朱旭辉

男， 广州华南理工大学发光材料与器件全国重点实验室/高分子光电材料与器件研究所， 教授/研究员/教授级高工或同等级别

学习/工作经历

1990.09 – 1994.06，安徽大学，化学系，本科学位
1994.09 – 1997.06，安徽大学，化学系，硕士学位
1997.09 – 2000.06，南京大学，化学学院，博士学位
2000.10 – 2001.09, 德国Martin-Luther University of Halle-Wittenberg, 无机化学研究所，博士后
2001.11 - 2002.9,法国University of Angers, IMMO,博士后
2003.01 –2004.12, 复旦大学，先进材料研究院，博士后
2004.12 -现在，华南理工大学材料科学与工程学院/发光材料与器件全国重点实验室，副教授、教授（广东省高等学校珠江学者特聘教授、二级教授）、博士生导师

研究领域和兴趣

分子基光电材料与化学；有机半导体；发光；OLED显示；光伏；闪烁体；电荷传输

主要业绩

朱旭辉 （Xu-Hui ZHU），华南理工大学发光材料与器件全国重点实验室教授 (State Key Laboratory of Luminescent Materials & Devices, South China University of Technology, SCUT)、博士生导师【1-33, 46】。入选教育部新世纪优秀人才计划、广东省珠江学者特聘教授，中国化学会高级会员。他先后在安徽大学、南京大学获得本科、硕士和博士学位，并在德国马丁·路德-哈勒维滕贝格大学、法国昂热大学和复旦大学从事博士后研究【34-45】。

研究方向聚焦于分子基光电材料的合成制备与性质研究，涵盖发光、吸光、闪烁体和电荷传输材料，并探求在OLED显示、光伏、光探测和成像等领域中的应用。他主持承担了NSFC-广东联合基金重点项目、科技部973课题、国家重点研发计划课题以及广东省重点领域研发计划课题。

主要研究成果包括：

1. 研发了兼具“高纯度”和“高玻璃化转变温度”的系列菲咯啉衍生物（如国际知名的Phen-NaDPO，实验室试剂），系统研究分子结构-性能关系，用于有机光电器件的阴极界面修饰层（适合空气中印刷）和蒸镀型叠层OLED器件的中间连接层（在约1.7×10⁻⁶ torr高真空度、300 °C高温条件下，经受住持续240小时的封管耐热试验）【1-9】。

2. 提出了一类芳香磷氧化合物的合成纯化方法，实现了长寿命OLED器件和长时间的封管耐热稳定性（在1.7×10⁻⁶ torr高真空度、285 °C高温和封闭条件下，持续加热240小时），揭示了其封管耐热机制，促进高纯有机半导体，特别是强极性材料的发展与应用，并因此获得2026年度国际显示技术大会（ICDT）优秀论文奖【10-15】。

3. 持续开展溶液加工电致发光材料的合成制备与性能研究，特别是蓝光材料。前期报道了高PL效率有机分子电致红光材料；通过广泛的合作，揭示了三重态激子参与电致发光过程，以及在高电流密度下，保持电流效率稳定的机制；发现在溶液、薄膜、纳米粒子状态，呈现高效率有机电化学红光，并且属于为数甚少、优于9,10-二苯基蒽的电化学发光材料；实现了650 nm光泵浦有机固态激光发射(PMMA光纤通信窗口)；优化墨水，利用喷墨打印技术，制备出平整、均匀的有机小分子发光薄膜；受邀撰写“可溶液加工、高PL效率有机分子电致荧光材料”的综述论文(Tutorial review，Chem Soc Rew 2011, 40, 3509)【16-30】。

4. 研发了日照下固态发光化合物；合作研发了新型高性能锰基闪烁体【31】。

其他研究还包括有机空穴传输材料【32】、分子离子玻璃【33,46】等。

非常感谢一起学习和工作的学生、合作者和同事们。My deepest gratitude goes to all the hard-working students, collaborators, and colleagues who have made incredible contributions.

