赵彦英

女， 浙江理工大学， 教授/研究员/教授级高工或同等级别

学习/工作经历

1996年~2000年 河北师范大学 化学学院 本科
2000年~2003年 河北师范大学 化学学院 硕士
2003年~2004年 河北师范大学汇华学院 教师
2004年~2007年 复旦大学 化学系 博士
2007年~2009年 浙江理工大学 讲师
2009年~2019年 浙江理工大学 副教授
2013年~2014年 日本产业技术研究所（关西分所）访问（合作教授：徐强）
2015年~2016年 日本京都大学 CSC访问学者（合作教授：Morokuma Keiji）
2019年1月 日本北海道大学 访问（合作教授：Naoki Watanabe & WMC Sameera）
2019年~至今 浙江理工大学 教授

研究领域和兴趣

分子光谱和化学反应动力学，涉及过渡金属催化、C-X(X=H, C, Cl…)键的活化、稀有气体成键、功能有机分子的设计合成及光物理化学机制，包括激发态质子转移，光致、电致、聚集诱导发光及溶剂致变色等等领域。

主要业绩

任现职以来，承担国家自然科学基金4项、省自然科学基金1项，参与多项。一直从事分子光谱和化学反应动力学研究。提出了烯胺-亚胺类分子的激发态质子转移，光致、电致、聚集诱导发光及溶剂致变色；微溶剂团簇激发态结构动力学的共振拉曼光谱表征；过渡金属催化氧化甲烷及卤代甲烷的机制；金属-稀有气体成键机制等等。入选浙江理工大学首批521人才培养(首批)资助计划。从事教学工作以来，主要承担了本科生的《物理化学》和《物理化学实验》等专业基础课程等，《现代分子光谱学》和《高斯计算及应用》等研究生课程的教学工作。2009级和2018级本科生班主任，多次获得“优秀班主任”、“十佳班主任”等荣誉称号。

