孙頔

男， 山东大学化学与化工学院， 教授/研究员/教授级高工或同等级别

学习/工作经历

2001.09-2005.07, 聊城大学化学化工学院，本科学生
2005.09-2008.06, 厦门大学化学化工学院，硕士研究生
2008.09-2011.06, 厦门大学化学化工学院，博士研究生
2011.07-2014.08, 山东大学化学与化工学院，讲师
2014.09-2017.08, 山东大学化学与化工学院，副教授
2017.09-至今 山东大学化学与化工学院，教授

研究领域和兴趣

金属团簇化学；功能配合物

主要业绩

孙頔一直致力于功能配（簇）合物的设计合成、可控制备与性能研究；在合成方法学的探索、结构调变机制、组装机理、构效关系阐明等方面取得了多项具有创新性的科研成果。自2016至今，以通讯作者在CCS Chem (1篇), Proc. Natl. Acad. Sci. USA (1篇), Nature Comm. (4篇), J. Am. Chem. Soc., (6篇), Angew. Chem. Int. Ed., (6篇), Adv. Mater.,（1篇）等杂志发表高水平SCI论文100余篇。研究工作被Chem. Rev., Chem. Soc. Rev., Angew.Chem. Int. Ed., J. Am. Chem. Soc.等许多国际著名学术期刊论文引用。同时也被Science, Nat Rev Chem., ChemViews等学术组织或网站撰写专文亮点评述。论文被他引7000余次，H指数=49, ESI高被引论文12篇。主持国家自然科学基金委青年基金，面上项目，优秀青年基金各一项，霍英东教育基金会第十七届高等院校青年教师基金一项，中国博士后基金面上项目，特别资助项目各一项。主要研究方向：1）高核金属团簇的设计合成、结构、组装机理与性质； 2）功能晶体材料。

