郑彦臻

男， 西安交通大学前沿科学技术研究院， 教授/研究员/教授级高工或同等级别

学习/工作经历

1998.09-2002.07， 中山大学化学与化工学院/化学系，本科学生
2002.09-2007.07， 中山大学化学与化工学院/化学系，硕博连读
2007.10-2009.04，德国卡尔斯鲁厄大学/无机化学系，洪堡学者
2009.05-2009.08，德国亚琛工业大学/无机化学系，博士后
2009.09-2011.08，英国曼彻斯特大学/化学系，玛丽居里学者
2011.09-今，西安交通大学/前沿科学技术研究院，教授

研究领域和兴趣

分子磁性与功能配合物

主要业绩

围绕稀土磁分子固体材料基础研究领域的关键科学前沿问题，深入研究，取得了颇具特色的创新性科研成果：1）通过对称性及配体场调控，将当时的单分子磁体能垒记录提升了近一倍，达1815 K（Angew. Chem. Int. Ed. 2016, 55, 16071）；之后深入研究了该类磁体的磁弛豫机理，发现磁量子隧穿行为与分子振动/转动能级有一定的相关性（Nat. Commun. 2018, 9, 3134），进而通过增强分子刚性，大幅提升了D5h单离子磁体的阻塞温度（Chem, 2020, 6. 1777），并成功制得了首例碳硼烷基单分子磁体（Angew. Chem. Int. Ed. 2020, 59, 9350）。2）构筑了数例高核稀土或过渡-稀土分子磁体（Angew. Chem. Int. Ed., 2016, 55, 9375; Adv. Mater., 2016, 28, 10772），并阐明了稀土离子的磁交换作用在磁场下具有 “指纹谱”效应（J. Am. Chem. Soc. 2017, 139, 16405）、而过渡-稀土离子间得铁磁交换作用在低场下能产生大磁熵变（Nat. Commun., 2018, 9, 2107; J. Am. Chem. Soc. 2020, 142, 4663）、零场中可形成“涡旋”磁矩（Angew. Chem. Int. Ed. 2017, 56, 16571; Matter, 2020, 2, 1481）。系列研究成果不仅得到同行的认可，还得到了《科技日报》、《中国科技报》、科学网、新浪网等媒体的报道宣传，国内外学术大会做报告40余次，为新型多功能稀土材料的开发提供了新思路和新途径，并先后获得亚洲国际学术论坛杰出授课奖、陕西省高等学校科学技术奖及中华医学会奖。