代表成果

近五年发表主要论文：
★Wang Yuanyue, Yang Chuchu, Feng Xiaoqing, Zhao Yanying*. Urolithin-Based Ratiometric Fluorescent Probe: Instant Quantitative Monitoring for F-. Talanta, 2024, 276, 126220-7. https://doi.org/10.1016/j.talanta.2024.126220
★Li Wenbo, Wu Xiao-Feng, Zhao Yanying*. Mechanistic Insights into the Palladium-Catalyzed Perfluoroalkylative Carbonylation of Unactivated Alkenes to β‑Perfluoroalkyl Esters: A DFT Study. Published as part of The Journal of Physical Chemistry A (virtual special issue “Women Scientists in China”), 2024, 128, 3777−3783. https://doi.org/10.1021/acs.jpca.3c08287
★Yuanrui Wang, Hefei Yang, Yan Zheng, Mingxia Hu, Jintao Zhu, Zhi-Peng Bao, Zhao Yanying, Xiao-Feng Wu*. Carbon monoxide enabling synergistic carbonylation and (hetero)aryl migration. Nature Catalysis. 2024, https://doi.org/10.1038/s41929-024-01204-6
★王甦昊，胡明霞，徐卉，赵彦英*，喹吖啶酮分子的合成与结构及光物理荧光机制. 化学学报，2024, 82, DOI: 10.6023/A24060183.
★ WangYuanyue, Li Yu, Feng Xiaoqing*, Zhao Yanying*. Exploring the Highly Selective Fe(III) and Al(III) Triggered “OFF-ON” Ellagic Acid Based Fluorescent Sensor: Spectroscopic, Structural Elucidations and Dual-Response Mechanism. Journal of Molecular Liquid, 2023, 381, 121809. DOI: 10.1016/j.molliq.2023.121809
★Li Yu, Lan Yaxing, Zheng Xuming, Zhao Yanying*. Insights into Wavelength-Mediated Excited State Intramolecular Proton Transfer in Solution: UV Resonance Raman Spectroscopy and Theoretical Calculation. Journal of Molecular Liquid, 2023, 380, 121740. DOI: 10.1016/j.molliq.2023.121740
★Liu Yanhui, Wang Guanjun*, Zhao Yanying*. Direct Observation on Argon Tagging Nitrobenzene Radical Anion in Gas Phase: Infrared Photodissociation Spectroscopy and Theoretical Calculation. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2023, 294, 122482. (IF=4.831)
★Yu Li, Feng Xiaoqing, Yanying Zhao*. Spectroscopic and Mechanistic Insights into Solvent Mediated Excited-State Proton Transfer and Aggregation-Induced Emission: Introduction of Methyl Group onto 2-(o-hydroxyphenyl)benzoxazole. Physical Chemistry Chemical Physics, 2022, 24, 26297–26306. https://doi.org/10.1039/D2CP03007A.
★ Li Yu, Liu Bo-Long, An Suosuo, Zhao Yanying*, Zheng Xuming, Xie Bin-Bin*. Spectroscopic and Theoretical Insights in Hydrogen Bonding Clusters, Triplet Species, and Relaxation Mechanism of Light (1ππ*) State of 4-Methyl-1, 2, 4-Triazole-3-Thione. New Journal of Chemistry, 2022, 46, 20354–20365. DOI: 10.1039/d2nj03262g
★ Yue Qianqian, Li Yu, Zhao Yanying.* Vibrational and electronic absorption spectroscopic and density functional theoretical studies on the 2(3H)-benzothiazolone and its anion. Journal of Molecular Structure, 2022, 1271, 134060.
★ 王园月，安梭梭，郑旭明，赵彦英*. 5-巯基-1,3,4-噻二唑-2-硫酮（MTT）微溶剂团簇的光谱 和密度泛函理论计算研究. 高等学学化学学报，2022, 40(10), 20220354.
★ Zhou Zhaoman, Yue Qianqian, Zhao Yanying*. A DFT Study on the Binuclear Copper(I)-Catalyzed Synthesis Mechanism of 1,2,3-Triazolo[1,5-c]Pyrimidine via Interrupted Click and Ketenimine Rearrangement. ChemPhysChem, 2022, 2022, 23, e202100751 (1 of 8). http://doi.org/10.1002/cphc.202100751.
★ Suosuo An, Shuang Meng, Jiadan Xue, Huigang Wang, Xuming Zheng, Yanying Zhao*, UV–Vis, Raman spectroscopic and density functional theoretical studies on microsolvation 1, 2, 4-triazole-3-thione clusters. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2021, 258, 119762.
★ Fan Yu, Zhaoman Zhou, Jiajia Song and Yanying Zhao* DFT and AFIR study on the copper(I)-catalyzed mechanism of 5-enamine-trisubstituted-1,2,3-triazole synthesis via C–N cross-coupling and the origin of ring-opening of 2H-azirines. RSC Advances, 2021, 11, 2744
★ Aimin Duan, Suosuo An, Jiadan Xue, Xuming Zheng and Yanying Zhao*, Absorption, fluorescence, Raman spectroscopic and density functional theoretical studies on the singlet and triplet excited state decay of 3-amino-5-mercapto-1,2,4-triazole. RSC Advances, 2020, 10, 13442
★ Quan Yaping, Zhao Yanying*, Density Functional Theoretical Study on the Electronic Structure of Rh2O7+ with Low Oxidation States. ACS Omega, 2020, 5, 19422−19428
★ Cheng-Min Hu, Qianqian Yue, Fu-Gang Zhao*, Yanying Zhao*, Bingyige Pan, Li Bai, Xinping Wang & Wei-Shi Li*, Regioregular and Nondestructive Graphene Functionalization for High-Performance Electrochromic and Supercapacitive Devices. CCS Chem. 2020, 2, 1–13
★ Deng Yaoliang, Liu Xin, Zhao Yanying,* Xue Jiadan, Zheng Xuming. Resonance Raman spectroscopic and density functional theoretical study on microsolvated 2-Thiocytosine clusters with polar solvents[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2020, 230, 118043.
★ Zhao Yanying*, Yu Fan, Wang Caixia, Zhou Zhaoman. Simultaneous Formation of cis-and trans-CH3OCu (OH) Intermediates in Methane Activation by Cu in Solid Ar[J]. Inorganic Chemistry, 2019, 58(5): 3237-3246.
★ Liu Jiafengh, Xue Jiadan, Zhao Yanying*, Zheng Xuming. Short-time dynamics and decay mechanism of E, E-2, 4-hexadienal in the first light-absorbing S2(π π*) state[J]. The Journal of Chemical Physics, 2019, 151(23): 234303.
★ Zhou Zhaoman, Zhao Yanying*. Noble Gas–Tungsten Peroxide Complexes in Noble Gas Matrixes: Infrared Spectroscopy and Density Functional Theoretical Study[J]. The Journal of Physical Chemistry A, 2019, 123(2): 556-564.
★ Wei Xin, Duan Aimin, Deng Yaoliang, Xue Jiadan, Zheng Xuming, Zhao Yanying*. Excited‐state proton transfer via higher excited state in 2‐mercaptobenzothiazole: Absorption, fluorescence, Raman spectroscopic study, and theoretical calculation[J]. Journal of Raman Spectroscopy, 2019, 1, 1-9.

*以上信息由高级会员个人更新和维护。