张武

女， 安徽师范大学， 教授/研究员/教授级高工或同等级别

学习/工作经历

1989.9-1993.7 安徽师范大学化学系化学教育专业 本科学生
1993.9-1996.7 安徽师范大学有机化学研究所有机化学专业 硕士学生
1996.7-2000.4 安徽师范大学有机化学研究所 助教 讲师
2000.4-2002.7 安徽师范大学化学与材料科学学院 讲师
2002.7-2006.7 安徽师范大学化学与材料科学学院 副教授
2002.9-2005.6 中国科学技术大学化学系无机化学专业 博士学生
2006.7 至今 安徽师范大学化学与材料科学学院 教授

研究领域和兴趣

金属导向有机合成；绿色化学；纳米催化

主要业绩

一直从事有机化学、金属有机化学、有机合成、纳米催化等方面的研究工作，主持过两项国家自然科学基金面上项目，参加过三项国家自然科学基金的研究。目前研究方向主要在分子内C-C和C-N键形成及C-H键活化。实现了纳米氧化铜催化芳香杂环与卤代芳烃、溴代烯烃等偶联反应，脒类底物与醇、腈等的脱氢环化合成喹唑啉、三嗪、三唑等含氮杂环化合物等。实现了廉价金属铜催化C-H键活化官能团化。开展了还原氧化石墨烯负载PdM合金（MPd-rGO）的制备及表征并首次将它作为可回收催化剂，实现了吡啶氮原子导向的脱氢偶联反应和酰胺邻位C−H键和烯酯的烯基化反应。目前已在Org. Lett., Chem. Eur. J., Green Chem., Adv. Synth. Catal., J. Org. Chem., Org. Biomol. Chem., RSC Adv., J. Mater. Chem. A, J. Phys. Chem. C, Carbon, CrystEngComm, Tetrahedron, Dalton Trans., Catal. Commun., J. Phys. Chem. B等SCI期刊上发表了四十多篇论文，申请国家发明专利十八项，已授权十三项。2020年获安徽省教学名师。获第七届安徽省自然科学优秀论文二等奖，第八届安徽省自然科学优秀论文三等奖和安徽省科学技术奖三等奖（2017年，第二完成人）。

