韩秋霞

女， 河南大学化学与分子科学学院， 教授/研究员/教授级高工或同等级别

学习/工作经历

1997/9-2001/7 河南大学，化学教育，理学学士
2001/9-2004/7 河南大学，无机化学，理学硕士
2004/7-2012/5 河南大学，助教及讲师
2010/9-2015/4 大连理工大学化学化工学院，无机化学，理学博士
2015/5-2019/8 河南大学化学博士后流动站，博士后
2012/6-2021/5 河南大学，副教授，硕士/博士生导师
2021/6-至 今 河南大学，教授，硕士/博士生导师

研究领域和兴趣

无机化学，功能配合物

主要业绩

长期从事无机化学、多酸化学和催化化学的交叉性研究工作，特别是以多酸基金属有机框架（POMOFs）晶态多孔功能材料为研究平台，围绕催化中心微环境的化学调控方面开展了较为系统的研究工作，部分研究成果获2020年度河南省自然科学三等奖（第一完成人）。研究结果已在国际重要SCI期刊上发表论文50余篇，部分发表在J. Am. Chem. Soc.、Nat. Commun.、J. Catal.、Chem. Commun.、Inorg. Chem.、ACS Appl. Mater. Interfaces等国际知名期刊上；获授权发明专利8项。

代表成果

1. Jiachen Jiao, Ting Zhang, Jiangbo Xu, Kaixin Guo, Jie Li and Qiuxia Han,* Hydroxyl Radical-dominated Selective Oxidation of Ethylbenzene over a Photoactive Polyoxometalate-based Metal-organic Framework, Chem. Commun., 2023, https://doi.org/10. 1039/d2cc06403k
2. Chen Si, Xueling Liu, Ting Zhang, Jiangbo Xu, Jie Li, Jiya Fu,* Qiuxia Han,* Constructing a Photocatalyst for Selective Oxidation of Benzyl Alcohol to Benzaldehyde by Photo-Fenton-like Catalysis, Inorg.Chem., 2023, accepted.
3. Xiaomei Yan, Jiangbo Xu, Ting Zhang, Chen Si, Jiachen Jiao, Jie Li, Qiuxia Han,*Designing polyoxometalate-based metal-organic framework for oxidation of styrene and cycloaddition of CO2 with epoxides, Chinese Chem. Lett., 2023 https://doi.org/10.1016/j.cclet.2022.107851
4. Ting Zhang, Chen Si, Kaixin Guo, Xueling Liu, Qingchao Liu, Jiya Fu,* and Qiuxia Han,* Constructing a Redox-Active Cu(I)-Pyridyltriazine Framework for Catalytic Photoreduction of Nitrobenzenes and Carboxylic Cyclization of Alkynol with CO2, Inorg. Chem., 2022, 61, 20657−20665. https://doi.org/10.1021/acs.inorgchem.2c03627
5. Jiachen Jiao, Hui Sun, Chen Si, Jiangbo Xu, Ting Zhang, Qiuxia Han,* Photocatalytic Multielectron Reduction of Nitroarenes to Anilines by Utilizing Electron-storable Polyoxometalate-based Metal-organic Framework, ACS Appl. Mater. Interfaces, 2022, 14, 16386−16393. https://pubs.acs.org/doi/10.1021/acsami.1c24911.
6. Chen Si, Fan Liu, Xiaomei Yan, Jiangbo Xu, Guiqin Niu, Qiuxia Han,* Designing Polyoxometalate-incorporated Metal-organic Frame-work for Reduction of Nitroarenes to Anilines by Sequential Proton-Coupled Electron Transfers, Inorg. Chem., 2022, 61, 5335−5342. https://doi.org/10.1021/acs.inorgchem.2c00106
7. Jiachen Jiao, Xiaomei Yan, Songzhu Xing, Ting Zhang, and Qiuxia Han,* Design of a Polyoxometalate-Based Metal−Organic Framework for Photocatalytic C(sp3 )−H Oxidation of Toluene, Inorg. Chem., 2022, 61, 2421−2427. https://pubs.acs.org/10.1021/acs.inorgchem.1c03150
8. Xiaomei Yan, Zhuolin Shi, Jiachen Jiao, Chen Si, Qiuxia Han*, An Isopolymolybdate-Incorporated Metal−Organic Framework with Sulfite Oxidase-Mimicking Activity for Photocatalytic Oxidation of Sulfides Utilizing In Situ-Generated Singlet Oxygen, Inorg. Chem., 2021, 60, 16810−16816. https://doi.org/10.1021/acs.inorgchem.1c02701
9. Chen Si, Pengtao Ma,* Qiuxia Han,* Jiachen Jiao, Wei Du, Jingpin Wu, Mingxue Li, and Jingyang Niu*. A Polyoxometalate-based Inorganic Porous Material with both Proton and Electron Conductivity by Light Actuation: Photocatalysis for Baeyer−Villiger Oxidation and Cr(VI) Reduction. Inorg. Chem., 2021, 60, 682−691. https://dx.doi.org/10.1021/acs.inorgchem.0c02658
10. Jie Li, Jiachen Jiao, Jiangnan Chang, Mingxue Li,* and Qiuxia Han,* Visible-Light-Driven C−N Bond Formation by a Hexanickel Cluster Substituted Polyoxometalate-Based Photocatalyst, Inorg. Chem., 2021, 60, 10022-10029. https://doi.org/10.1021/acs.inorgchem.1c01311
11. Jiachen He, Jie Li, Qiuxia Han,* Chen Si, Guiqin Niu, Mingxue Li, Jingping Wang, Jingyang Niu, Photoactive Metal-Organic Framework for the Reduction of Aryl Halides by the Synergistic Effect of Consecutive Photo-Induced Electron-Transfer and Hydrogen-Atom Transfer Processes, ACS Appl. Mater. Interfaces, 2020, 12, 2199−2206. https://doi.org/10.1021/acsami.9b13538
12. Jie Li, Jiachen He, Chen Si, Mingxue Li,* Qiuxia Han,* Ziliang Wang, Junwei Zhao，Special-Selective C–H Oxidation of Toluene To Benzaldehyde by a Hybrid Polyoxometalate Photocatalyst Including a Rare [P6W48Fe6O180]30– Anion, J Catal., 2020, 392, 244–253. https://doi.org/10.1016/j.jcat.2020.10.013
13. Jiachen He,† Qiuxia Han,*,† Jie Li, Zhuolin Shi, Xiaoyun Shi, Jingyang Niu,* Ternary Supramolecular System for Photocatalytic Oxidation with Air by Consecutive Photo-induced Electron Transfer Processes, J. Catal., 2019, 376, 161–167. https://doi.org/10.1016/j.jcat.2019.06.040
14. Zhuolin Shi, Jie Li, Qiuxia Han,* Xiaoyun Shi, Chen Si, Guiqin Niu, Pengtao Ma, and Mingxue Li, Polyoxometalate-Supported Aminocatalyst for the Photocatalytic Direct Synthesis of Imines from Alkenes and Amines, Inorg. Chem., 2019, 58, 12529−12533. https://doi.org/10.1021/acs.inorgchem.9b02056
15. Qiuxia Han, Bo Qi, Weimin Ren, Cheng He, Jingyang Niu, Chunying Duan.* Polyoxometalate-Based Homochiral Metal-Organic Frameworks for Tandem Asymmetric Transformation of Cyclic Carbonates from Olefins. Nat. Commun., 2015, 6, 10007. https://www.nature.com/articles/ncomms10007
16. Qiuxia Han, Cheng He, Min Zhao, Bo Qi, Jingyang Niu, Chunying Duan.* Engineering Chiral Polyoxometalate Hybrid Metal−organic Frameworks for Asymmetric Dihydroxylation of Olefins. J. Am. Chem. Soc., 2013, 135, 10186−10189. https://pubs.acs.org/doi/10.1021/ja401758c

