佟浩

男， 南京航空航天大学材料学院， 教授/研究员/教授级高工或同等级别

学习/工作经历

1992-1996于兰州大学化学化工学院，读本科
2000-2005于兰州大学化学化工学院，读博士
2005-2007于南京航空航天大学材料科学与技术学院，博士后
2007-今 于南京航空航天大学材料科学与技术学院，教学科研

研究领域和兴趣

超级电容器电极材料，水系电池电极材料，锂离子电池电极材料

主要业绩

本人长期从事异质结结构等高比能、高稳定的电化学储能电极材料的研究，这些课题均是目前国际上交叉领域的前沿热点问题。因从事基础研究，研究成果主要以纵向项目和文章为主。已在JMCA, ACS AMI, Carbon, Nanoscale, JPS等国内国际主流期刊论文34篇，其中第一作者/通讯作者论文23篇。
独立主持了纵向项目6项，其中包含“国家自然科学基金面上项目”1项、“江苏省自然科学基金面上项目”等省部级项目4项。参与了国家级科研项目3项。共发表SCI论文34篇，其中包含ESI高被引论文1篇，中科院1区论文10篇，总他引次数大于1000次，年均被引74.6次，单篇论文最高被引123次，其中3篇论文被引用次数超过100次。影响因子大于8的论文7篇，其中大于14的论文3篇；获授权发明专利7项。获江苏省高校自然科学奖一等奖1项。
创新贡献点1：交联状电池型材料与含氮石墨烯基导电载体的协同效应
电池型电容材料因具有超高的比电容而倍受关注，然而该类材料的主要问题是循环稳定性低、倍率性能差，因此制约了该类材料的应用。申请人发现了交联状结构电池型材料（如NiCo2O4、ZnCo2O4、Ni(OH)2）与氮掺杂石墨烯膜(NGN/CNTs)之间的异质结构的协同效应，交联结构的电极材料与含氮载体之间的应力场作用可有效抑制电池材料在充放电过程中的体积膨胀，可同时实现电极的循环寿命及倍率性能的明显提升，解决了此类材料稳定性差、倍率性能低的关键瓶颈问题。如NiCo2O4在20A g-1大电流密度下循环1万圈容量仍可保持125%。相关论文发表于(J. Mater. Chem. A, 2017, ESI；J. Mater. Chem. A, 2015；J. Mater. Chem. A, 2016中科院二区IF=14.5；Ceram. International, 2021中科院一区)。获授权发明专利2项。相关成果获江苏省高校自然科学奖一等奖1项。

创新贡献点2：高载量条件下的空位及异质结构对电极的离子输运、电子传导的作用影响
高电极载量是获得高能量密度超电容器件的前提，但由于高电极载量易导致离子的输运阻力增大，进而使得电极的比电容和倍率性能降低。申请人制备了具有可三维压缩特性的碳纳米管泡沫，并在其上负载了异质结构（NiS2/NiCo2S4）、核壳结构（NiCo2S4@Ni(OH)2）、氧空位结构的电池型电容材料。利用碳纳米管泡沫/电池型电容结构的可压缩特性，通过调控电容材料的结构以及电极密度，获得了高负载量条件下的高倍率、高比容量的电极材料，实现了电极负载量为14mg cm-2时，它的厚度达到360 μm，面积/质量比电容为24.15 F cm-2/1725 F g-1。相关成果发表于J. Power Sources 2022中科院二区IF=9.8; Nanoscale 2017中科院二区IF=8.3；Ceram. International 2018中科院一区，氧空位结构的J. Alloys. Compd. 2020中科院一区。获授权发明专利3项。

创新贡献点3：高稳定锌负极锌离子电容器的研究
水系锌基电容器的锌负极易产生枝晶以及析氢反应，极大地制约了其应用。申请人利用InF3对锌箔进行表面改性，在金属锌表面同时引入金属In和ZnF2涂层，这种改性层有效地减少了锌枝晶和锌箔表面的腐蚀，同时也能够抑制析氢反应。将改性后的锌箔（Zn@In&ZnF2）与活性炭匹配组装的锌离子电容器能够在2 A g–1电流密度下具有33.5 Wh kg–1的能量密度和1608 W kg–1的功率密度，稳定充放电循环10000次后仍能保持100%的容量。相关论文发表于ACS Appl. Mater. Interfaces, 2022中科院二区IF=10.4。