代表成果

1. Fei Huang, Feifan Wang, Qiyan Hu, Lin Tang, Dongping Xu, Yang Fang and Wu Zhang* Monodisperse CuPd alloy nanoparticles as efficient and reusable catalyst for the C (sp2)–H bond activation, Appl. Organometal. Chem. 2021, e6236. DOI: 10.1002/aoc.6236
2. Feifan Wang, Fei Huang, Yingliang Yu, Shuangliu Zhou, Zhenghua Wang, Wu Zhang, Monodisperse CuPd alloy nanoparticles supported on reduced graphene oxide as efficient catalyst for directed C–H activation, Catal. Commun. 2021, 153, 106296. DOI:10.1016/j.catcom.2021.106296
3. Feifan Wang, Xiaoyue Li, Zhongyu Li, Shuangliu Zhou, and Wu Zhang*, Copper salts/TBAB -catalyzed chemo- and regioselectivity β-C(sp3) –H acyloxylation of aliphatic amides, ACS Omega, 2019, 4, 1, 331–343. DOI: 10.1021/acsomega.8b02430
4. Tianchao Shi, Feng Qin, Qian Li, Wu Zhang*, Copper-catalyzed three-component synthesis of pyrimidines from amidines and alcohols, Org. Biomol. Chem., 2018, 16, 9487–9491. DOI: 10.1039/C8OB02694G
5. Qiyan Hu, Xiaowang Liu*, Fei Huang, Feifan Wang, Qian Li, Wu Zhang*, Ag1Pd1-rGO nanocomposite as recyclable catalyst for CDC reactions of 2-arylpyridines with aldehydes, Catal. Commun. 2018, 113, 27–31. DOI: 10.1016/j.catcom.2018.05.007
6. Feifan Wang, Zhiyang Lin, Weisheng Yu, Qingdong Hu, Chao Shu, and Wu Zhang*, Copper-Catalyzed C–H Acyloxylation of 2-Phenylpyridine Using Oxygen as Oxidant, RSC Adv. 2018, 8, 16378 –16382. DOI: 10.1039/c8ra01974f
7. Liang Liu, Lei Song, Yujun Guo, Dewen Min, Tianchao Shi, Wu Zhang*, Cyclization and oxidation of o-bromophenyl-acetamides for the synthesis of oxindoles and isoindigoes, Tetrahedron, 2018, 74, 354–359. DOI: 10.1016/j.tet.2017.12.005
8. Lin Tang, Chaoting Wu, Qiyan Hu, Qian Li and Wu Zhang*, Cross-coupling reactions using porous multipod Cu2O microcrystals as recoverable catalyst in aqueous media, Appl. Organometal. Chem. 2018, 32, e3980. DOI:10.1002/aoc.3980
9. Feifan Wang, Qiyan Hu, Chao Shu, Zhiyang Lin, Dewen Min, Tianchao Shi and Wu Zhang*, Copper-Catalyzed Direct Acyloxylation of C(sp2)–H Bonds in Aromatic Amides, Org. Lett. 2017, 19, 3636−3639. DOI: 10.1021/acs.orglett.7b01559
10. Qiyan Hu, Xiaowang Liu,* Guoliang Wang, Feifan Wang, Qian Li and Wu Zhang*, Ag1Pd1 nanoparticles-reduced graphene oxide as highly efficient and recyclable catalyst for direct aryl C−H olefination, Chemistry-A European Journal, 2017, 23, 17659–17662. DOI:10.1002/chem.201704056
11. Qiyan Hu, Xiaowang Liu, Lin Tang, Dewen Min, Tianchao Shi and Wu Zhang*, Pd–ZnO nanowire arrays as recyclable catalysts for 4-nitrophenol reduction and Suzuki coupling reactions, RSC Adv. 2017, 7, 7964–7972. DOI: 10.1039/c6ra28467a
12. Qiyan Hu, Xiaowang Liu, Chaoting Wu, Qing You, Tianchao Shi and Wu Zhang*, A general and rapid approach to hybrid metal nanoparticle–ZnO nanowire arrays and their use as active substrates for surface-enhanced Raman scattering detection, RSC Adv., 2016, 6, 1542–1548. DOI: 10.1039/c5ra24113h
13. Dan Yu, Qing You, Xinming Zhang, Guide Tao and Wu Zhang*, CuO nanoparticle-catalyzed diaminations for synthesis of benzimidazole derivatives Appl. Organometal. Chem. 2016, 30, 695–698. DOI: 10.1002/aoc.3492
14. Fei Wang, Qing You, Chaoting Wu, Dewen Min, Tianchao Shi, Yuting Kong and Wu Zhang*, Mild Cu(OAc)2·H2O-catalyzed synthesis of multisubstituted 1,2,4-triazoles from amidines with nitriles via a N–N/C–N coupling, RSC Adv., 2015, 5, 78422–78426. DOI: 10.1039/c5ra15919a
15. Qing You, Fei Wang, Chaoting Wu,Tianchao Shi, Dewen Min, Huajun Chen, Wu Zhang*, Synthesis of 1,3,5-Triazines via Cu(OAc)2-Catalyzed Aerobic Oxidative Coupling of Alcohols and Amidine hydrochlorides, Org. Biomol. Chem., 2015, 13, 6723–6727. DOI: 10.1039/c5ob00724k
16. Wei Kong, Chenchen Lu, Wu Zhang*, Jun Pu and Zhenghua Wang*, Homogeneous core–shell NiCo2S4 nanostructures supported on nickel foam for supercapacitors, J. Mater. Chem. A, 2015, 3, 12452–12460. DOI: 10.1039/c5ta02432c
17. Na Zhao, Liang Liu, Fei Wang, Jia Li, Wu Zhang*, Copper/N,N,N’,N’-Tetramethylene diamine-Catalyzed Synthesis of N-Substituted Benzoheterocycles via C–S Cross-Coupling at Ambient Temperature in Water, Adv. Synth. Catal. 2014, 356, 2575–2579. DOI: 10.1002/adsc.201400043
18. Wu Zhang*, Fei Guo, Fei Wang, Na Zhao, Liang Liu, Jia Li, Zhenghua Wang, Synthesis of quinazolines via CuO nanoparticles catalyzed aerobic oxidative coupling of aromatic alcohols and amidines, Org. Biomol. Chem., 2014, 12, 5752–5756. DOI: 10.1039/c4ob00569d
19. Wu Zhang*, Yujie Tian, Na Zhao, Yuanyuan Wang, Jia Li, Zhenghua Wang*, Nano CuO-catalyzed C–H functionalization of 1,3-azoles with bromoarenes and bromoalkenes, Tetrahedron, 2014, 70, 6120–6126. DOI: 10.1016/j.tet.2014.04.065
20. Wu Zhang*, Yun Yue, Dan Yu, Lei Song, Yangyang Xu, Yujie Tian, Yujun Guo, 1, 10-Phenanthroline Catalyzed Tandem Reaction of 2-Iodoanilines with Isothiocyanates in Water, Adv. Synth. Catal. 2012, 354, 2283–2287. DOI: 10.1002/adsc.201200175
21. Wu Zhang*, Qinglong Zeng, Xinming Zhang, Yujie Tian, Yun Yue, Yujun Guo, Zhenghua Wang, Ligand-free CuO Nanospindles Catalyzed Arylation of Heterocycle C–H Bonds, J. Org. Chem. 2011, 76, 4741–4745. DOI: 10.1021/jo200452x
22. Wu Zhang*, Hongling Qi, Liusan Li, Xiang Wang, Jie Chen, Kaishan Peng and Zhenghua Wang*, Hydrothermal Heck reaction catalyzed by Ni nanoparticles, Green Chem., 2009, 1194–1200. DOI: 10.1039/b900697d
23. Hongling Qi, Wu Zhang*, Xiang Wang, Hong Li, Jie Chen, Kaishan Peng, Mingwang Shao, Heck reaction catalyzed by flower-like cobalt nanostructures, Catal. Commun. 2009, 10, 1178–1183. DOI: 10.1016/j.catcom.2009.01.018
24. Wu Zhang*, Jie Chen, Xiang Wang, Hongling Qi, Kaishan Peng, Self-assembled 3D flower-like α-Fe2O3 nanostructures and their application in catalysis, Appl. Organomet. Chem. 2009, 200–203. DOI: 10.1002/aoc.1496

*以上信息由高级会员个人更新和维护。