代表成果

[1] Z. Wang, H. F.Su, Y. Z. Tan, S. Schein,* S. C.Lin, W. Liu, S. A. Wang,W. G. Wang, C. H. Tung, D. Sun,* L. S. Zheng, Assembly of silver Trigons into a buckyball-like Ag180 nanocage, Proc Natl Acad Sci USA 114, (2017) 12132-12137.
[2] Y. K. Deng, H. F.Su, J. H. Xu,W. G. Wang, M. Kurmoo, S. C. Lin, Y. Z. Tan, J. Jia, D. Sun,* L. S. Zheng, Hierarchical Assembly of a {MnII15MnIII4} Brucite Disc: Step-by-Step Formation and Ferrimagnetism. J. Am. Chem. Soc., 138, (2016) 1328-1334.
[3] L. Y. Guo, H. F. Su, M. Kurmoo, C. H. Tung, D. Sun,* L. S. Zheng, Core−Shell {Mn7⊂(Mn,Cd)12} Assembled from Core {Mn7} Disc, J. Am. Chem. Soc., 139, (2017) 14033-14036.
[4] J. W. Liu, L. Feng, H. F. Su, Z. Wang, Q. Q. Zhao, X. P. Wang, C. H. Tung, D. Sun,* L. S. Zheng, Anisotropic Assembly of Ag52 and Ag76 Nanoclusters, J. Am. Chem. Soc., 140, (2018) 1600-1603.
[5] S. S. Zhang, F. Alkan, H. F. Su, C. M. Aikens,* C. H. Tung, D. Sun,* [Ag48(C≡CtBu)20(CrO4)7]: An Atomically Precise Silver Nanocluster Co-protected by Inorganic and Organic Ligands, J. Am. Chem. Soc., 141, (2019) 4460-4467.
[6] Z. Wang, J. W. Liu, H. F. Su, Q. Q. Zhao, M. Kurmoo, X. P. Wang, C. H Tung, D. Sun,* L. S. Zheng, Chalcogens-Induced Ag6Z4@Ag36 (Z = S or Se) Core–Shell Nanoclusters: Enlarged Tetrahedral Core and Homochiral Crystallization, J. Am. Chem. Soc., 141, (2019) 17884-17890.
[7] B. L. Han, Z. Liu, L. Feng, Z. Wang, R. K. Gupta, C. M. Aikens,* C. H. Tung, D. Sun,* Polymorphism in Atomically Precise Cu23 Nanocluster Incorporating Tetrahedral [Cu4]0 Kernel, J. Am. Chem. Soc., 142, (2020) 5834-5841.
[8] Y. M. Su, Z. Wang, C. H. Tung, D. Sun,* S. Schein, Keplerate Ag192 Cluster with 6 Silver and 14 Chalcogenide Octahedral and Tetrahedral Shells, J. Am. Chem. Soc., 143, (2021) 13235-13244.
[9] S.-S. Zhang, S. Havenridge, C. K. Zhang, Z. Wang, L. Feng, Z.-Y. Gao, C. M. Aikens, C.-H. Tung, Di Sun,* Sulfide Boosting Near-Unity Photoluminescence Quantum Yield of Silver Nanocluster, J. Am. Chem. Soc., 144, (2022) 18305-18314.
[10] W. Chen, Z. Wang, Q. Wang, K. El-Yanboui, K. Tan, H. M. Barkholtz, D.-J. Liu, P. Cai, L. Feng, Y. Li, J.-S. Qin, S. Yuan,* D. Sun,* H.-C. Zhou,* Monitoring the Activation of Open Metal Sites in [FexM3–x(μ3-O)] Cluster-Based Metal–Organic Frameworks by Single-Crystal X-ray Diffraction. J. Am. Chem. Soc., 145, (2023) 4736-4745.
[11] T. Jia, Z. J. Guan, C. Zhang, X. Z. Zhu, Y. X. Chen, Q. Zhang, Y. Yang,* D. Sun,* An Eight-Electron Superatomic Cu31 Nanocluster with Chiral Kernel and NIR-II Emission, J. Am. Chem. Soc., 145, (2023) 10355-10363.
[12] K. Sheng, Z. Wang, L. Li, Z.-Y. Gao, C.-H. Tung, D. Sun,* Solvent-Mediated Separation and Reversible Transformation of 1D Supramolecular Polymorphs Built from [W10O32]4– Templated 48-Nuclei Silver(I) Cluster, J. Am. Chem. Soc., 145, (2023) 10595-10603.
[13] Z. Wang, R. K. Gupta, F. Alkan, B. L. Han, L. Feng, X. Q. Huang, Z. Y. Gao, C. H. Tung, D. Sun,* Dicarboxylic Acids Induced Tandem Transformation of Silver Nanocluster, J. Am. Chem. Soc., 145, (2023) 19523-19532.
