徐柏庆

男， 清华大学化学系， 教授/研究员/教授级高工或同等级别

学习/工作经历

1978,09 - 1982,07： 江西大学（现南昌大学） 化学系，物理化学专业本科生
1982,08 - 1985,02： 中国科学院大连化学物理研究所，多相催化专业硕士研究生
1985,03 - 1988,10： 中国科学院大连化学物理研究所，物理化学专业博士研究生
1986,01 - 1988, 04: 日本国北海道大学理学院，日本政府奖学金物理化学专业博士研究生
1988,10 - 1991,11： 中科院大连化物所，助理研究员（一级）、催化领域学术活动领导小组成员兼秘书。
1991,12 - 1992,09： 大连理工大学副教授
1992,10 - 1998,04： 大连理工大学教授, 校务委员会委员
1995,03 - 1996,06: 美国西北大学催化与表面科学研究中心, 中国教育部优秀中青年高级访问学者
1996,07 - 1997,06: 美国佐治亚理工大学化工学院, research faculty
1997,07 - 1998,04: 美国西北大学催化与表面科学研究中心, research associate
1998,05 - ： 清华大学化学系教授、清华大学一碳化学与化工国家重点实验室主任 (1999－2002), 物理化学研究所所长 (2002～2017), 教育部长江学者奖励计划特聘教授 (2016-2019)
2001,12 - 2002,03: 美国加州大学伯克利分校, 催化中心访问教授
2002,12 - 2003,05: 香港浸会大学化学系, 香港裘槎基金会访问学者

研究领域和兴趣

催化物理化学

主要业绩

发现并提出了固体酸碱催化剂表面烷基胺分解转化反应的活性与选择性规律；阐明了硫酸氧化锆催化剂上丁烷异构化反应的质子酸催化本质；提出和发展了“纳米复合物型金属/氧化物”催化剂学说；近年提出了发展贵金属节约型催化剂的新思路，在一些生物质平台分子的催化增值转化研究中做出了若干新发现。

代表成果

1. G.-R. Zhang, D. Zhao, Y.-Y. Feng, B.-S. Zhang, D.-S. Su, G. Liu, and B.-Q. Xu*, Catalytic Pt-on-Au nanostructures: Why Pt becomes More Active on Smaller Au Particles, ACS Nano 6, 2226-2236 (2012).
2. Zhao, D; Xu, BQ*, Enhancement of Pt utilization in electrocatalyst using gold nanoparticles, Angew. Chem. Int. Ed. 45: 4955-4959 (2006).
3. Zhang, X; Shi, H; Xu, BQ*, Catalysis by gold: Isolated surface Au3+ ions are active sites for selective hydrogenation of 1,3-butadiene over Au/ZrO2 catalysts, Angew. Chem. Int. Ed. 44, 7132-7135 (2005).
4. Zhang, X; Wang, H; Xu, BQ*; Remarkable nanosize effect of zirconia in Au/ZrO2 catalyst for CO oxidation, J. Phys. Chem. C 109, 9678-9683 (2005).
5. Chai, SH; Wang, HP; Liang, Y; Xu, BQ*, Sustainable Production of Acrolein: Investigation of Solid Acid-Base Catalysts for Gas-phase Dehydration of Glycerol, Green Chemistry 9: 1130- 1136 (2007).
6. Y. Gu, L. Wang, B.-Q. Xu*, H. Shi*. Recent advances in the molecular-level understanding of catalytic hydrogenation and oxidation reactions at metal-aqueous interfaces. Chin. J. Catal. 54: 1-55 (2023).
7. B. Yan, Z. -H. Liu, Y. Liang, B.-Q. Xu*. Acrylic Acid Production by Gas-Phase Dehydration of Lactic Acid over K+-Exchanged ZSM-5: Reaction Variable Effects, Kinetics, and New Evidence for Cooperative Acid–Base Bifunctional Catalysis. Ind. Eng. Chem. Res., 59(39): 17417-17428 (2020).
8. J.-W. Yang, W.-T. Zheng, Z. Hu, M. Zhang, B.-Q. Xu*, Do Olefin Hydrogenation Reactions Remain Structure Insensitive over Pt in Nanostructured Pt-on-Au Catalyst? ACS Catal. 8, 10254-10260 (2018).
9. Zi-Fei Yuan, Wei-Na Zhao, Zhi-Pan Liu and Bo-Qing Xu, NaOH alone can be a homogeneous catalyst for selective aerobic oxidation of alcohols in water, J. Catal. 353, 37-43 (2017).
10. Bo Yan, Li-Zhi Tao, Azhar Mahmood, Yu Liang, Bo-Qing Xu*, Potassium-Ion-Exchanged zeolites for sustainable production of acrylic acid by gas-phase dehydration of lactic acid, ACS Catal. 7, 538–550 (2017).
11. Liu-Liu Shen, Gui-Rong Zhang, Shu Miao, Jingyue (Jimmy) Liu, Bo-Qing Xu*, Core−shell nanostructured Au@NimPt2 electrocatalysts with enhanced activity and durability for oxygen reduction reaction, ACS Catal. 2016, 6, 1680-1690 (2016).
12. B. Yan, L.-Z. Tao, Y. Liang, and B.-Q. Xu*, Sustainable Production of Acrylic Acid: Catalytic Performance of hydroxyapatites for gas-phase dehydration of lactic acid, ACS Catal. 4, 1931-1943 (2014).
13. S.-S. Liu, K.-Q. Sun, and B.-Q. Xu*, Specific selectivity of Au-catalyzed oxidation of glycerol and other C3‑polyols in water without the presence of a base, ACS Catal. 4, 2226-2230 (2014).
14. R.-Y. Zhong, K.-Q. Sun, Y.-C. Hong, and B.-Q. Xu*, Impacts of Organic Stabilizers on Catalysis of Au Nanoparticles from Colloidal Preparation, ACS Catal. 4, 3982-3993 (2014).
15. L.-Z. Tao, B. Yan, Y. Liang and B.-Q. Xu*, Sustainable production of acrolein: catalytic performance of hydrated tantalum oxides for gas-phase dehydration of glycerol, Green Chem. 15, 696-705 (2013).
16. K.-Q. Sun, Y.-C. Hong, G.-R. Zhang, B.-Q. Xu*, Synergy between Pt and Au in Pt-on-Au (Ptm^Au) Nanostructures for Chemoselective Hydrogenation Catalysis, ACS Catal. 1, 1336-1346 (2011).
17. X. Zhang, H. Shi, B.-Q. Xu*, Vital roles of hydroxyl groups and gold oxidation states in Au/ZrO2 catalysts for 1,3-butadiene hydrogenation, J. Catal. 279, 75-87 (2011).
18. Nan-Hong Xie, Xiang-Hui Yan, Bo-Qing Xu*, Is Ammonium peroxydisulfate indispensable for preparation of aniline-derived iron-nitrogen-carbon electrocatalysts? ChemSusChem 9, 2301-2306 (2016).
19. X.-H. Yan, and B.-Q. Xu*, Mesoporous carbon material co-doped with nitrogen and iron (Fe–N–C): high-performance cathode catalyst for oxygen reduction reaction in alkaline electrolyte, J. Mater. Chem. A 2, 8617-8622 (2014).
20. H. Zhang, B. Yao, L. Zhao, D.-X. Wang, B.-Q. Xu, M.-X. Wang*, Direct Synthesis of High-Valent Aryl-Cu(II) and Aryl-Cu(III) Compounds: Mechanistic Insight into Arene C-H Bond Metalation, J. Am. Chem. Soc. 136, 6326-6332 (2014).

*以上信息由高级会员个人更新和维护。