代表成果

近期发表的学术论文：
1. Xudong Chen ‡, Yuan Wu, Yang Zhou, Zhenming Xu, Cunqi Wu, Lei Li, Cheng Li, Xiaogang Zhang, Hao Tong *‡, Preparation of sulfur vacancy modified NiCo2S4@NiCoS2 core-shell electrode material and its application in asymmetric supercapacitors, Electrochimica Acta, 2023, 454, 142376.
https://doi.org/10.1016/j.electacta.2023.142376，中科院2区，IF=7.3.
2. Yang Zhou, Hao Tong*,Yuan Wu, Xudong Chen, Cunqi Wu, Zhenming Xu*, Laifa Shen, Xiaogang Zhang*, A Dendrite-Free Zn Anode Co-modified with In and ZnF2 for Long-Life Zn-Ion Capacitors, ACS Appl. Mater. Interfaces, 2022, 14, 41, 46665–46672. 10.1021/acsami.2c13536. [IF=10.3] JCR1区, 中科院2区, TOP期刊
3. Yuan Wu, Hao Tong*, Xudong Chen, Yang Zhou, Cunqi Wu, Daxiong Gong, Jinpan Xiao, Xiaogang Zhang*, Preparation of nanosheets of Ni5P2@Ni9S8/CoS1.097 heterostructure for aqueous asymmetric supercapacitors with high electrochemical performance, J. Alloys. Compd. 2022, 923, 166378. 中科院1区，TOP期刊 https://doi.org/10.1016/j.jallcom.2022.166378
4. Daxiong Gong‡, Hao Tong‡*, Jinpan Xiao, Yuan Wu, Xudong Chen, Yang Zhou and Xiaogang Zhang*, Enhanced reaction kinetics of N–MnO2 nanosheets with oxygen vacancies via mild NH3·H2O bath treatment for advanced aqueous supercapacitors, ACS Applied Energy Materials, 2022, 5, 7490-7502. DOI： 10.1021/acsaem.2c00984[IF=6.9] 中科院3区
5. HaoTong*, DaxiongGong, JiangLiu, JinpanXiao, Xudong Chen, YuanWu, YangZhou, Laifa Shen, Xiaogang Zhang*, High-performance 2.5 V supercapacitor with high energy density and long cycling stability based on graphene coated oxygen-vacancy birnessite, J. Alloys. Compd. 2022, 901, 163543. 2021.12.30出版 DOI:10.1016/j.jallcom.2021.163543. JCR1区，中科院1区，TOP期刊
6. Jinpan Xiao, Hao Tong*, Fengqiao Jin, Daxiong Gong, Xudong Chen, Yuan Wu, Yang Zhou, Laifa Shen, Xiaogang Zhang*, Heterostructure NiS2/NiCo2S4 nanosheets array on carbon nanotubes sponge electrode with high specific capacitance for supercapacitors, J. Power Sources, 2022, 518, 230763.[IF=9.4] JCR1区, 中科院2区, TOP期刊 DOI:10.1016/j.jpowsour.2021.230763
7. Daxiong Gong, Hao Tong*, Jinpan Xiao, Tingting Li, Jiang Liu, YuanWu, Xvdong Chen, Jie Liu, Xiaogang Zhang*, Self-standing manganese dioxide/graphene carbon nanotubes film electrode for symmetric supercapacitor with high energy density and superior long cycling stability, Ceramics International, 2021, 47(23), 33020-33027. [IF=3.057] JCR1区，中科院1区 TOP期刊 WOS:000708571600004
8. Hao Tong*, Jiang Liu, Tingting Li, Daxiong Gong, Jinpan Xiao, Liang Lu, Laifa Shen, Xiaogang Zhang*, Self-Standing flexible N-doped graphene/CNTs supported spiral low-crystalline Ni(OH)2 electrode with ultra-long cycling stability for supercapacitors, Nano, 2021, 16(2), 2150013, 1-13. WOS:000623086800003
9. Hao Tong*, Tingting Li, Jiang Liu, Daxiong Gong, Jinpan Xiao, Laifa Shen,* Bing Ding, Xiaogang Zhang, Fabrication of the oxygen vacancy amorphous MnO2/carbon nanotube as cathode for advanced aqueous Zinc-ion batteries, Energy Technol. 2021, 9, 2000769. DOI: 10.1002/ente.202000769 [IF=4.1] JCR1区 中科院4区 (WOS: 000599083000001)
10. Hao Tong*, Qing Meng, Jiang Liu, Tingting Li, Daxiong Gong, Jinpan Xiao, Laifa Shen*, Tengfei Zhang, Ding Bing, Xiaogang Zhang, Cross-linked NiCo2O4 nanosheets with low crystallinity and rich oxygen vacancies for asymmetric supercapacitors, J. Alloys. Compd.,2020,882, 153689. doi: https://doi.org/10.1016/ j.jallcom.2020.153689. JCR1区，中科院1区，TOP期刊 (WOS: 000512377800017)
11. Fengqiao Ji, Hao Tong*, Liang Lu, Qing Meng, Shihong Yue, Bing Ding, Xiaogang Zhang*,
Honeycombed NiCo2O4 nanosheets grown on the sponge of a carbon nanotube/graphene prepared by the flame burning method with an advanced performance as a supercapacitor, J. Alloys. Compd., 2019, 787, 36-44. [IF=3.779] JCR1区，中科院2区，TOP期刊 WOS:000623086800003
12. Liang Lu, Hao Tong*, Fengqiao Jin, Shihong Yue, Qing Meng, Xiaogang Zhang*, Superfast preparation of SWNT sponge by flame burning method and its adsorptive, elastic and electrochemical properties, Nano, 2018, 13, 18500771-17. (封面论文及亮点文章) JCR3区，中科院4区
13. Hao Tong,* Shihong Yue, Fengqiao Jin, Liang Lu, Qing Meng, Xiaogang Zhang,* Honeycomb-like NiCo2O4@Ni(OH)2 supported on 3D N-doped graphene/carbon nanotubes sponge as an high perforamnce electrode for supercapacitor, Ceram. International, 2018, 44, 3133-3121. [IF=3.057] JCR1区，中科院2区 TOP期刊
14. Hao Tong,*Shihong Yue, Liang Lu, Fengqiao Jin, Qiwei Han, Xiaogang Zhang,* Jie Liu, * A binder-free NiCo2O4 nanosheet/3D elastic N-doped hollow carbon nanotube sponge electrode with high volumetric and gravimetric capacitances for asymmetric supercapacitors, Nanoscale, 2017, 9, 16826-16835.[IF=12.7] JCR1区，中科院1区 TOP期刊
15. Shihong Yue , Hao Tong, * Liang Lu, Weiwei Tang, Wenlong Bai, Fengqiao Jin, Qiwei Han, Jianping He, Jie Liu, Xiaogang Zhang*, Hierarchical NiCo2O4 Nanosheets/Nitrogen Doped Graphene/Carbon Nanotube Film with Ultrahigh Capacitance and Long Cycle Stability as Flexible Binder-free Electrode for Supercapacitor, J. Mater. Chem. A, 2017, 5: 689–698. [IF=12.7] (ESI高被引论文) JCR1区，中科院1区 TOP期刊
16. Shihong Yue, Hao Tong*, Zhenzhen Gao, Wenlong Bai, Liang Lu, Jie Wang, Xiaogang Zhang*, Fabrication of flexible nanoporous nitrogen doped graphene film for high performance supercapacitors, J Solid State. Electr. 2017, 21(6):1653-1663. DOI: 10.1007/s10008-017-3538-y. [IF=2.327] JCR2区，中科院3区
17. Hao Tong,* Wenlong Bai, Shihong Yue, Zhenzhen Gao, Liang Lu, Laifa Shen, Shengyang Dong, Jiajia Zhu, Jianping He and Xiaogang Zhang*, Zinc cobalt sulfide nanosheets grown on nitrogendoped graphene/carbon nanotube film as a highperformance electrode for supercapacitors, J. Mater. Chem. A, 2016, 4: 11256-11263. [IF=12.7] JCR1区，中科院1区 TOP期刊
18. Wenlong Bai, Hao Tong,*† Zhenzhen Gao, Shihong Yue, Sichuan Xing, Shengyang Dong, Laifa Shen, Jianping He, Xiaogang Zhang* and Yanyu Liang, Preparation of ZnCo2O4 nanoflowers on a 3D carbon nanotube/nitrogen-doped graphene film and its electrochemical capacitance, J. Mater. Chem. A, 2015, 3: 21891–21898. [IF=12.7] JCR1区，中科院1区 TOP期刊

