钟地长

男， 天津理工大学， 教授/研究员/教授级高工或同等级别

学习/工作经历

1999年9月－2003年6月 赣南师范大学 大学本科
2003年9月－2006年6月 广西师范大学 硕士研究生
2006年7月－2008年8月 宜春学院 助教、讲师
2008年9月－2011年6月 中山大学 博士研究生
2011年7月－2020年8月 赣南师范大学 讲师、副教授、教授
2011年11月－2013年11月 日本产业技术综合研究所 JSPS博士后特别研究员
2020年9月－至今 天津理工大学 教授、博士生导师

研究领域和兴趣

功能配合物化学

主要业绩

围绕金属配合物分子催化剂的控制合成与能源催化转化开展了系统的研究工作，特别是在光电催化分解H2O制氢和CO2还原方面取得了系列重要进展：(1) 构筑了上百例具有不同结构的单核金属配合物分子催化剂，系统研究了金属中心、配位原子、空间位阻、共轭效应和限域作用对催化活性的影响规律，对催化反应机理进行了详细研究，总结了催化活性与结构之间的构效关系，获得了首例能抵抗氧气和CO毒化的高效电催化分解H2O制氢分子催化剂；(2) 在单核金属配合物研究的基础上，设计合成了系列双核金属配合物，获得了比相应单核金属配合物显著提升的光催化CO2还原活性，提出了双核金属协同催化CO2还原的学术思想；(3) 针对分子催化剂分离和回收利用不便的问题，发展了利用超分子作用力将分子催化剂有序异相化的有效方法。上述研究成果共计发表第一或通讯作者SCI收录论文70余篇，包括Proc. Natl. Acad. Sci. USA (1篇)、Sci. Adv. (1篇)、Angew. Chem. Int. Ed. (6篇)、J. Am. Chem. Soc. (1篇)、Coord. Chem. Rev. (3篇)等，5篇论文入选ESI高被引论文，授权中国发明专利5项；被聘为Exploration, SmartMat, eScience, Chin. Chem. Lett., Chin. J. Struct. Chem., Trans. Tianjin Univ., 山东化工等杂志（青年）编委，兼任中国稀土学会稀土分子材料与超分子器件专业委员会委员；获江西省五一劳动奖章，入选教育部青年长江学者和天津市特聘教授。

