. J. Am. Chem. Soc., 2017, 139, 7648-7656.
11) Guohai Xu, Bin Li,* Hui Wu, Wei Zhou,* and Banglin Chen*, “Construction of ntt-Type Metal-Organic Framework from C2-symmetry Hexacarboxylate Linker for Enhanced Methane Storage Capacities”. Cryst, Growth, Des. 2017, 17, 4795-4800.
12) Min Xie, Guohai Xu*. “Bis(triethanolamine)bis(μ2-trimesato)dicobalt(II): a CoII dimer with an unreported two-dimensional supramolecular topology formed from triethanolamine and trimesic acid ligands”. Acta Cryst. 2016. C72, 143-148.
13) Guohai Xu,* Min Xie, Xiaokang Li,* Wenjie Shi, Hui Yu, Yinhui Hu, Xiaochen Xun, and Yongrong Xie* “Four Binuclear Coordination Polymers with 63 Net and Self-Assembly of 2D 63 Topology into Different Supramolecular Networks Using Unit-Unit H-Bonds”. CrystEngComm, 2015, 17, 3677-3686.
14) Guohai Xu,* Jianyi Lv, Peng Guo, Zhonggao Zhou, Ziyi Du and Yongrong Xie* “Two ligand-length-tunable interpenetrating coordination networks with stable Zn2 unit as threeconnected uninode and supramolecular topologies”. CrystEngComm, 2013, 15, 4473-4482.
15) Guohai Xu,* Jianyi Lv, “Two Mn¬3 cluster-based frameworks with porosity tuned by solvent coordination/non-coordination: structural correlation and sorption properties”. Inorg. Chem. Commun, 2013, 37,214-218.
16) Guohai Xu,* Xiyun He, Jianyi Lv, Zhonggao Zhou, Ziyi Du, and Yongrong Xie* “Solvent-Dependent Assemblies of Trinuclear Copper Cluster into Variable Frameworks Based on Mixed Ligands of Polyalcohol Amines and Organic Carboxylates”. Cryst, Growth, Des. 2012, 12, 3619-3630
17) Xiyun He, Jianyi Lv and Guohai Xu*
“Poly[(μ3-benzene-1,4-dicarboxylato)-di-l-chlorido-(triethanolamine)dicadmium(II)]: a cadmium–halide coordination polymer with a hydrogen-bonded three-dimensional framework”. Acta Cryst. 2012. C68, m109-m112.
18) Guohai Xu* and Xiyun He.
“catena-Poly[1,1’-dimethyl-4,4’-(ethane-1,2-diyl)dipyridinium[lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]”. Acta Cryst. 2011. E67, m847.
19) Peng Guo, Jing Wang, Jun Wang, Daocheng Pan, Guohai Xu.* “Ag (I)-based 2D metal frameworks with helical structures decorated by the homochiral camphor-10-sulfonic acid”. Solid State Sciences. 2010. 12. 2091-2095.
20) Guohai Xu and Yongrong Xie.*
“Poly[aqua(μ2-benzene-1,4-dicarboxylato)(μ2-4,4’-bipyridine N,N’-dioxide)cadmium(II)], a threefold interpenetrating diamond net”. Acta Cryst. 2010, C66, m201-m203.
21) Peng Guo, Jing Wang, Dao-cheng Pan and Guo-Hai Xu.*
“Poly[diaquabis(μ3-hexamethylenetetramine)[μ2-2,2’-(piperazine-1,4-diyl)bis(ethanesulfonato)]disilver(I)]: a three-dimensional pillared-layer framework encapsulating a water chain of (H2O)12 clusters”. Acta Cryst. 2010, C66, m266-m268
22) Guohai Xu, Xiaoguang Zhang, Peng Guo, Chengling Pan, Hongjie Zhang* and Cheng Wang*, “MnII-based MIL-53 Analogues: Synthesis Using Neutral Bridging μ2-Ligands and Application in Liquid-Phase Adsorption and Separation of C6-C8 Aromatics”, J. Am. Chem. Soc. 2010, 132, 3656-3657.
23) Guohai Xu, Peng Guo, Shuyan Song, Hongjie Zhang,* and Cheng Wang*. “Molecular Nanocluster with a [Sn4Ga4Zn2Se20]8- T3 Supertetrahedral Core”. Inorg. Chem. 2009, 48, 4628-4630.
24) Guohai Xu, Cheng Wang* and Peng Guo. “Poly[[(pentaethylenehexamine)manganese(II)] [hepta-μ-selenido-tritin(IV)]]: a tin–selenium net with remarkable flexibility”. Acta Cryst. 2009, C65, m171-m173.
25) Guohai Xu, Jianfang Ma,* Haixia Yu, Shunli Li, Yingying Liu, Jin Yang, Zhongmin Su, and Chunfeng Shi. “A Series of New Organotin-Cyanometalate Compounds Based on Triorganotin, Diorganotin, and Organooxotin Clusters”. Organometallics. 2006, 25, 5996-6006.
26) Guohai Xu, Jianfang Ma,* Yingying Liu and Shunli Li. “Chloro(μ-6-methylpyridine-2-carboxylato)bis(6-methylpyridine-2-carboxylato)triphenylchromium(III)tin(IV) chlorotriphenyltin(IV)”. Acta Cryst. 2006, C62, m581-m583.
27) 不同维度金属有机配合物超分子化学及功能性研究，2014年江西省自然科学奖二等，徐国海，李小康，王成。
28) 徐国海，段军安，孙光辉，石红柳，王甜，周中高，手性微孔Pb(II)金属有机框架化合物及其制备方法和用途，国家发明专利，授权号ZL2021108360077。
29) 2022年江西省一流课程《无机化学》，徐国海，刘美玭，张世勇，罗序中，练萍。
30) 《无机化学实验》，胡乔生，练萍编著，徐国海（第八章），浙江大学出版社，2014，一月。

*以上信息由高级会员个人更新和维护。