王万辉

男， 大连理工大学， 教授/研究员/教授级高工或同等级别

学习/工作经历

2002/09-2004/06 济南大学化学化工学院 本科； 专业：化学工程与工艺
2004/09-2007/07 济南大学化学化工学院 硕士研究生；专业：化学工艺
2007/10-2008/03 日本埼玉大学理工学研究科 研修生
2008/04-2011/03 日本埼玉大学理工学研究科 博士研究生；专业：理工学（化学）
2011/05-2014/02 日本产业技术综合研究所（AIST）；特别研究员
2014/02-2020/12 大连理工大学石油与化学工程学院 副教授
2021/01至今 大连理工大学化工学院盘锦分院 教授

研究领域和兴趣

CO2资源化利用；化学储氢；金属有机化学；绿色有机合成

主要业绩

开发了一些列含羟基侧坠的仿生催化剂，用于催化甲酸储放氢和二氧化碳资源化利用。该类催化剂被广泛应用于加氢、脱氢反应中，展示出优异的催化活性，成为高效催化剂的设计理念之一。

代表成果

1. Wang, W.-H.; Wang, H; Yang, Y.; Lai, X.; Li, Y.;* Wang, J.; Himeda, Y.; Bao, M.* Synergistic Effect of Pendant N Moieties for Proton Shuttling in the Dehydrogenation of Formic Acid Catalyzed by Biomimetic Ir (III) Complexes, ChemSusChem 2020, 13, 5015-5022.
2. Wang, W.-H.; Feng, X.; Sui K.; Fang, D.; Bao, M.* Transition metal-free carboxylation of terminal alkynes with carbon dioxide through dual activation: Synthesis of propiolic acids. Journal of CO₂ Utilization 2019, 32, 140–145.
3. Wang, W.-H.; Tang, H.-P.; Lu, W.-D.; Li, Y.*; Bao, M.; Himeda, Y.* Mechanistic Insights into the Catalytic Hydrolysis of Ammonia Borane with Proton-Responsive Iridium Complexes: an Experimental and Theoretical Study ChemCatChem, 2017, 9, 3191-3196.
4. Wang, W.-H.*; Himeda, Y.*; Muckerman, J. T.*; Manbeck, G. F.; Fujita, E.* CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction. Chemical Reviews, 2015, 115, 12936–12973.
5. Wang, W.-H.; Ertem, M. Z.; Xu, S.; Onishi, N.; Manaka, Y.; Suna, Y.; Kambayashi, H.; Muckerman, J. T.;* Fujita, E.;* Himeda, Y.* Highly Robust Hydrogen Generation by Bioinspired Ir Complexes for Dehydrogenation of Formic Acid in Water: Experimental and Theoretical Mechanistic Investigations at Different pH. ACS Catalysis, 2015, 5, 5496–5504.
6. Wang, W.-H.; Xu, S.; Manaka Y.; Suna, Y.; Kambayashi, H.; Muckerman, J. T.; Fujita, E.; Himeda, Y.* Highly efficient formic acid dehydrogenation using bio-inspired Ir complexes: A deuterium kinetic isotope effect study and mechanistic insight. ChemSusChem, 2014, 7, 1976-1983.
7. Wang, W.-H.; Muckerman, J. T.;* Fujita, E.;* Himeda, Y.* Mechanistic insight through factors controlling effective hydrogenation of CO2 catalyzed by bio-inspired proton responsive iridium(III) complexes. ACS Catalysis, 2013, 3, 856-860.
8. Wang, W.-H.; Hull, J. F.; Muckerman, J. T.; Fujita, E.;* Himeda, Y.* Second-coordination-sphere and electronic effects enhance iridium(III)-catalyzed homogeneous hydrogenation of carbon dioxide in water near ambient temperature and pressure. Energy & Environmental Science 2012, 5, 7923-7926.
9. Wang, W.-H., Feng, X. and Bao, M., Transformation of Carbon Dioxide to Formic Acid and Methanol, Springer, 2017,
Singapore.
10. Wang, W.-H., Feng, X. and Bao, M., Homogeneously Catalyzed CO2 Hydrogenation to Formic Acid/Formate by Using Precious Metal Catalysts, In CO2 Hydrogenation Catalysis, Himeda Y. Ed., Wiley-VCH, 2021, pp13-52.

*以上信息由高级会员个人更新和维护。