代表成果

(1) Jian-Hua Mei,† Ya-Ru Zeng,† Yun-Nan Gong, Wen-Jie Shi, Di-Chang Zhong*, and Tong-Bu Lu. π–π Stacking as Electron Transfer Channels in Hydrogen-bonded Organic Frameworks for Boosting Photocatalysis. Angew. Chem. Int. Ed. 2025, 64, e202507332.
(2) Ji-Hong Zhang, Zhao-Ming Ge, Di-Chang Zhong,* Jing-Lin Zuo, Marc Robert,* Tong-Bu Lu*. Self-photosensitizing Cobalt Complexes for Photocatalytic CO2 Reduction Coupled with CH3OH Oxidation. Angew. Chem. Int. Ed. 2025, 64, e202506060.
(3) Chong-Jiu Lu, Ji-Hong Zhang, Jian-Hua Mei, Yun-Nan Gong,* Tong-Bu Lu, and Di-Chang Zhong*. Modulating the Chromophores of Metal-Covalent Organic Frameworks for Boosting Low-Concentration CO2 Photoreduction. Angew. Chem. Int. Ed. 2025, 64, e202505292.
(4) Di-Chang Zhong, Yu-Chen Wang, Mei Wang, and Tong-Bu Lu*. Precise Synthesis of Dual-atom Catalysts for Better Understanding the Enhanced Catalytic Performance and Synergistic Mechanism. Acc. Chem. Res. 2025, 58, 1379-1391.
(5) Ji-Hong Zhang,† Zhao-Ming Ge,† Juan Wang, Di-Chang Zhong*, Tong-Bu Lu, Hydrogen-bonded organic frameworks for overall photosynthesis of hydrogen peroxide. Nat. Commun. 2025, 16, 2448.
(6) Yun-Nan Gong, Di-Chang Zhong*, Tong-Bu Lu. Porous Supramolecular Crystalline Materials for Photocatalysis. Angew. Chem. Int. Ed. 2025, 64, e202424452.
(7) Jiaxin Wang, Tianqun Song, Zheyuan Liu, Qinbai Yun, Juehan Sun, Ying Zhang, Kuo Yuan*, Dichang Zhong*, Zhiyong Tang, Tongbu Lu. Novel Inorganic-Organic Dual-Photosensitizing Dinuclear-Metal Self-Assembly System for Efficient Artificial Photosynthesis without Sacrificial Electron Donors. Angew. Chem. Int. Ed. 2025, 64, e202417373.
(8) Jian-Hua Mei,† Shan Lai,† Yun-Nan Gong,† Wen-Jie Shi, Ji-Hua Deng, Tong-Bu Lu, Di-Chang Zhong*. A Supramolecular-nanocage-based Framework Stabilized by π-π Stacking Interactions with Enhanced Photocatalysis. Angew. Chem. Int. Ed. 2025, 64, e202413413.
(9) Yun-Nan Gong§, Si-Qi Zhao§, Hong-Juan Wang§, Zhao-Ming Ge, Chen Liao, Ke-Ying Tao, Di-Chang Zhong*, Ken Sakai*, and Tong-Bu Lu*. A Planar-Structured Dinuclear Cobalt Complex for Synergistically Photocatalytic CO2-to-CO Conversion. Angew. Chem. Int. Ed. 2024, 63, e202411639.
(10) Chong-Jiu Lu,† Wen-Jie Shi,† Yun-Nan Gong*, Ji-Hong Zhang, Yu-Chen Wang, Jian-Hua Mei, Zhao-Ming Ge, Tong-Bu Lu, and Di-Chang Zhong*. Modulating the Microenvironments of Robust Metal Hydrogen-Bonded Organic Frameworks for Boosting Photocatalytic Hydrogen Evolution. Angew. Chem. Int. Ed. 2024, 63, e202405451.
(11) Kuo Yuan,* Zongyang Liu, Zhuang Yan, Qinbai Yun, Tianqun Song, Jun Guo, Xiaotao Zhang, Dichang Zhong*, Zhiyong Tang, Tongbu Lu*, Wenping Hu*. Metal-Organic Framework-Based Hetero-Phase Nanostructure Photocatalysts with Molecular-Scale Tunable Energy Levels. Angew. Chem. Int. Ed. 2024, 63, e202402693.
(12) Hui-Feng Wang,† Hong-Juan Wang,† Di-Chang Zhong*, Tong-Bu Lu.* Unveiling the role of proton concentration in dinuclear metal complexes for boosting photocatalytic CO2 reduction. Proc. Natl. Acad. Sci. USA 2024, 121, e2318384121.
(13) Kuo Yuan,*,† Keying Tao,† Tianqun Song,† Ying Zhang, Tao Zhang, Fei Wang, Shuming Duan, Zheng Chen, Lujiang Li, Xiaotao Zhang, Dichang Zhong,* Zhiyong Tang, Tong-Bu Lu*, and Wenping Hu.* Large-Area Conductive MOF Ultrathin Film Controllably Integrating Dinuclear-Metal Sites and Photosensitizers to Boost Photocatalytic CO2 Reduction with H2O as an Electron Donor. J. Am. Chem. Soc. 2024, 146, 6893−6904.
(14) Yun-Nan Gong,† Jian-Hua Mei,† Wen-Jie Shi, Jin-Wang Liu, Di-Chang Zhong,* Tong-Bu Lu.* Boosting CO2 Photoreduction to Formate or CO with High Selectivity over a Covalent Organic Framework Covalently Anchored on Graphene Oxide. Angew. Chem. Int. Ed. 2024, 63, e202318735.
(15) Ji-Hong Zhang,+ Hong-Juan Wang,+ Wen-Jie Shi, Wei Yang, Jian-Hua Mei, Yu-Chen Wang, Tong-Bu Lu, & Di-Chang Zhong*. Modulating the Binding of Metal Centers with Reaction Intermediates to Boost Photocatalytic CO2 Reduction. CCS Chem. 2024, 6, 2961–2970.
(16) Yun-Nan Gong, Si-Ya Lv, Hao-Yu Yang, Wen-Jie Shi, Jing-Jing Wang, Long Jiang, Di-Chang Zhong*, Tong-Bu Lu*. Heterogenization of a dinuclear cobalt molecular catalyst in porous polymers by covalent strategy for CO2 photoreduction with record CO production efficiency. CCS Chem. 2024, 6, 3030–3040.
(17) Di-Chang Zhong†, Yun-Nan Gong†, Chao Zhang†, Tong-Bu Lu.* Dinuclear metal synergistic catalysis for energy conversion. Chem. Soc. Rev. 2023, 52, 3170-3214.
(18) Ji-Hong Zhang+, Yun-Nan Gong+, Hong-Juan Wang+, Yu-Chen Wang, Wei Yang, Jian-Hua Mei, Di-Chang Zhong*, Tong-Bu Lu*. Ordered heterogeneity of molecular photosensitizer towards enhanced photocatalysis. Proc. Natl. Acad. Sci. USA 2022, 119, e2118278119.
(19) Yun-Nan Gong+, Chang-Yu Cao+, Wen-Jie Shi+, Ji-Hong Zhang, Ji-Hua Deng, Tong-Bu Lu, Di-Chang Zhong*. Modulating the Electronic Structures of Dual-Atom Catalysts via Coordination Environment Engineering for Boosting CO2 Electroreduction. Angew. Chem. Int. Ed. 2022, 61, e202215187.
(20) Wei Yang+, Hong-Juan Wang+, Rui-Rui Liu+, Jia-Wei Wang, Chao Zhang, Chao Li, Di-Chang Zhong*, Tong-Bu Lu*. Tailoring Crystal Facets of Metal–Organic Layers to Enhance Photocatalytic Activity for CO2 Reduction. Angew. Chem. Int. Ed. 2021, 60, 409-414.

*以上信息由高级会员个人更新和维护。