代表成果

代表论文（*为通讯作者）
1. Enhancing Magnetic Hysteresis in Single-Molecule Magnets by Ligand Functionalization; Ke-Xin Yu, Jon G.C. Kragskow,You-Song Ding, Yuan-Qi Zhai, Daniel Reta, Nicholas F. Chilton*,Yan-Zhen Zheng*，Chem, 2020, DOI: 10.1016/j.chempr.2020.04.024
2. Single-Molecule Toroic Design through Magnetic Exchange Coupling; Hao-Lan Zhang, Yuan-Qi Zhai, Lei Qin, Liviu Ungur, Hiroyuki Nojiri, Yan-Zhen Zheng*, Matter, 2020, DOI: 10.1016/j.matt.2020.02.021
3. The Gigantic {Ni36Gd102} Hexagon: A Sulfate-Templated “Star-of-David” for Photocatalytic CO2 Reduction and Magnetic Cooling; Wei-Peng Chen, Pei-Qin Liao, Peng-Bo Jin, Lei Zhang, Bo-Kai Ling, Shi-Cheng Wang, Yi-Tsu Chan, Xiao-Ming Chen, and Yan-Zhen Zheng* J. Am. Chem. Soc. 2020, DOI: 10.1021/jacs.9b11543 (IF = 14,695, featured on cover)
4. Dysprosiacarboranes: A New Type of Organometallic Single‐Molecule Magnet; Peng-Bo Jin, Yuan-Qi Zhai, Ke-Xin Yu, Richard E. P. Winpenny, and Yan-Zhen Zheng* Angew. Chem. Int. Ed. 2020, DOI: 10.1002/anie.202001401 (IF = 12.257)
5. Field- and temperature-dependent quantum tunnelling of the magnetisation in a large barrier single-molecule magnet; Y. -S. Ding , K.-X. Yu , D.Reta, F.Ortu, R. E.P. Winpenny , Y.-Z. Zheng*, Nicholas F. Chilton*, Nat. Commun., 2018, 9, 3134 (IF = 12.1)
6. Quantum Monte Carlo simulations of a giant {Ni21Gd20} cage with a S =91 spin ground state; W.-P. Chen, J. Singleton, L. Qin, A. Camón, L. Engelhardt,* F. Luis, R. E. P. Winpenny,* and Y.-Z. Zheng*, Nat. Commun., 2018, 9, 2107 (IF = 12.1)
7. Quantum Monte Carlo Simulations and High-Field Magnetization Studies of Antiferromagnetic Inter-actions in a Giant Hetero-Spin Ring; L. Qin, J. Singleton, W.-P. Chen, H. No-jiri, L. Engelhardt,* R. E. P. Winpenny,* and Y.-Z. Zheng*, Angew. Chem. Int. Ed., 2017, 56, 16571-16574. (IF = 12.0)
8. Topological Self-Assembly of Highly-Symmetric Lanthanide Clusters: A Magnetic Study of Exchan-ge-Coupling “Fingerprints” in Giant Gadolinium(III) Cages; L. Qin, G.-J. Zhou, Y.-Z. Yu, H. Nojiri, C. Schröder*, R. E. P. Winpenny* and Y.-Z. Zheng*, J. Am. Chem. Soc., 2017, 139, 16405–16411. (IF = 13.9)
9. On Approaching the Limit of Molecular Magnetic Anisotropy：A Near-Perfect Pentagonal Bipyram-idal Dysprosium(III) Single-Molecule Magnet; Y.-S. Ding, N. F. Chilton,* R. E. P. Winpenny,* and Y.-Z. Zheng*, Angew. Chem. Int. Ed., 2016, 55, 16071–16074. (IF = 12.0, ESI hot paper)
10. A “Molecular Water Pipe”: A Giant Tubular Cluster {Dy72} Exhibits Fast Proton Tra-nsport and Slo-w Magnetic Relaxation; L. Qin, Y.-Z. Yu, P.-Q. Liao, W. Xue, Z. Zheng, X.-M. Chen and Y.-Z. Zheng*, Adv. Mater., 2016, 28, 10772–10779. (IF = 19.8)
11. A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni64RE96} for Gas Sep-aration and Magnetic Cooling Applications; W.-P. Chen, P.-Q. Liao, Y. Yu, Z. Zheng, X.-M. Chen and Y.-Z. Zheng*, Angew. Chem. Int. Ed., 2016, 55, 9375-9379. (IF = 12.0)
12. Molecule-based magnetic coolers; Y.-Z. Zheng*, G.-J. Zhou, Z. Zheng, R. E. P. Winpenny, Chem. Soc. Rev., 2014, 43, 1462-1475. (入选ESI高被引, IF = 38.6)
13. A symbol approach for classification of molecule-based magnetic materials exemplifi-ed by coordi-nation polymers of metal carboxylates; Y.-Z. Zheng*, Z. Zheng, X.-M. Chen, Coord. Chem. Rev., 2014, 258-259, 1-15. (入选ESI高被引, IF = 13.3)
14. Co-Ln Mixed-Metal Phosphonate Grids and Cages as Molecular Magnetic Refrigerants; Y.-Z. Zheng, M. Evangelisti, F. Tuna, R. E. P. Winpenny,* J. Am. Chem. Soc., 2012, 134, 1057-1065. (入选ESI高被引, IF = 13.9)
15. Large Magnetocaloric Effect in a Wells-Dawson Type {Ni6Gd6P6} Cage; Y.-Z. Zheng, M. Evangelisti, R. E. P. Winpenny,* Angew. Chem. Int. Ed., 2011, 50, 3692-3695. (入选ESI高被引, IF = 12.0)
16. Néel Temperature Enhancement by Increasing the In-plane Magnetic Correlati-on in Layered Inorganic–Organic Hybrid Materials; Y.-Z. Zheng, W. Xue, S.-L. Zheng, M.-L. Tong and X.-M. Chen, Adv. Mater., 2008, 20,1534-1538. (IF = 18.9)
17. A “Star” Antiferromagnet: A Polymeric Iron(III) Acetate That Exhibits Both Spin-Frustration and Long-Range Magnetic Ordering; Y.-Z. Zheng, M.-L. Tong, W. Xue, W.-X. Zhang, X.-M. Chen, F. Grandjean, G. J. Long, Angew. Chem. Int. Ed., 2007, 46, 6076-6080. (入选ESI高被引, IF = 11.7)
18. Assembling Magnetic Nanowires into Network: A Layered Co(II)-Carboxylate C-oordination Polymer Exhibiting Single-Chain-Magnet Behavior; Y.-Z. Zheng, M.-L. Tong, W.-X. Zhang, X.-M. Chen, Angew. Chem. Int. Ed., 2006, 45, 6310-6314. (入选ESI高被引, IF = 11.7)

书籍章节
1.Han, Tian, You-Song Ding, and Yan-Zhen Zheng,* Recent Development in Clusters of Rare Earths and Actinides: Chemistry and Materials, 2016, 173, pp 209-314

专利
1. 郑彦臻，王艳艳，秦雷， 周国军，“一种含稀土氢氧化物的磁制冷材料及制备方法”，发明专利，申请号：201410817811.0

会议
1. 2019年7月，应邀赴法国波尔多大学及帕斯卡研究中心（CRPP）做为期一个月的访问教授。
2. 2017年11月6-8日受邀在德国比勒费尔德大学举办的分子磁体会议做题为Barrier Engineering of Dysprosium(III) Single-Ion Magnets with an Equatorially-assisted Pseudo-Two-Coordinate Model的学术报告。
3. 2017年3月15-19日受Hiroki Oshio教授邀请前往日本筑波大学做学术报告，并于3月17日前往在东京领Keio大学举办的97届日本化学年会，领取日本化学会颁与的“亚洲国际学术论坛杰出授课奖”（Distinguish Lectureship Awards in Asian International Symposium）。
4. 11/2017 郑彦臻, Pseudo-Two-Coordinate Dysprosium(III) Single-Ion Magnets, 2017分子磁性前沿研讨会，广州。
5. 10/2017 郑彦臻，多孔功能稀土配合物——合成与性质探索，2017年多孔功能材料分子工程学研讨会,宝鸡。
6. 11/2016 郑彦臻，稀土基无机中空纳米团簇 ——合成与性质探索，第七届全国 结构化学学术会议，广州
7. 5/2016 郑彦臻，基于3d过渡金属单分子磁体磁各向异性能调控，第七届全国 物理无机化学学术会议，北京
8. 11/2015 郑彦臻，多功能稀土簇合物，第九届无机化学青年学者研讨会，上海

*以上信息由高级会员个人更新和维护。