代表成果

(1)https://www.dotaindex.com/scholar?q=Phen-NaDPO&page=1&start=0&end=0&lr=&scisbd=&sortType=0&as_rr= Last visited on 2026-06-14
(2)Tan, W.Y. et al. Lending Triarylphosphine Oxide to Phenanthroline: a Facile Approach to High-Performance Organic Small-Molecule Cathode Interfacial Material for Organic Photovoltaics utilizing Air-Stable Cathodes. Adv. Funct. Mater. 2014, 24, 6540 (Dedicated to Prof. Xiaozeng You's 80th birthday）.
(3)朱旭辉等，一类含有三芳基磷氧及氮杂环功能基团的醇溶性阴极缓冲层分子型材料及其合成方法与应用，ZL 201310275234.2，申请日：2013-07-02， 授权公告日：2016-01-16
(4)Hong Zhang, Wan-Yi Tan, Stefanie Fladischer, Lili Ke, Tayebeh Ameri, Ning Li, Mathieu Turbiez, Erdmann Spiecker, Xu-Hui Zhu, Yong Cao and Christoph J. Brabec, Roll to roll compatible fabrication of inverted organic solar cells with a self-organized charge selective cathode interfacial layer. J. Mater. Chem. A 2016, 4, 5032.
(5)Jin, G. et al. Appending triphenyltriazine to 1,10-phenanthroline: a robust electron-transport material for stable organic light-emitting diodes. Sci. Bull. 2018, 63, 446.
(6)Wenzhan Xu, Yu Gao, Wenjie Ming, Fang He, Jingzhou Li, Xu-Hui Zhu, Feiyu Kang, Jiangyu Li, and Guodan Wei. Suppressing Defects-Induced Nonradiative Recombination for Efficient Perovskite Solar Cells through Green Antisolvent Engineering. Adv. Mater. 2020, 2003965.
(7)Yaohui Li, Xiang Wu, Guangzheng Zuo, Yufei Wang, Xianjie Liu, Yanxian Ma, Bolun Li, Xu-Hui Zhu, Hongbin Wu, Jian Qing, Lintao Hou, and Wanzhu Cai, An n-n Heterojunction Configuration for Efficient Electron Transport in Organic Photovoltaic Devices. Adv. Funct. Mater. 2023, 33, 2209728.
(8)Jifa Wu, Yumeng Li, Feng Tang, Yinchun Guo, Guoqiang Liu, Shaoguang Wu, Bin Hu, Yuang Fu, Xinhui Lu, Guanghao Lu, Zhicai He, Xuhui Zhu, and Xiaobin Peng, Beyond Conventional Enhancements: Self-Organization of a Buffer Material on Tin Oxide as a Game-Changer for Improving the Performance of Inverted Organic Solar Cells. Small 2024, 20, 2404066.
(9)Wu, S.G. et al. A phenanthroline derivative modified by arylphosphine oxide moiety as nCGL in tandem OLEDs. SID Symp. Digest Tech. Papers 2024, 55, 316.
(10)Chen, L.L. et al. Molecular engineering of an electron-transport triarylphosphine oxide-triazine conjugate toward high-performance phosphorescent organic light-emitting diodes with remarkable stability. Sci. China Chem. 2020, 63, 904.
(11)Chen, L.L. et al. Phosphine oxide derivatives as a robust component for optoelectronics. Sci. Bull. 2020, 65, 2033 (News & Views).
(12)Xu, J.H. et al. Arylphosphine oxide derivative for OLEDs: Exhibiting robust stability under device operation & simulated evaporation chamber conditions. SID Symp. Digest Tech. Papers In press (2026年度ICDT优秀论文奖).
(13)朱旭辉等，不对称取代的可溶性吡啶类衍生物及制备、n-掺杂电子传输层与应用，ZL 201910313376.0，申请日：2019-04-18；授权公告日：2020-08-18
(14)朱旭辉等，一类高纯度芳香膦氧化合物的制备方法，ZL 202211692535.0，申请日：2022-12-28，授权公告日：2025-11-21
(15)朱旭辉等，一类含芳基膦酰基团的化合物的纯化制备方法，ZL 202211692534.6，申请日: 2022-12-28，授权公告日：2026-03-09
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(17)Huang, J. et al. A dithienylbenzothiadiazole pure red molecular emitter with electron transport and exciton self-confinement for non-doped organic red light-emitting diodes. Adv. Mater. 2008, 20, 4172.
(18)Huang, J. et al. Electroluminescence and laser emission of soluble pure red fluorescent molecular glasses based on dithienylbenzothiadiazole. Adv. Funct. Mater. 2009, 19, 2978.