发明专利（第一发明人）：
1. 韩秋霞;韦爱芬;宫德龙;焦嘉晨;司晨,一类缺位型多酸基金属有机框架分子材料及其在光催化选择性还原硝基苯的应用, 中国，发明专利，专利号：ZL 202210009328.4, 授权日期：2023.2.12。
2. 韩秋霞，马鹏涛，李杰，何佳宸，司晨，一种手性多酸基金属有机框架材料及其制备方法和应用, 中国，发明专利，专利号：ZL 2019 1 0209209.1, 授权日期：2021.10.12。
3. 韩秋霞，陈淑敏，马鹏涛，牛桂琴，司晨，一类富电子体系的金属有机框架分子材料及其在光催化还原重金属离子中的应用，中国，发明专利，专利号：ZL 2019 1 1324193.5，授权日期：2021.06.29。
4. 韩秋霞，李明雪，李杰，史卓林，司晨，基于Zn取代Keggin型杂多钨酸盐的有机-无机复合物、合成方法及应用，中国，发明专利，专利号：ZL 2019 1 0496900.2，授权日期：2021.04.23。
5. 韩秋霞，李明雪，李杰，邢松珠，王书改，一种亲水性无机多孔材料、制备方法及其在选择性催化醛或酮与羟胺反应方面的应用，中国，发明专利，专利号：ZL 2017 1 0352407.4，授权日期：2019.07.05。

*以上信息由高级会员个人更新和维护。