李阔

男， 北京高压科学研究中心， 教授/研究员/教授级高工或同等级别

学习/工作经历

2002-2006 北京师范大学化学系，本科，学士。
2006-2011 北京大学化学与分子工程学院，研究生，博士。
2011-2014 美国卡耐基研究院地球物理实验室，橡树岭国家实验室散裂中子源，博士后。
2014-至今 北京高压科学研究中心，研究员。

研究领域和兴趣

高压化学

主要业绩

一、综合运用包括大科学装置在内的多种先进手段，揭示了典型有机分子在高压下（数万到数十万大气压）的特有化学反应。如高压拓扑聚合、脂肪基向氰基、炔基的氢转移等，将人们对有机化学反应的认识推进到数十万大气压。
二、运用原位高压同步辐射X射线衍射、中子衍射等多种高压原位晶体学手段研究高压拓扑化学聚合反应，总结得到了炔基、芳基等官能团发生聚合反应的临界距离，并结合理论计算阐明了该距离的物理化学本质，为运用高压手段进行精准、理性合成奠定了基础。
三、从小分子晶体出发，控制合成了多种具有不同维度原子尺度有序结构的超细金刚石纳米线、纳米带材料，详细表征了它们的长程与短程结构，为精准控制合成不同维度的金刚石基纳米材料开辟了道路。
四、开拓了压力梯度驱动分解反应的研究方向。给出了压力梯度驱动化学反应的基本热力学关系，利用压力梯度驱动含氢化合物分解放出氢气，并将其设计为电池过程，发现了将压差转化为电动势的压伏效应。

代表成果

1. Zhe Zhang, Kuo Li, Shangchao Lin, Ruiqi Song, Dehong Yu, Yida Wang, Jingfan Wang, Shogo Kawaguchi, Zhao Zhang, Chengyang Yu, Xiaodong Li, Jie Chen, Lunhua He, Richard Mole, Bao Yuan, Qingyong Ren, Kun Qian, Zhuangli Cai, Jingui Yu, Mingchao Wang, Changying Zhao, Xin Tong, Zhidong Zhang, Bing Li, Thermal batteries based on inverse barocaloric effects, Science Advances, 9(7) (2023), DOI: 10.1126/sciadv.add0374;
2. Peijie Zhang, Dexiang Gao, Xingyu Tang, Xin Yang, Haiyan Zheng, Yida Wang, Xuan Wang, Jingqin Xu, Zijia Wang, Jie Liu, Xiaoge Wang, Jing Ju, Mingxue Tang, Xiao Dong, Kuo Li, Ho-kwang Mao, Ordered Van der Waals Hetero-nanoribbon from Pressure-Induced Topochemical Polymerization of Azobenzene, Journal of the American Chemical Society, 145(12) (2023), DOI: 10.1021/jacs.2c13753;
3. Xuan Wang, Xin Yang, Yida Wang, Xingyu Tang, Haiyan Zheng, Peijie Zhang, Dexiang Gao, Guangwei Che, Zijia Wang, Aijiao Guan, Jun-Feng Xiang, Mingxue Tang, Xiao Dong, Kuo Li, Ho-kwang Mao, From Biomass to Functional Crystalline Diamond Nanothread: Pressure-Induced Polymerization of 2,5-Furandicarboxylic Acid, Journal of the American Chemical Society, 144(48) (2022), DOI: 10.1021/jacs.2c08914;
4. Dexiang Gao, Xingyu Tang, Jingqin Xu, Xin Yang, Peijie Zhang, Guangwei Che, Yajie Wang, Yongjin Chen, Xiang Gao, Xiao Dong, Haiyan Zheng, Kuo Li, Ho-kwang Mao, Crystalline C3N3H3 tube(3,0) nanothreads, PNAS, 119(17) (2022), DOI: 10.1073/pnas.2201165119;
5. Yida Wang, Xin Yang, Xingyu Tang, Xuan Wang, Yapei Li, Xiaohuan Lin, Xiao Dong, Dongliang Yang, Haiyan Zheng, Kuo Li, Ho-kwang Mao, Pressure Gradient Squeezing Hydrogen out of MnOOH: Thermodynamics and Electrochemistry, The Journal of Physical Chemistry Letters, 12(44) (2021), DOI: 10.1021/acs.jpclett.1c03382;
6. Zhang, Peijie, Tang, Xingyu, Wang, Yida, Wang, Xuan, Gao, Dexiang, Li, Yapei, Zheng, Haiyan, Wang, Yajie, Wang, Xinxin, Fu, Riqiang, Tang, Mingxue, Ikeda, Kazutaka, Miao, Ping, Hattori, Takanori, Sano-Furukawa, Asami, Tulk, Christopher A., Molaison, Jamie J., Dong, Xiao, Li, Kuo, Ju, Jing, Mao, Ho-Kwang, Distance-Selected Topochemical Dehydro-Diels-Alder Reaction of 1,4-Diphenylbutadiyne toward Crystalline Graphitic Nanoribbons, Journal of the American Chemical Society, 142(41) (2020), DOI: 10.1021/jacs.0c08274;
7. Yajie Wang, Xiao Dong, Xingyu Tang, Haiyan Zheng, Kuo Li, Xiaohuan Lin, Leiming Fang, Guang’ai Sun, Xiping Chen, Lei Xie, Craig L. Bull, Nicholas P. Funnell, Takanori Hattori, Asami Sano-Furukawa, Jihua Chen, Dale K. Hensley, George Cody, Yang Ren, Hyun Hwi Lee, Hokwang Mao, Pressure-Induced Diels–Alder Reactions in C6H6‐C6F6 Cocrystal towards Graphane Structure, Angewandte Chemie International Edition, 58(5) (2019), DOI: 10.1002/anie.201813120;
8. Haiyan Zheng, Lijuan Wang, Kuo Li, Youyou Yang, Yajie Wang, Jiajia Wu, Xiao Dong, Chun-Hai Wang, Christopher A. Tulk, Jamie J. Molaison, Ilia N. Ivanov, Mikhail Feygenson, Wenge Yang, Malcolm Guthrie, Yusheng Zhao, Ho-kwang Mao, Changqing Jin, Pressure Induced Polymerization of Acetylide Anions in CaC2 and 10^7 Folds Enhancement of Electrical Conductivity, Chemical Science, 8(1) (2017), DOI: 10.1039/C6SC02830F;
9. Jiangman Sun, Xiao Dong, Yajie Wang, Kuo Li, Haiyan Zheng, Lijuan Wang, George D. Cody, Christopher A. Tulk, Jamie J. Molaison, Xiaohuan Lin, Yufei Meng, Changqing Jin, Ho-kwang Mao, Pressure Induced Polymerization of Acetylene: Structure Directed Stereoselectivity and a Possible Route to Graphane, Angew. Chem. Int. Ed, 129(23) (2017), DOI: 10.1002/anie.201702685;
10. Haiyan Zheng, Kuo Li, George D. Cody, Christopher A. Tulk, Xiao Dong, Guoying Gao, Jamie J. Molaison, Zhenxian Liu, Mikhail Feygenson, Wenge Yang, Ilia N. Ivanov, Leonardo Basile, Juan-Carlos Idrobo, Malcolm Guthrie, Ho-kwang Mao, Polymerization of Acetonitrile via a Hydrogen Transfer Reaction from CH3 to CN under Extreme Conditions., Angewandte Chemie International Edition, 55(39) (2016), DOI: 10.1002/anie.201606198.

*以上信息由高级会员个人更新和维护。