(19)M. Shen, J. Rodriguez Lopez, J. Huang, Q. Liu, X.-H. Zhu and A. J. Bard. Electrochemistry and Electrogenerated Chemiluminescence of Dithienylbenzothiadiazole Derivative. Differential Reactivity of Donor and Acceptor Groups and Simulations of Radical Cation-Anion and Dication-Radical Anion Annihilations. J. Am. Chem. Soc. 2010, 132, 13453.
(20)Zhu, X.H. et al. Solution-processable single-material molecular emitters for organic light-emitting devices, Chem. Soc. Rev. 2011, 40, 3509.
(21)Mei Shen, Xu-Hui Zhu, and Allen J. Bard, Electrogenerated Chemiluminescence of Solutions, Films, and Nanoparticles of Dithienylbenzothiadiazole-Based Donor−Acceptor−Donor Red Fluorophore. Fluorescence Quenching Study of Organic Nanoparticles. J. Am. Chem. Soc. 2013, 135, 8868.
(22)S. Tang, W.-Y. Tan, X.-H. Zhu, L. Edman, Small-molecule light-emitting electrochemical cells: evidence for in situ electrochemical doping and functional operation, Chem. Commun. 2013, 49, 4926.
(23)Ping Chen, Li-Ping Wang, Wan-Yi Tan, Qi-Ming Peng, Shi-Tong Zhang, Xu-Hui Zhu and Feng Li, Delayed Fluorescence in a Solution-Processable Pure Red Molecular Organic Emitter Based on Dithienylbenzothiadiazole: A Joint Optical, Electroluminescence, and Magnetoelectroluminescence Study. ACS Appl. Mater. Interfaces 2015, 7, 2972.
(24)Zhao, L. et al. Anthracene-Cored Dendrimer for Solution-Processible Blue Emitter: Syntheses, Characterizations, Photoluminescence, and Electroluminescenc Macromol. Rapid Commun. 2006, 27, 914.
(25)Zhao, L. et al. Asymmetrically 9,10-disubstituted anthracenes as soluble and stable blue electroluminescent molecular glasses. Org. Electron. 2008, 9, 649.
(26)Li, Y. et al. Asymmetrically 4,7-Disubstituted Benzothiadiazoles as Efficient Non-doped Solution-Processable Green Fluorescent Emitters. Org. Lett. 2009, 11, 5318.
(27)Huimin Liu, Wei Xu, Wanyi Tan, Xuhui Zhu, Jian Wang, Junbiao Peng, Yong Cao, Line printing solution-processable small molecules with uniform surface profile via ink-jet printer. Journal of Colloid and Interface Science 2016, 465, 106.
(28)Peng, L. et al. Efficient soluble deep blue electroluminescent dianthracenylphenylene emitters with CIE y (y < = 0.08) based on triplet-triplet annihilation. Sci. Bull. 2019, 64, 774.
(29)Lan Mu, Mengjiao He, Congbiao Jiang, Juanhong Wang, Chaohuang Mai, Xiaolan Huang, Hua Zheng, Jian Wang, Xu-Hui Zhu and Junbiao Peng, Inkjet printing a small-molecule binary emitting layer for organic light-emitting diodes. DOI: 10.1039/d0tc00628a
(30)Zhang, J. et al. A 9-(4-diphenylphosphinylphenyl)anthracene derivative as a blue emitter host and a hole-blocking layer in Deep Blue OLEDs. SID Symp. Digest Tech. Papers 2023, 54, 48.
(31)Liju Liu, Shaoguang Wu, Junhao Xu, Chuang Zhang, Xu-Hui Zhu, Enhai Song, and Qinyuan Zhang, Structural Design and Performance Prediction of Zero-Dimensional Manganese (II) Halide Scintillators for X-Ray Imaging: A Case Study of (C33H29NP)2MnBr4·EtOH. DOI: 10.1002/adom.202503244
(32)Huang X.L. et al. A high Tg small-molecule arylamine derivative as a doped hole-injection/transport material for stable organic light-emitting diodes. Org. Electron. https://doi.org/10.1016/j.orgel.2018.04.012
