亢小辉

女， 大连医科大学， 教授/研究员/教授级高工或同等级别

学习/工作经历

1. 2005.08-2009.07 大连民族大学 应用化学专业，学士
2. 2009.09-2015.06 大连理工大学 应用化学专业，硕博连读，博士，导师：罗一
3. 2012.11-2013.11 日本理化学研究所 有机金属化学实验室，联合培养(留学基金委资助，一年)，导师：候召民
4. 2015.08-2016.11 中国科学院大连化学物理研究所 生物技术部 助理研究员 组长：吴仁安
5. 2016.12-2019.01 大连医科大学 药学院 讲师
6. 2019.01-2023.11 大连医科大学 药学院 副教授
7. 2023.12-至今 大连医科大学 药学院 正教授

研究领域和兴趣

高分子合成理论模拟

主要业绩

现任教于大连医科大学药学院药物化学教研室，主讲本科《药物化学》和《波谱分析》等课程，参编人卫本科规划教材《药学英语》1部。研究方向为医药用高分子材料合成机制的理论模拟研究。在国际著名期刊发表SCI论文70余篇，撰写英文专著1部；主持国家自然科学基金面上项目和青年项目各1项，辽宁省“兴辽英才计划”青年拔尖人才项目1项，大连市高层次人才创新创业项目1项，其他项目若干；入选辽宁省“兴辽英才计划”青年拔尖人才，辽宁省“百千万”人才工程，大连市青年科技之星。
主持项目
1) 国家自然科学基金面上项目，22171038，60万，2022.1-2025.12
2) 国家自然科学基金青年项目，21704011，23万，2018.1-2020.12
3) 辽宁省“兴辽英才计划”青年拔尖人才项目，XLYC2203034，50万，2023.10-2026.09
4) 2019年大连市高层次人才创新创业项目-青年科技之星，2019RQ088，10万元，2020.1-2021.12
5）辽宁省教育厅面上项目，LJKZ0848，3万，2021.08-2023.07
6) 辽宁省博士启动基金项目，20180540038，3万，2018.09-2021.08
7) 大连理工大学精细化工重点实验室开放课题，KF1713，5万，2017.12-2020.03