[14] J. Y. Liu, F. Alkan, Z. Wang, Z. Y. Zhang, M. Kurmoo, Z. Yan, Q. Q. Zhao, C. M. Aikens*, C. H. Tung, D. Sun*, Different Silver Nanoparticles in One Crystal: Ag210(iPrPhS)71(Ph3P)5Cl and Ag211(iPrPhS)71(Ph3P)6Cl, Angew. Chem. Int. Ed., 58, (2019) 195-199.
[15] J. W. Liu, Z. Wang, Y. M. Chai, M. Kurmoo, Q. Q. Zhao, X. P. Wang, C. H. Tung, D. Sun*, Core Modulation of 70-Nuclei Core-Shell Silver Nanoclusters, Angew. Chem. Int. Ed., 58, (2019) 6276-6279.
[16] Y. Yang*, T. Jia, Y.-Z. Han, Z.-A. Nan, S.-F. Yuan, F.-L. Yang , D. Sun*, An Unprecedented All-Alkynyl Protected 74-Nuclei Silver(I)-Copper(I)-Oxo Nanocluster: Oxo-Induced Hierarchical Bimetal Aggregation and Anisotropic Surface, Angew. Chem. Int. Ed., 58, (2019) 12280-12285.
[17] Z. Xie, P. Sun, Z. Wang, H. Li,* L. Yu, D. Sun*, M. Chen, Y. Bi, X. Xin,* J. Hao, Metal-Organic Gels from Silver Nanoclusters with Aggregation-Induced Emission and Fluorescence-to-Phosphorescence Switching, Angew. Chem. Int. Ed., 59, (2020) 9922-9927.
[18] C. Deng, C. Sun, Z. Wang, Y. Tao, Y. Chen, J. Lin, G. Luo,* B. Lin, D. Sun,* L. Zheng, A Sodalite-Type Silver Orthophosphate Cluster in a Globular Silver Nanocluster, Angew. Chem. Int. Ed., 59, (2020) 12659-12663.
[19] M. Zhao, S. Huang, Q. Fu, W. Li, R. Guo, Q. Yao, F. Wang, P. Cui,* C. H. Tung, D. Sun,* Ambient Chemical Fixation of CO2 Using a Robust Ag27 Cluster-Based Two-Dimensional Metal-Organic Framework, Angew. Chem. Int. Ed., 59, (2020) 20031-20036.
[20] W. J. Zhang, Z. Liu, K. P. Song, C. M. Aikens, S. S. Zhang, Z. Wang, C. H. Tung, D. Sun,* A 34-Electron Superatom Ag78 Cluster with Regioselective Ternary Ligands Shells and Its 2D Rhombic Superlattice Assembly, Angew. Chem. Int. Ed., 60, (2021) 4231-4237.
[21] P. P. Sun, B. L. Han, H. G. Li, C. K. Zhang, X. Xin, J. M. Dou, Z. Y. Gao, D. Sun,* Real-Time Fluorescent Monitoring of Kinetically Controlled Supramolecular Self-Assembly of Atom-Precise Cu8 Nanoclusters, Angew. Chem. Int. Ed., 61, (2022) e202200180.
[22] Z. Wang, L. Li, L. Feng, Z. Y. Gao, C. H. Tung, L. S. Zheng, D. Sun,* Solvent-Controlled Condensation of [Mo2O5(PTC4A)2]6- Metalloligand in Stepwise Assembly of Hexagonal and Rectangular Ag18 Nanoclusters, Angew. Chem. Int. Ed., 61, (2022) e202200823.
[23] Z. Wang, F. Alkan, C. M. Aikens, M. Kurmoo, Z. Y. Zhang, K. P. Song, C. H. Tung, D. Sun,* An Ultrastable 155-Nuclei Silver Nanocluster Protected by Thiacalix[4]arene and Cyclohexanethiol for Photothermal Conversion, Angew. Chem. Int. Ed., 61, (2022) e202206742.
[24] Z.-R. Yuan, Z. Wang, B.-L. Han, C.-K. Zhang, S.-S. Zhang, Z.-Y. Zhu, J.-H. Yu, T.-D. Li, Y.-Z. Li,* C.-H. Tung, D. Sun,* Ag22 Nanoclusters with Thermally Activated Delayed Fluorescence Protected by Ag/Cyanurate/Phosphine Metallamacrocyclic Monolayers through In-Situ Ligand Transesterification, Angew. Chem. Int. Ed., 61, (2022) e202211628.
[25] Q. Hu,* C. Zhang, X. Wu, G. Liang, L. Wang, X. Niu, Z. Wang, W.-D. Si, Y. Han, R. Huang, J. Xiao,* D. Sun,* Highly Effective Hybrid Copper(I) Iodide Cluster Emitter with Negative Thermal Quenched Phosphorescence for X-Ray Imaging, Angew. Chem. Int. Ed., 62, (2023) e202217784.