(33)Liu, G. et al. An Ionic Molecular Glass as Electron Injection Layer for Efficient Polymer Light-Emitting Diode. Macromol. Rapid Commun. 2009, 30, 1484.
(34)H. Xu, L.-H. Wang, X.-H. Zhu, K. Yin, G.-Y. Zhong, X.-Y. Hou, W. Huang, Application of chelate phosphine oxide ligand in Eu-III complex with mezzo triplet energy level, highly efficient photoluminescent and electroluminescent performances. J. Phys. Chem. B 2006, 110, 3023.
(35)X. H. Zhu, L.-H. Wang, J. Ru, W. Huang, J. F. Fang, D. G. Ma, An efficient electroluminescent (2,2'-bipyridine mono N-oxide)europium(III) beta-diketonate complex. J. Mater. Chem. 2004, 14, 2732.
(36)Xu-Hui Zhu, Nicolas Mercier, Magali Allain, Pierre Frère, Philippe Blanchard,  Jean Roncali, Amédée Riou, Crystal structure of NH3-R-NH3)(NH3-R-NH2)PbI5 (R=5,5'-bis(ethylsulfanyl)-2,2'-bithiophene): NH3+⋯NH2 interaction as a tool to reach densely packed organic layers in organic-inorganic perovskites. Journal of Solid State Chemistry 2004, 177, 1067.
(37)X.H. Zhu, D. Gindre, N. Mercier, P. Frere, J.-M. Nunzi. Stimulated emission from a needle-like single crystal of an end-capped fluorene/phenylene co-oligomer. Adv. Mater. 2003, 15, 906.
(38)X.H. Zhu, N. Mercier, P. Frere, P. Blanchard, J. Roncali, M. Allain, C. Pasquier, A. Riou. Effect of mono- versus di-ammonium cation of 2,2'-bithiophene derivatives on the structure of organic-inorganic hybrid materials based on iodo metallates. Inorg. Chem. 2003, 42, 5330.
(39)X. H. Zhu, N. Mercier, A. Riou, P. Blanchard, P. Frere, (C4H3SCH2NH3)2(CH3NH3)Pb2I7: non-centrosymmetrical crystal structure of a bilayer hybrid perovskite. Chem. Commun. 2002, 2160.
(40)Xuhui Zhu, Eduard Rusanov, Ralph Kluge, Harry Schmidt, and Dirk Steinborn, Synthesis, Characterization, and Structure of [{PtMe3(9-MeA)}3] (9-MeAH= 9-Methyladenine): A Cyclic Trimeric Platinum(IV) Complex with a Nucleobase. Inorganic Chemistry, 2002, 41, 2667.
(41)X. H. Zhu, X. Z. You, X.-M. Ren, W. L. Tan, W. Ji, S. S. S. Raj, H.-K. Fun, Nonlinear Optical Properties of [C6H5N-R] [Ni(mnt)2] [R= p-nitrobenzyl]. Chem. Lett. 2000, 442.
(42)X. H. Zhu, X. F. Chen, Y. Zhang, X. Z. You, W. L. Tan, W. Ji, J. J.Vittal, G. K. Tan, C. H. L Kennard, Crystal structures, molecular packing and picosecond optical limiting properties of quadridentate Schiff-base divalent metal complexes derived from S-benzyl dithiocarbazate. New J. Chem. 2000, 24, 419.
(43)X. H. Zhu, X. F. Chen, Y. Zhang, X. Z. You, W. L. Tan, W. Ji, Nanosecond and picosecond optical limiting properties of a square-planar complex C30H24N6O4S4Cu, CuL2 [HL = p-nitrobenzaldehyde S-benzyl dithiocarbazate]. Chem. Lett. 1999, 1211.
(44)H.-K. Fun, S. Shanmuga Sundara Raj, X.-H. Zhu, X.-F. Chen, J.-L. Zuo and X.-Z. You, A neutral cobalt(II) complex of a Schiff base ligand containing mixed O2S2N2 donors. Acta Cryst. 1999. C55, 896-899.
(45)Xu-Hui Zhu, Shu-Hua Liu, Yong-Jiang Liu, Jing Ma, Cun-Ying Duan, Xiao-Zeng You, Yu-Peng Tian, Fu-Xing Xie, Shi-Sheng Ni, Syntheses and metal complexes of a quadridentate NNSS ligand derived from S-benzyl dithiocarbazate (H2L) and crystal structure of the complex CuL. Polyhedron 1998, 4, 181-185.
(46)Zhu X.H. Solution-processed molecular functional materials for organic optoelectronics.
SPIE Newsroom 2012-08-24 DOI: 10.1117/2.1201208.004357.

*以上信息由高级会员个人更新和维护。