代表成果

论文：
(1) Xiaoxi Zhou, Qingde Zhuo, Takanori Shima*, Xiaohui Kang*, and Zhaomin Hou.* Denitrogenative Ring-Contraction of Pyridines to a Cyclopentadienyl Skeleton at a Dititanium Hydride Framework, J. Am. Chem. Soc., 2024, 146, 45, 31348−31355.
(2) Jinbo Zhang, Lihang Jiang, Shaofeng Liu,* Junhao Shen, Pierre Braunstein,* Yong Shen, Xiaohui Kang,* Zhibo Li.* Bifunctional and recyclable polyesters by chemoselective ring-opening polymerization of a δ-lactone derived from CO2 and butadiene, Nature Communications, 2024, 15, 8698.
(3) Huijun Fan, Xiaohui Kang,* and Shengyu Dai,* Stable ultrahighly branched polyethylene synthesis via externally robust chain-walking polymerization, ACS Catalysis, 2024, 14, 13531−13541.
(4) Zhen Zhang,⊥ Xiaohui Kang,⊥ Yang Jiang, Zhongyi Cai, Shihui Li, Dongmei Cui, Access to Disentangled Ultrahigh Molecular Weight Polyethylene via a Binuclear Synergic Effect, Angew. Chem. Int. Ed., 2023, 62, e202215582.
(5) Guanglin Zhou, Hongliang Mu, Xiaohui Kang,* Zhongbao Jian,* Direct Synthesis of Ultrahigh Molecular Weight Functionalized Isotactic Polypropylene, CCS Chemistry 2023, 5, 2638–2649.
(6) Chuang Song, Guoliang Mao, Xiukuan Yao, Yuxing Zhang, Wei Gao, Xiaohui Kang,* Zhongbao Jian*, Simple and sterically open Nickel catalyst for ultrahigh molecular weight polyethylene synthesis, Macromolecules, 2023, 56, 9540−9549.
(7) Yuxing, Zhang, Xiaohui Kang*, Zhongbao Jian,* Selective branch formation in ethylene polymerization to access precise ethylene-propylene copolymers. Nature Communication, 2022, 13, 725.
(8) Lanxiao Zhao, Peng Deng, Xun Gong, Xiaohui Kang,* Jianhua Cheng,* Regioselective C-H Alkylation of Aromatic Ethers with Alkenes by a Half-Sandwich Calcium Catalyst, ACS Catalysis, 2022, 12, 7877–7885.
(9) Wenhui Ren, Fen You, Jingjing Zhai, Xiaohui Kang*, Yat-Ming So*, and Xiaochao Shi,* Living (Co)Polymerization of Isoprene and Butadiene with Unparallel Stereoselectivity Catalyzed by Single Rare-Earth Metal Cationic Species, Macromolecules, 2022, 55, 23, 10640–10650.
(10) Kangkang Li, Hongliang Mu, Xiaohui Kang*, and Zhongbao Jian,* Suppression of Chain Transfer and Promotion of Chain Propagation in Neutral Anilinotropone Nickel Polymerization Catalysis, Macromolecules, 2022, 55, 2533–2541.
(11) Chaoqun Wang,⊥ Xiaohui Kang,⊥ Jian Zhongbao,* Efficient Suppression of Chain Transfer and Branching via C-sType Shielding in a Neutral Nickel(II) Catalyst, Angew. Chem. Int. Ed., 2021, 60, 4018−4022.
(12) Jinbo Zhang, Lebin Wang, Shaofeng Liu,* Xiaohui Kang,* Zhibo Li,* Lewis pair as organocatalyst for one-pot synthesis of block copolymers from mixture of epoxide, Anhydride, and CO2, Macromolecules, 2021, 54, 763−772.
(13) Zhen Zhang,⊥ Xiaohui Kang,⊥ Yang Jiang, Zhongyi Cai, Shihui Li, Dongmei Cui, Access to Disentangled Ultrahigh Molecular Weight Polyethylene via a Binuclear Synergic Effect, Angew. Chem. Int. Ed., 2023, 62, e202215582. (共同 一作, IF = 16.8)
（14）Chaoqun Wang,⊥ Xiaohui Kang,⊥ Jian Zhongbao,* Efficient Suppression of Chain Transfer and Branching via C-sType Shielding in a Neutral Nickel(II) Catalyst, Angew. Chem. Int. Ed., 2021, 60, 4018−4022. (共同一作, IF = 16.8)
（15） Xiaohui Kang, Gen Luo, Lun Luo, Shaowei Hu, Yi Luo,* Zhaomin Hou,* Mechanistic Insights into ring cleavage and contraction of benzene over a titanium hydride cluster, Journal of the American Chemical Society 2016, 138, 11550–11559.
(16) Xiaohui Kang, Yi Luo,* Guangli Zhou, Xingbao Wang, Xuerong Yu, Zhaomin Hou, Jingping Qu, Theoretical mechanistic studies on the trans-1,4-specific polymerization of isoprene catalyzed by a cationic La−Al binuclear complex, Macromolecules 2014, 47, 4596–4606.
(17) Xiaohui Kang, Yuming Song, Yi Luo,* Gang Li, Zhaomin Hou,* Jingping Qu,* Computational studies on isospecific polymerization of 1-hexene catalyzed by cationic rare earth metal alkyl complex bearing a C3 iPr-trisox ligand Macromolecules 2012, 45, 640–651.
(18) Takanori Shima, Shaowei Hu, Gen Luo, Xiaohui Kang, Yi Luo, Zhaomin Hou,* Dinitrogen cleavage and hydrogenation by a trinuclear titanium polyhydride complex, Science 2013, 340, 1549–1552.

著作
(1) Xiaohui Kang, Yi Luo, Zhaomin Hou. Chapter 10: Theoretical Insights into Olefin Polymerization Catalyzed by Cationic Organo Rare-Earth Metal Complexes, In Book: Computational Quantum Chemistry, Elsevier, 2019, DOI: 10.1016/B978-0-12-815983-5.00010-6.

*以上信息由高级会员个人更新和维护。