[26] G. L. Dong, Z. H. Pan, B. L. Han, Y. W. Tao, X. Chen, G. G. Luo*, P. P. Sun, C. F. Sun, D. Sun,* Multi-layer 3D Chirality and Double-Helical Assembly in a Copper Nanocluster with a Triple-Helical Cu15 Core, Angew. Chem. Int. Ed., 62, (2023) e202302595.
[27] G. G. Luo,* Z. Pan, B. Han, G. L. Dong, C. L. Cheng, M. Azam, Y. W. Tao, J. He, C. F. Sun, D. Sun,* Total Structure, Electronic Structure and Catalytic Hydrogenation Activity of Metal-Deficient Chiral Polyhydride Cu57 Nanoclusters, Angew. Chem. Int. Ed., 62, (2023) e202306849.
[28] Q. J. Wu, D. H. Si, P. Sun, Y. L. Dong, S. Zheng, Q. Chen, S. H. Ye, D. Sun,* R. Cao,* Y. B. Huang,* Atomically Precise Copper Nanoclusters for Highly Efficient Electroreduction of CO2 towards Hydrocarbons via Breaking the Coordination Symmetry of Cu Site, Angew. Chem. Int. Ed., 62, (2023) e202306822.
[29] Z. Wang, H. F. Su, C. H. Tung, D. Sun,* L. S. Zheng, Deciphering synergetic core-shell transformation from [Mo6O22@Ag44] to [Mo8O28@Ag50], Nat. Commun., 9, (2018) 4407.
[30] Z. Wang, H. F. Su, M. Kurmoo, C. H. Tung, D. Sun,* L. S. Zheng, Trapping an octahedral Ag6 kernel in a seven-fold symmetric Ag56 nanowheel, Nat. Commun., 9, (2018) 2094.
[31] Z. Wang, H. F. Su, Y. W. Gong, Q. P. Qu, Y. F. Bi, C. H. Tung, D. Sun,* L. S. Zheng, A Hierarchically Assembled 88-Nuclei Silver-Thiacalix[4]arene Nanocluster, Nat. Commun., 11, (2020) 308.
[32] Y. M. Su, Z. Wang, S. Schein,* C. H. Tung, D. Sun,* A Keplerian Ag90 Nest of Platonic and Archimedean Polyhedra in Different Symmetry Groups, Nat. Commun., 11, (2020) 3316.
[33] X. Q. Liang, Y. Z. Li, Z. Wang, S. S. Zhang, Y. C. Liu, Z. Z. Cao, L. Feng, Z. Y. Gao, Q. W. Xue, C. H. Tung, D. Sun,* Revealing the Chirality Origin and Homochirality Crystallization of Ag14 Nanocluster at the Molecular Level, Nat. Commun., 12, (2021), 4966.
[34] Z. Wang, Y. J. Zhu, Y. Z. Li, G. L. Zhuang, K. P. Song, Z. Y. Gao, J. M. Dou, M. Kurmoo, C. H. Tung, D. Sun,* Nuclearity Enlargement from [PW9O34@Ag51] to [(PW9O34)2@Ag72] and 2D and 3D Network Formation Driven by Bipyridines, Nat. Commun., 13, (2022) 1802.
[35] Z. Wang, Y. J. Zhu, B. L. Han, Y. Z. Li, C. H. Tung, D. Sun,* A route to metalloligands consolidated silver nanoclusters by grafting thiacalix[4]arene onto polyoxovanadates, Nat. Commun., 14, (2023) 5295.
[36] W. D. Si, C. Zhang, M. Zhou, W. D. Tian, Z. Wang, Q. Hu, K. P. Song, L. Feng, X. Q. Huang, Z. Y. Gao, C. H.Tung, D. Sun,* Two triplet emitting states in one emitter: Near-infrared dual-phosphorescent Au20 nanocluster, Sci. Adv., 9, (2023) eadg3587.
[37] Y. Chu, L. Guo, B. Xi, Z. Feng, F. Wu, Y. Lin*, J. Liu, D. Sun*, J. Feng, Y. Qian, S. Xiong,*, Embedding MnO@Mn3O4 Nanoparticlesin an N-Doped-Carbon Framework Derived from Mn-Organic Clusters for Efficient Lithium Storage, Adv. Mater., 30, (2018) 1704244.
[38] P. Wang, T. Xu, B. Xi, J. Yuan, N. Song, D. Sun,* S. Xiong,* A Zn8 Double-Cavity Metallacalix[8]arene as Molecular Sieve to Realize Self-Cleaning Intramolecular Tandem Transformation of Li−S Chemistry, Adv. Mater., 34, (2022) 2207689.

*以上信息由高级会员个人更新和维护。