已授权专利：
1.硫化镍/硫钴镍/碳纳米管泡沫的制备方法与应用 中国 佟浩,金凤巧,孟晴,李婷婷,刘江,张校刚 ZL201811579139.0
2021-04-20
2碳纳米管泡沫负载核壳型Ni-CoLDH@Ni-MnLDH的制备方法及应用 中国 佟浩,金凤巧,孟晴,李婷婷,刘江,张校刚
ZL201910283861.8 2021-06-22
3石墨烯－聚苯胺导电复合物的制备方法及应用 中国 佟浩,白文龙,张校刚,高珍珍,岳世鸿 ZL201410786468.8
2018-02-06
4. 一种碳纳米管海绵体的制备方法 中国 佟浩,岳世鸿,张校刚,卢亮 ZL201610639896.7 2018-11-09
5. 氮掺杂石墨烯/氮掺杂碳纳米管/钴酸锌复合材料的制备方法与应用 中国 佟浩,白文龙,张校刚,高珍珍,岳世鸿,幸四川 ZL201510569811.8 2017-10-31
6. 铅酸电池用铅碳复合材料的制备方法及复合负极板 中国 张校刚，杨高梁，原长洲，佟浩，丁兵 ZL201410564028.8
（万元） 2017-06
7. 一种铅酸电池用改性短纤的制备方法及包含该改性短纤的负极板 中国 张校刚，杨高梁，丁兵，窦辉，佟浩
ZL201510317253.6 2017-07

*以上信息由高级会员个人更新和维护。